全文获取类型
收费全文 | 140篇 |
免费 | 27篇 |
国内免费 | 4篇 |
专业分类
化学 | 27篇 |
力学 | 5篇 |
数学 | 2篇 |
物理学 | 109篇 |
无线电 | 28篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 5篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2017年 | 10篇 |
2016年 | 5篇 |
2015年 | 7篇 |
2014年 | 12篇 |
2013年 | 8篇 |
2012年 | 9篇 |
2011年 | 9篇 |
2010年 | 10篇 |
2009年 | 6篇 |
2008年 | 4篇 |
2007年 | 12篇 |
2006年 | 8篇 |
2005年 | 3篇 |
2004年 | 9篇 |
2003年 | 9篇 |
2002年 | 3篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有171条查询结果,搜索用时 15 毫秒
1.
A. N. Iyer U. Balachandran L. R. Motowidlo J. G. Hoehn P. Haldar 《Journal of Electronic Materials》1994,23(11):1087-1091
Pb0.4Bi1.8Sr2Ca2.2Cu3Ox (Bi-2223) precursor powder was prepared by a solid-state reaction of carbonates and oxides of lead, bismuth, strontium, calcium,
and copper, and the powder was then used to fabricate silver-clad tapes by the powder-in-tube technique. Transport critical
current density (Jc) values>4×104 A/cm2 at 77K and 2×105 A/cm2 at 4.2 and 27K have been achieved in short tape samples. Long lengths of tape were tested by winding them into pancake coils.
Recently, we fabricated a test magnet by stacking ten pancake coils, each containing three 16m lengths of rolled tape, and
tested it at 4.2, 27 and 77K. A maximum generated field of 2.6 T was measured in zero applied field at 4.2K and the test magnet
generated significant self-field in background fields up to 20 T. The results are discussed in this paper. 相似文献
2.
An HPLC post column chemical derivatization procedure based on the interaction between an acridinium triflate and amines to form highly colored derivatives on-line is described for the determination of aromatic amines. Benzocaine and butesin, local anesthetic agents that contain the aromatic amine group, were used as model compounds. Reversed-phase HPLC conditions were developed for both the separation of analytes and the reaction between analytes and the acridinium triflate in the system. Three-dimensional knitted teflon shape coils and the internal diameter and length of the coils were important parameters in reducing band broadening and background noise.N-Methyl-9-chloroacridinium triflate was shown to be applicable to the determination of primary aromatic amines, selected secondary aromatic amines, hydrazides, and hydrazines. Application of the on-line chemical derivatization procedure to the analysis of pharmaceutical dosage forms containing procainamide (primary aromatic amine), isoniazid (hydrazide), and hydralazine (hydrazine) is also described. 相似文献
3.
Prof. Dr. Gebhard Haberhauer Prof. Dr. Rolf Gleiter 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(25):8646-8653
The double “pancake” bonding in the dimers of the six‐membered heterocycles 1,3‐dithia‐2,4,6‐triazine ( 4 ) and 1,3‐dithia‐2,4‐diazine ( 16 ) were investigated by means of high‐level quantum chemical calculations (B3LYP and CCSD(T)). It was found that the S–S dimers, 20 a and 27 , are not the most stable isomers, but the dimers showing short S?N ( 21 a ) and S?C ( 25 , 28 ) bonds. An investigation of the 5‐phenyl‐1,3‐dithia‐2,4,6‐triazine ( 4 b ) yields that the syn dimer with two S?S bonds (2.57 Å) is the most stable one. In this dimer, the phenyl groups are placed on top of each other. The additional dispersion energy of the phenyl rings causes a stabilization of the syn‐S–S (C2v‐like) isomer. As a result, two weak albeit relevant single S?S bonds (2.57 Å) are predicted. These findings contradict the recently published concept of double “pancake” bonding in the dimer 4 b 2. 相似文献
4.
为了验证高温超导体中涡旋薄饼运动的存在,我们设计了电流和电位引线分处样品不同表面的实验。实验结果表明,在这种电流电位引线配置下的E~j关系不同于刚性涡旋线运动所预期的E~j关系,由此支持了涡旋薄饼运动的存在。 相似文献
5.
6.
In the strict sense, it is not very clear why with magnetic field increasing, the normal-superconductive (NS) transition becomes broad for Bi2Sr2CaCu2O8+δ(Bi2212) while the NS transitions are almost parallel for La1.93Sr0.07CuO4+δ(La214). In this paper, R-T relations are measured by the six-probe method. We propose a moving mechanism of the pancake vortex and vortex line for Bi2212. The theoretical curves fit the experiment data well. 相似文献
7.
