Simultaneous and Sensitive Detection of Cd(II) and Pb(II) Using a Novel Bismuth Film/Ordered Mesoporous Carbon‐molecular Wire Modified Graphite Carbon Paste Electrode

An electrochemical sensor for the simultaneous and sensitive detection of Cd(II) and Pb(II) is proposed on the basis of square‐wave anodic stripping voltammetry (SWASV) experiments using a novel bismuth film/ordered mesoporous carbon‐molecular wire modified graphite carbon paste electrode (Bi/OMC‐MW/GCPE). Ordered mesoporous carbon (OMC) and molecular wire (MW) (diphenylacetylene) were used as the modifier and binder, respectively. The Bi/OMC‐MW/GCPE was prepared with the addition of graphite powder, OMC and DPA at the ratio of 2 : 1 : 1. The electrochemical properties and morphology of the electrode were characterized by electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), SWASV and scanning electron microscopy (SEM). The parameters affecting the stripping current response were investigated and optimized. The experimental results show that the prepared electrode exhibited excellent electrochemical performance, good electrical conductivity and a high stripping voltammetric response. Under optimized conditions, a linear range was achieved over a concentration range from 1.0 to 70.0 μg/L for both Cd(II) and Pb(II) metal ions, with detection limits of 0.07 μg/L for Cd(II) and 0.08 μg/L for Pb(II) (S/N=3) with the deposition time 150 s. Moreover, the sensor exhibited improved sensitivity and reproducibility compared to traditional CPEs. The fabricated electrode was then successfully used to satisfactorily detect Cd(II) and Pb(II) in real soil samples.     

Effect of Free‐Stream Turbulence on the Flow Structure near a Wedge and the Windward Side of an Airfoil

The flow structure behind wire grids is studied for flows with a low subsonic velocity, and the effect of grids on the boundarylayer flow structure is considered. It is shown that the meanvelocity inhomogeneity induced by the grid does not disappear until a distance of 925 calibers downstream of the grid is reached. Liquidcrystal thermography combined with hotwire measurements made it possible to find the source of steady largescale streamwise vortex structures in the boundary layer on a wedge and on an airfoil and to determine the parameters of these structures.     

量子线/铁基超导隧道结中隧道谱的研究

考虑铁基超导中能带间的相互作用和界面对每一个能带的散射作用, 利用推广的Blonder-Tinkham-Klapwijk模型, 并通过求解Bogoliubov-de Gennes 方程研究了具有不同类型双能隙系统的量子线/铁基超导隧道结中准粒子的输运系数和隧道谱. 研究表明: 1)在弹道极限时, 随着带间相互作用的增大, s_± 波隧道谱中零偏压附近的平台演变成电导峰; s₊₊ 波的平台演变成凹陷; p波的零偏压电导峰被压低. 2)界面对两个能带的散射作用不为零时, 随着带间相互作用的增大, s_± 波和s₊₊ 波两能隙处的峰值将降低, 而两峰间的凹陷值将变大; p波的零偏压电导峰被压低, 非零偏压电导增大. 3)界面对每个能带的散射, 可使其产生的电导峰变得更加尖锐, 但可压低和抹平另一个带产生的电导峰值. 这些结果对于澄清铁基超导体的能隙结构和区别不同类型铁基超导体有所帮助.     

局域共振型声学超材料机理探讨

本文以二维固体薄板中的弹性波传播为例, 对基于共振子结构的声学超材料带隙机理进行了探讨, 证明在声学超材料中带隙形成既与共振子对波的散射相位有关, 也与波在共振体之间的几何传播相位有关. 通过调节散射相位和几何传播相位均能实现对色散关系的调控. 基于这一理解, 探究了弹性波超材料中的次波长缺陷态和负折射现象的实现条件.     

DNA-templated photonic arrays and assemblies: design principles and future opportunities

Molecular photonics is a rapidly developing and multi-disciplinary field of research involving the construction of molecular assemblies comprising photoactive building blocks that are responsive to a light stimulus. A salient challenge in this field is the controlled assembly of these building blocks with nanoscale precision. DNA exhibits considerable promise as an architecture for the templated assembly of photoactive materials. In this Concept Article we describe the progress that has been made in the area of DNA photonics, in which DNA acts as a platform for the construction of optoelectronic assemblies, thin films and devices.     

一种电力架空线垂度的简算方法

以输配电工程中带有绝缘子的电力架空线为研究对象, 简化绝缘子的力学模型, 采用纵横弯 曲理论推导了钢芯铝铰线的挠度方程, 计算了在自重和温度载荷共同作用下的架空线垂度和 水平张力. 计算结果表明, 文中算法简单有效, 架空线跨距和温度等是架空线垂度的主要 影响因素. 架空线垂度对温度的平均变率为2.55mm/$^{\circ}$C; 当跨距减 小1%时, 垂度增加近60%.     

On the formation of gap solitons in nonlinear electromagnetic metamaterials

A nonlinear (Kerr‐type) electromagnetic metamaterial, characterized by a double‐Lorentz model of its frequency‐dependent linear effective dielectric permittivity and magnetic permeability, is considered. The formation of gap solitons in the low‐ and high‐frequency band gaps of this metamaterial is investigated analytically. Evolution equations governing the gap solitons, of the form of a nonlinear Klein‐Gordon and a nonlinear Schrödinger equation, are obtained, and the structure of their solutions is discussed.     

太赫兹波段超材料的制作、设计及应用

本文从制作方法、结构设计和材料选择几方面综述了超材料在太赫兹波段的电磁响应特性和潜在应用。首先,介绍了获得不同维度、具有特异电磁响应以及结构可调超材料的各种微加工制作方法,进而分析和讨论了超材料的电磁响应特性。文中指出,结构设计可以控制超材料的电磁响应特性,如各向异性、双各向异性、偏振调制、多频响应、宽带响应、不对称透射、旋光性和超吸收等。超材料的电磁响应依赖于周围微环境的介电性质,因而可用于制作对环境敏感的传感器件。此外,电光、磁光、相变、温度敏感等功能材料的引入可以获得光场、电场、磁场、温度等主动控制的太赫兹功能器件。最后,简单介绍了超材料在太赫兹波段进一步发展所面临的机遇和挑战。     

Analysis of volatiles associated with industrial scale processing of expanded polystyrene Part II: Identification and quantitation

Expanded polystyrene was pyrolyzed on a laboratory scale hot wire cutter. The resulting volatiles were characterized using GC/MS as the primary analytical tool. Use was also made of retention data from a complex petrochemical standard. In situ bromination of the pyrolysate further helped in structure elucidation. Air samples were collected in the field and compared to the model experiments from a laboratory scale hot wire cutter. The results indicate that alkylbenzene type compounds were the primary compounds in this environment. A few oxygenated substances were also formed. Traces of brominated compounds were detected in the model experiments but not in the samples collected in the field, with one exception. Quantitative data are presented from a typical industrial operation.     

Hybridization of optical phonons with double quantum-wire plasmons including drift instabilities

We examine the collective mode spectrum for a double quantum-wire system embedded in semi-infinite polar medium, taking account of the role of optical phonons in interaction with the double quantum-wire plasmons and bulk/surface plasmons. The collective mode frequencies are exhibited as functions of q_x (wavenumber parallel to the wires) and as functions of z₀ (distance of first wire from the interface). We also find that the region of drift instability of the collective modes is split into two disjoint regions of instability by the optical phonons, with a region of stability between them.