硕果繁花荣九秩 仁风德范仰高贤——祝贺吴浩青先生九秩华诞暨执教69周年讲誌庆

著名电化学家、中国科学院资深院士吴浩青教授今年迎来他的九秩华诞．在半个多世纪来，吴老以他广博的学识和勤奋的精神为我国电化学事业作出了突出的贡献．     

The Isoelectric Point and the Points of Zero Charge of Fe-Al-Mg Hydrotalcite-like Compounds

The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations.     

Magnetic and Crystalline Microstructures of Fe-Pt-B Nanocomposite Ribbons

We investigate magnetic and crystalline microstructures of melt-spun (Fe0.675Pt0.325)100-xBx (x=12, 14, 16, 18,20) nanocomposite ribbons after optimal thermal treatment using a magnetic force microscope. The magnetic microstructures are characterized by darker spots adjacent to brighter ones in a sub-micro scale and in random distribution. It is found that the strength of the exchange coupling interaction between the crystals in the 10-100 nm scale, implied by the maximum value (δM)max of the Henkel plot, could be roughly described by the ratio of the average width of the magnetic spots w^- to the average crystal size D^- for the ribbons. Moreover, we find that the intrinsic coercivity jHc of the ribbons is sensitive to their crystal sizes, and the smaller D^-, the higher jHc. Finally, by using roughness analysis, the curve of the root mean square values (δФ)rms of the phase shift of the magnetic force images versus the boron content x is obtained, which is qualitatively consistent with that of the magnetization σ12 kOe of the ribbons versus x.     

介电多层膜与人工介电超晶格的研究

近年来，铁电薄膜制备技术的迅速发展使得人工介电超晶格的生长成为现实。简要介绍了有关介电多层膜和人工介电超晶格的制备、结构和性能的研究状况，讨论了进一步研究需解决的问题。     

阶跃电压法确定产生寿命的计算公式

采用一个最近发展起来的产生区宽度模型，导出了描述阶跃电压作用下ＭＯＳ电容器的电容－时间瞬态特性方程，给出了阶跃电压法确定产生寿命的一个计算公式。     

Study on the in—plane electrical resistivity and thermoelectric power in single crystals of La2—xBaxCuO4

The in-plane electrical resistivity and thermoelectric power have been measured on single crystals of La_2-xBa_xCuO₄ at around x=0.125. The room temperature resistivity and thermopower have their maximum values at x=0.125, indicating that the carrier concentration is the minimum and the carriers are most strongly localized at x=0.125. The observed semiconductor-like behaviour can be well described by the weak-localized quasi-two-dimensional state. The steep rise in electric resistivity of the sample at x=0.125 below 70K is attributed to the formation of static stripe-order of holes and spins, which are pinned by the low-temperature tetragonal (LTT) structure, as discovered in La_1.48Nd_0.4Sr_0.12CuO₄. The temperature dependence of electric resistivity below 70K is still well described by the formula ρ∝ lnT. A definite change in the slope of thermopower is observed at the low-temperature orthorhombic-LTT structural phase transition temperature. The origin of the 1/8 anomaly is discussed in the text.     

场论说对非线性网络节点电压法一般形式方程的推导

从场论说的非线性网络中积分形式的基尔霍夫定律出发，能严格和简练地推导从非线性网络到线性网络的节点电压法的一般形式的网络状态方程，并给出复自导和复互导各与复电导之间包括正负号关系在内的普遍关系式。     

金钢石的制备研究

本文研究了两种不同质异构体石墨—金刚石的转化条件，以及在实验室现有条件下，利用石墨材料制备金刚石颗粒的具体方法和试验结果。     

MCS—51单片机在大滞后温度智能控制中的应用

文章介绍了以ＭＣＳ５１系列单片机为核心的计算机控制系统，用以实现工业催化剂活性检测过程床层温度程序控制。被控对象是具有３～８分钟的纯滞后、时变、非线性特性的催化剂电加热炉，控制难度大。采用了广义最小方差自校正控制算法，具有时变滞后的极点自校正ＰＩＤ算法，极点对消直接ＰＩＤ三种算法进行了仿真与现场试验研究。前两种，由于工作过程允许的信号对系统激励不够充分，对象在线辩识有困难，试验结果表现，不能实现预期的控制要求。最终采用了极点对消直接ＰＩＤ算法，成功地实现了催化剂活性温度自动控制。该系统工作稳定、可靠，控制精度达到了检测标准要求。     

热处理WO3电变色膜稳定性研究

采用电子束蒸发淀积ＷＯ３薄膜。根据已有的ＷＯ３薄膜脱水过程结论而选择适当温度对薄膜进行退火处理。在大量含水的和不含水的两类Ｌｉ＾＋电解质中进行比较性着色和消色循环实验，表明在２９０℃以下热退火处理能明显增加ＷＯ３薄膜在含水 电解质中的循环寿命。