Wavelength tunability of tandem optical parametric oscillator based on single PPMgOLN crystal

The theoretical analysis and experimental results of the wavelength tunability of a tandem optical parametric oscillator (TOPO) based on a single nonlinear crystal are presented.TOPO is a configuration wherein the signal laser is used as a pump laser to generate secondary optical parametric oscillator (OPO).The cascaded parametric interactions are achieved synchronously in a single-grating-period MgO doped periodically poled lithium niobate (PPMgOLN).Tunable multiple-wavelength mid-infrared (mid-IR) lasers are obtained by changing the temperature of the crystal.When the PPMgOLN crystal with a grating period of 31.2 μm is operated at 148 ℃,the dual OPOs generate an identical mid-IR laser of 2.83 μm.The secondary OPO transforms into an optical parametric amplifier,in which different frequency mixing from the signal laser results in the amplification of the idler laser in the first OPO.TOPO is a useful configuration for multiple laser output,broad tuning range,and high-efficiency mid-IR lasers.     

单频脉冲光纤放大器中的SBS效应实验研究

为了研究受激布里渊散射(SBS)效应对单频脉冲光纤激光放大器中脉冲波形的影响,搭建了单频脉冲光纤激光放大器系统。实验中观测到脉冲波形的畸变,继续提高功率,畸变处出现峰值功率极高的尖峰,分析认为,光纤中的二次受激布里渊散射导致了尖峰脉冲出现。为验证这一结论,构造包含二阶Stokes波的耦合方程组,进行了模拟仿真。结果表明,该峰值功率极高的尖峰正是SBS效应的二阶Stokes波。     

取代位置对香豆素衍生物二阶非线性光学性质影响的DFT研究

采用密度泛函理论（DFT）B3LYP/6-31G方法,对设计的6个不同位置取代氨基的香豆素衍生物的几何构型进行优化。在所得优化结构的基础上对这些分子的稳态二阶NLO系数β值进行计算分析,并采用含时密度泛函理论（TD-DFT）方法计算了其电子性质,研究了取代位置对香豆素类衍生物分子的二阶NLO性质的影响规律。结果表明：当氨基取代在4号位时香豆素分子中的羰基表现出供电性,对分子内电荷转移非常不利,不利于提高分子的β值;当氨基取代在在3、5、6、7、8位时分子中的羰基表现出吸电性,使分子形成D-π-A构型,并且氨基在3、7位的取代能够扩大体系的共轭范围,有效增加了香豆素分子的βtot值。     

1,3-取代方酸衍生物非线性光学性质的从头算和半经验方法的比较研究

The structures of 1,3-substituted squaraine derivatives Sq1 ～ Sq12 were fully optimized by ab initio HF method with 6-31G* basis set level,and the electronic structures of Sq1 ～ Sq12 were also calculated. Based on the optimized structures,the electronic spectra were obtained by the CIS / 6-31G* method,which suggested that the max absorption wavelength mainly resulted from the electronic transition from HOMO to LUMO. The second nonlinear optical coefficients（β0）were calculated using ab initio CPHF method at 6-31G* basis set level and FF / AM1,FF / PM3,FF / MNDO,FF / MINDO3 methods. A systematic comparison between the results was carried out. It indicated that the second nonlinear optical coefficients were affected dramatically by the properties of five-membered hetero-rings. β0 can be enhanced by introducing pyrrole,thiazole and oxazole. The position of five-membered rings containing two heteroatoms which were connected with four-membered squaraine rings also affected β0 .     

Influence of Excitation Pulse Width on the Second-Order Correlation Functions of the Exciton-Biexciton Emissions

We investigate theoretically the population dynamics and the second-order correlation functions of photon emissions from the biexciton-exciton system of a single quantum dot with excitation from pulses to continuous wave. The dynamic equations of the correlation functions are deduced by applying quantum regression theorem to optical Bloch equations. The influences of excitation pulse width on the correlation function have been discussed in detail.     

A COMPACT UPWIND SECOND ORDER SCHEME FOR THE EIKONAL EQUATION

We present a compact upwind second order scheme for computing the viscosity solution of the Eikonal equation. This new scheme is based on： 1. the numerical observation that classical first order monotone upwind schemes for the Eikonal equation yield numerical upwind gradient which is also first order accurate up to singularities; 2. a remark that partial information on the second derivatives of the solution is known and given in the structure of the Eikonal equation and can be used to reduce the size of the stencil. We implement the second order scheme as a correction to the well known sweeping method but it should be applicable to any first order monotone upwind scheme. Care is needed to choose the appropriate stencils to avoid instabilities.     

正交各向异性摩擦接触分析的一个二阶锥线性互补法

建立了用于各向异性摩擦接触分析的一个新型互补模型:二阶锥线性互补模型.通过与弹翅性力学的类比,并引入线性二阶锥互补的概念,将正交各向异性摩擦接触定律表达为一个二阶锥线性互补模型.在此基础上,在参变量变分原理的框架下,建立了正交各向异性摩擦接触问题的有限元列式.由于避免了对摩擦锥的显式线性化,使得该文模型的变量个数较线性互补模型小很多,而解的精度又高很多.文末通过算例,说明了方法对于正交各向异性摩擦接触分析的有效性.     

盐酸吡哆辛及其制剂的二阶导数差示脉冲极谱法定量研究

建立盐酸吡哆辛及其制剂的二阶导数差示脉冲极谱定量分析方法。盐酸吡哆辛在0.1mol/L氢氧化钠溶液-0.1moL/L磷酸二氢钾溶液-水(体积比为1.2:8.8:990)的混合溶液中,于-0.140V(vs·Ag/AgCl)处出现一良好的二阶导数差示脉冲极谱峰,盐酸吡哆辛浓度在3.6×10~(-4)～9.6×10~(-4)mol/L范围内与其峰幅值呈显著的线性关系(P<0.01),线性相关系数r=0.9997,检出限为9.0nmol/L。     

2,4,6-三(对甲基苯乙烯基)均三嗪的合成、结构及其光学性质

合成了八极分子2,4,6-三(对甲基苯乙烯基)均三嗪[即2,4,6-tris(p—methylstyryl)-s-triazine,缩写为TMSTA],用四圆X衍射法测得该晶体属于正交晶系的Pmn21空间群,晶体结构非中心对称,分子构型为微弯曲的平面三角形,具有近似的D3h对称性．该化合物在氯仿中最长波长吸收峰位于337nm,在极性较强的溶剂乙腈中的荧光发射峰位于435nm．在1064nm皮秒脉冲基频光下,测得其粉末的倍频光强度为尿素的9．1倍．另外,TMSTA良好的热稳定性(熔点为235～237℃)增加了其作为1064nm Nd：YAG激光的倍频材料的应用价值．     

琼脂凝胶中形成铬酸铅周期性沉淀的机理研究

选择硝酸铅和铬酸钾作为相互扩散的反应物以形成铬酸铅在琼脂凝胶中的周期性沉淀．分别在光照和黑暗中对六种不同浓度的硝酸铅溶液进行了实验．根据实验现象对周期性沉淀的形成提出了可能的机理．认为光辐射可使铬酸铅部分电离，从而减慢了胶核成长速率，有利于汇聚成带．