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MEMS(微电子机械系统)湿度传感器是利用标准的CMOS技术加上MEMS的后处理技术制造,以其体积小、响应快等优点受到越来越多的重视,介绍了本实验室研制的MEMS压阻式湿度传感器的测试原理、硬件电路的设计和传输函数模型的建立,以及软件设计和封装设计,最后给出了样机的测试结果。 相似文献
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Room temperature ionic liquids (ILs) that can exhibit a colorimetric response to moisture in the air are rarely reported in the literature. In this study, an azophenolic IL solution exhibited a spontaneous a colorimetric response, driven by the formation of hydrogen bonding between the [PhN=NPhO] anion and moisture in the air. This phenomenon was clearly understood using ultraviolet-visible (UV-Vis) absorption spectroscopy, nuclear magnetic resonance (NMR) spectra, experimental data, and theoretical calculations. Specifically, in the UV-Vis absorption spectra, absorption around 455 nm decreased, while the band around 343 nm increased in the IL CHCl3 solution as time progressed; this was accompanied by a color change from orange to faint yellow. This spontaneous, self-responsive process was further observed using 1H NMR data. When the IL solution was placed with sufficient time, all the 1H NMR peaks of the azophenolic anion shifted downfield, but no new signals appeared in the upfield region. The reason for this was easily identified as the stimuli in the air, such as CO2 and moisture. When pure CO2 was bubbled through the IL CHCl3 solution, the solution color changed from its original orange to light orange, but could not change further to faint yellow, which ruled out CO2 gas as a stimulus. When a small amount of water was gradually added to the IL solution (MeCN solvent), the absorption band around 474 nm decreased, coupled with an increase in the absorption band around 347 nm. This was accompanied by a color change from orange to faint yellow, which was almost identical to the self-responsive process in CHCl3 and CCl4. Moreover, two cuvettes of IL CHCl3 solution were placed under relative humidities of 28% and 100%, respectively; the IL CHCl3 solution required a much longer time to exhibit a complete color change from orange to faint yellow under a lower relative humidity, demonstrating that moisture is the most likely stimulus triggering the self-responsive color change of the IL solution. As revealed by the Gaussian 09 program at the B3LYP/6-31++G(p, d) level, the distance between the oxygen atom on the azophenolic anion and the hydrogen atom on the H2O molecule was 0.174 nm, and the corresponding angle was 171.12°. Furthermore, the atomic dipole moment corrected Hirshfeld (ADCH) charge of the oxygen atom on the azophenolic anion was −0.52, and it increased to −0.62 after the azophenolic anion interacted with the H2O. Reduced density gradient analysis revealed that the spike corresponding to O∙∙∙H―O for the IL-H2O complex was located at around −0.04 a.u.. All the above data indicate that the presence of hydrogen bonding rendered the IL solution responsive to the moisture stimulus, and this response was accompanied by a color change that was visible to the naked eye. To the best of our knowledge, this is the first demonstration of a colorimetric change in an IL solution in response to moisture. We hope this work can help us to gain insight into some seemingly abnormal phenomena that occur during the research process. 相似文献
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相对湿度是许多领域的关键参数,环境湿度与人们的生活密切相关,因此对湿度进行测量和控制是各个领域中值得关注的问题之一. 在前期的研究中,作者制备了一种新型的超分子离子材料(SIM),它是由基于咪唑的双阳离子(如1,10-双(3-甲基咪唑-1-基)癸烷,C10(mim)2)和电活性二阴离子(如2,2'-连氮基-双(3-乙基苯并噻唑啉-6-磺酸),ABTS)组成的,发现其对湿度具有敏感且快速的响应. 在此基础上,本文制备了6种不同碳链(C4,C6,C8,C10,C12,C14)的咪唑基化合物,发现其中3种(C10,C12,C14)可与ABTS形成水稳定的SIM. 循环伏安法、计时电流法以及石英晶体微量天平表征了这些超分子离子材料的湿度传感性能,发现基于C12的SIM具有最佳的湿度传感性能. 同时,SEM结果显示随着碳链的增加,离子材料的厚度变薄并且形态变得不规则. 因此,作者认为疏水作用和材料比表面积均会影响湿度传感的灵敏度. 本研究为发展新的湿度响应的离子传感材料奠定了基础. 相似文献
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为了能够对汽轮机湿蒸汽各参数的变化进行精准的监测,提高汽轮机内部除湿技术和机组的运行效率,对湿蒸汽参数后向异轴散射测量模型进行了优化和实验研究。基于Mie散射理论建立了湿蒸汽测量模型,对原散射体的几何模型进行优化;通过MATLAB对该模型进行了仿真模拟,计算得到当接收距离d=0.32 m,水滴群质量中间半径r0.5=1 μm,尺寸分布参数K=5和水滴数浓度N=2.5×1011时,散射光强值达到最佳。利用相减消光法和均值滤波法对CCD相机信号进行了提取和处理,并对不同工况下的湿蒸汽参数进行了实验测量计算与反演,实验反演的结果和仿真模拟的结果变化趋势吻合。研究结果验证了基于CCD的后向异轴散射测量模型的准确性和测量汽轮机蒸汽湿度实验研究的可行性,为今后的汽轮机蒸汽湿度测量提供了科学依据。 相似文献
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