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11.
K. Dayananda R. Dhamodharan K. Vijayakumaran T. Rajamannar 《Journal of polymer science. Part A, Polymer chemistry》2004,42(21):5413-5423
A monolayer of covalently anchored, novel, binaphthyl ketone is used as a surface‐confined photochemical radical generator (PRG) for anchoring a variety of polymers to silicon surfaces. The precursor PRG is synthesized by the application of a facile and novel method for the oxidation of sterically hindered benzylic hydrocarbons to carbonyl compounds. Oxidation was carried out with a stoichiometric amount of potassium peroxydisulfate, in the presence of a catalytic amount of copper sulfate in an acetonitrile/water mixture. The PRG synthesized is characterized by 1H NMR, UV, and Fourier transform infrared (FTIR). The covalently attached monolayers are characterized by X‐ray photoelectron spectroscopy, ellipsometry, and water contact angle measurements. The method developed is applicable to the preparation of a monolayer of a variety of polymers on a wide range of substrates carrying surface hydroxyl groups. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5413–5423, 2004 相似文献
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由于可见光成像系统的聚焦范围有限,因而在成像过程中,除聚焦良好的物体能生成清晰的图像外,该物体前后一定距离外的所有物体都将呈现不同程度的模糊.为了获得场景内所有物体均清晰的图像,在分析了多聚焦图像成像机理的基础上,提出了一种基于小波包变换的融合方法.它是将成像系统先聚焦在一部分对象上,得到其清晰的图像;然后再将其聚焦在另一部分对象上,得到另一清晰的图像;最后把这两幅实验图像加以融合,从而获得场景内所有物体均清晰的图像.实验结果表明,基于小波包变换的融合方法能够将信号的频带进行多层次划分,对高频成分也能进一步地分解,可有效综合多聚焦图像. 相似文献
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用反向调制照明法分析光栅成像效应 总被引:2,自引:1,他引:1
提出了用反向调制照法明分析光栅成像效应的观点,研究了光栅系统的反向衍射干涉效应,成功地揭示了泰伯效应与劳效应的内在联系,并在白光双光栅衍射干涉的“消色效应”的基础上获得了白光扩展光源照明下白光光栅成像效应和具有实用意义的四光栅干涉系统。 相似文献
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We have used x-ray fluorescence analysis to study the elemental composition of gunshot residues from smooth-bore and rifled-bore
guns. We have established that it is possible to differentiate between types of projectiles (jacketed/lead), types of primers
(corrosive/noncorrosive), and types of propellant powders (black/smokeless) by analysis of the elemental composition of the
gunshot residues. We have shown that the mercury content in gunshot residues on the surface of the object carrying the residues
steadily decreases as storage time increases. Despite this fact, mercury can be preserved as a component of gunshot residues
on the object (cotton cloth) under room conditions for more than 45 days.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 3, pp. 320–325, May–June, 2006. 相似文献
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A planar metamaterial structure consisting of two layers of split-ring resonator (SRR) arrays is demonstrated to form the
image of a point source with subwavelength resolution. The source frequency is swept through the resonance gap of the metamaterial
layers and the lateral field intensity distribution is recorded on the transmission side of the metamaterial. When the source
is tuned to the resonance frequency of SRRs, the metamaterial acts as a high permeability medium and a distinct image with
subwavelength resolution in the lateral direction is obtained. Increasing the distance between the individual SRR layers reduces
the interlayer coupling, and the intensity and spatial resolution of the image decrease rapidly. 相似文献
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Recently, molecular imaging has been rapidly developed to studyphysiological and pathological processes in vivo at the cellularand molecular levels. Among molecular imaging modalities, opticalimaging has attracted a major attention for its unique advantages.In this paper, we establish a mathematical framework for multispectralbioluminescence tomography (BLT) that allows simultaneous studiesof multiple optical reporters. We show solution existence, uniquenessand continuous dependence on data as well as the limiting behaviourswhen the regularization parameter approaches zero or when thepenalty parameter approaches infinity. Then, we propose twonumerical schemes for multispectral BLT and derive error estimatesfor the corresponding solutions. 相似文献
20.
《Magnetic resonance in chemistry : MRC》2003,41(8):585-588
A novel, radical responsive MRI contrast agent based on a gadolinium chelate conjugated to a liposome through a disulfide linker was synthesized, with the aim of pursuing the in vivo mapping of radicals. The liposome was prepared by incorporating a thiol‐activated phospholipid, which was subsequently reacted with a gadolinium chelate containing a free thiol group. The long reorientational motion of the supramolecular adduct endows the paramagnetic agent with a relaxivity significantly higher than that of the free complex. The disulfide bond represents a radical‐sensitive moiety and a large decrease in contrast efficacy (T1 relaxivity) is shown upon its cleavage. A preliminary assessment of the system was made by means of in vitro gamma‐irradiation and thiol–disulfide bond exchange with dithiothreitol. Both methods showed a clear dose‐dependent decrease in T1‐relaxivity. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献