Nickel Chloride Promoted Glaser Coupling Reaction in Hot Water

A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride withoutany organics and bases in hot water has been developed, which produces the correspondinghomo-coupling products in good yields.     

铁基添加剂增强细水雾灭火性能的实验研究

采用实验模拟的方法,研究了添加氯化亚铁的细水雾在不同添加剂浓度、不同喷头压力下,熄灭不同性质的液体池火的性能。实验结果表明:添加有氯化亚铁的细水雾,其灭火性能发生了显著变化。存在一个最佳的灭火浓度,其对应的灭火时间最短,耗水量最少,灭火效率最高。细水雾喷头的工作压力和燃料的性质也对细水雾的灭火性能有影响:工作压力越大,细水雾的平均灭火时间越短。在相同的实验条件下,细水雾扑灭煤油池火的时间要短于扑灭酒精池火的时间。     

Investigation and optimization of the covering power and coloristic properties of paint coatings of complex composition

A method for finding the optimum sizes of pigment particles, their volume concentration, and the paint coating thickness that provide the covering power and the required coloristic characteristics of reflected light for the minimum flow rate of pigments is based on using a four-flow approximation of the solution to the equation of radiation transfer in dispersion media and is extended to coatings of complex composition. The capabilities of the method are demonstrated by examples of coatings of mixtures of hematite and rutile particles in a binder with n=1.5 for variations of the modal size and the half-width of the size distribution of the pigment particles. B. I. Stepanov Institute of Physics, Academy of Sciences of Belarus, 70, F. Skorina Ave., Minsk, 220072, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 90–96, January–February, 1997.     

证券投资组合的风险与收益

本文利用概率统计原理对证券的投资组合能减轻所遇的风险作了讨论 ,并介绍了如何选择投资组合可使所遇风险达到最小     

电流并联负反馈放大器实验的研究

用实验的方法，研究电流并联负反馈对放大器性能的改善，提出电流型、并联型负反馈放大器性能参数的测量方法。     

Linear and Nonlinear Optical Properties Of Racemic (±)2-(α-Methylbenzylamino)-5-Nitropyridine Single Crystals

Linear and nonlinear optical properties of racemic (±)2-(α-methylbenzylamino)-5-nitropyridine ((±)MBANP) single crystals have been comprehensively investigated and compared with those of the enantiomorph (–)2-(α-methylbenzylamino)-5-nitropyridine ((–)MBANP) crystals. (±)MBANP crystal exhibits very high chemical and physical stability, but relatively small nonlinear optical coefficients (d₃₁ = 6.8 pm/V, d₃₂ = 4.7 pm/V, d₃₃ = 0.84 pm/V). A comparison between the nonlinear optical coefficients of (±)MBANP and (–)MBANP demonstrates the validity of the oriented-gas model in molecular crystals that neglects all the contributions from intermolecular interaction.     

Assessing the Error Probability of the Model Selection Test

The asymptotic error probability of Linhart's model selection test isevaluated, and compared with the nominal significance level. We examine thecase where the expected discrepancies of the candidate models from the truemodel are asymptotically equal. The local alternatives method is employed inthe limiting operation of the asymptotic evaluation. Although the errorprobability under the null hypothesis is actually shown to be equal to orless than the level for most situations, intolerable violations of the errorcontrol are observed for nested models: It is often erroneously concludedthat the smaller model is significantly better than the larger model. Toprevent this violation, a modification of Linhart's test statistic isproposed. The effectiveness of the proposed test is confirmed throughtheoretical analysis and numerical simulations.     

类铜离子的电子碰撞参数及其规律

用准相对论扭曲波方法系统地计算了Ｂａ、Ｎｄ、Ｇｄ、Ｙｂ、Ａｕ、Ｐｂ类铜离子组态能级之间的电子碰撞激发强度Ω（ｎｌ－ｎｌ），３≤ｎ≤７，４≤ｎ≤７，同时给出了高能极限的碰撞强度和外推到阈值的碰撞强度，用最小二乘样条方法拟合了全能域碰撞强度及热平均速率系数。对于一个激发过程，用１０个参数可以得到碰撞电子在任意能量下的碰撞强度以及任意温度下的速率系数。     

Mathematical modelling and analytical solution for workpiece temperature in grinding

This paper deals with modelling the workpiece temperature field produced during the grinding process. The proposed model is given in terms of a two-dimensional boundary-value problem where the interdependence among the grinding wheel, the workpiece and the coolant is described by two variable functions in the boundary condition. An explicit integral form solution is constructed using the Laplace and Fourier transforms and the Green’s function method.     

浅水中污染物扩散的自适应有限元分析法

介绍浅水中污染物扩散分析中的有限元法.分析包括两个部分:1)流场速度、水面高度的计算;2)根据扩散模型计算污染物浓度场.联合使用了自适应网格技术以期提高解的精度,同时减少计算时间和计算机内存的消耗.通过几个有已知解的实例验证了有限元公式和计算机程序.最后,使用这种联合方法分析泰国Chao Phraya河附近海湾中的污染物扩散.