Hana Robson Marsden Alexander Kros Dr. 《Angewandte Chemie (International ed. in English)》2010,49(17):2988-3005
Biological self‐assembly is very complex and results in highly functional materials. In effect, it takes a bottom‐up approach using biomolecular building blocks of precisely defined shape, size, hydrophobicity, and spatial distribution of functionality. Inspired by, and drawing lessons from self‐assembly processes in nature, scientists are learning how to control the balance of many small forces to increase the complexity and functionality of self‐assembled nanomaterials. The coiled‐coil motif, a multipurpose building block commonly found in nature, has great potential in synthetic biology. In this review we examine the roles that the coiled‐coil peptide motif plays in self‐assembly in nature, and then summarize the advances that this has inspired in the creation of functional units, assemblies, and systems. 相似文献
8.
Vossen M Teeuwisse W Reijnierse M Collins CM Smith NB Webb AG 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,208(2):291-297
We describe the design and testing of a quadrature transmit, eight-channel receive array RF coil configuration for the acquisition of images of the entire human spinal column at 7 T. Imaging parameters were selected to enable data acquisition in a clinically relevant scan time. Large field-of-view (FOV) scanning enabled sagittal imaging of the spine in two or three-stations, depending upon the height of the volunteer, with a total scan time of between 10 and 15 min. A total of 10 volunteers have been scanned, with results presented for the three subjects spanning the range of heights and weights, namely one female (1.6 m, 50 kg), one average male (1.8 m, 70 kg), and one large male (1.9 m, 100 kg). 相似文献
9.
螺旋管内高压汽水两相流动沸腾干涸点的研究 总被引:1,自引:0,他引:1
在较宽的实验参数范围内(系统压力P=8~15 MPa,质量流速G=800~1800 kg·m~(-2)·s~(-1),壁面热流密度q_w=200~950 kW·m~(-2))对一立式螺旋管内(管内径为10 mm,螺旋直径为300 mm,节距为50 mm)汽水两相流动沸腾干涸特性进行了实验研究。通过研究,获得了干涸发生时螺旋管圈壁温的分布特征以及压力、质量流速和壁面热流密度这三个参数对临界干度的影响规律。同时在实验数据的基础上,提出了一个适用于计算螺旋管内高压高含汽率工况下汽水两相流临界干度的经验关系式。 相似文献
10.
Shahriar KhushrushahiMarkus Zahn 《Journal of magnetism and magnetic materials》2011,323(10):1302-1308
Ferrofluid spin-up flow is studied within a sphere subjected to a uniform rotating magnetic field from two surrounding spherical coils carrying sinusoidally varying currents at right angles and 90° phase difference. Ultrasound velocimetry measurements in a full sphere of ferrofluid shows no measureable flow. There is significant bulk flow in a partially filled sphere (1-14 mm/s) of ferrofluid or a finite height cylinder of ferrofluid with no cover (1-4 mm/s) placed in the spherical coil apparatus. The flow is due to free surface effects and the non-uniform magnetic field associated with the shape demagnetizing effects. Flow is also observed in the fully filled ferrofluid sphere (1-20 mm/s) when the field is made non-uniform by adding a permanent magnet or a DC or AC excited small solenoidal coil. This confirms that a non-uniform magnetic field or a non-uniform distribution of magnetization due to a non-uniform magnetic field are causes of spin-up flow in ferrofluids with no free surface, while tangential magnetic surface stress contributes to flow in the presence of a free surface.Recent work has fitted velocity flow measurements of ferrofluid filled finite height cylinders with no free surface, subjected to uniform rotating magnetic fields, neglecting the container shape effects which cause non-uniform demagnetizing fields, and resulting in much larger non-physical effective values of spin viscosity η′∼10−8−10−12 N s than those obtained from theoretical spin diffusion analysis where η′≤10−18 N s. COMSOL Multiphysics finite element computer simulations of spherical geometry in a uniform rotating magnetic field using non-physically large experimental fit values of spin viscosity η′∼10−8−10−12 N s with a zero spin-velocity boundary condition at the outer wall predicts measureable flow, while simulations setting spin viscosity to zero (η′=0) results in negligible flow, in agreement with the ultrasound velocimetry measurements. COMSOL simulations also confirm that a non-uniform rotating magnetic field or a uniform rotating magnetic field with a non-uniform distribution of magnetization due to an external magnet or a current carrying coil can drive a measureable flow in an infinitely long ferrofluid cylinder with zero spin viscosity (η′=0). 相似文献