飞秒激光低压N2等离子体特性的实验研究

在低于一个标准大气压的条件下对飞秒激光产生的N₂等离子体光谱进行了实验研究.结果表明, 各种样品气压下的激光N₂等离子体光谱均表现为连续谱和线状谱的叠加.随着样品气压的降低, 连续谱和原子谱线的强度经历了由缓慢增强发展为缓慢降低再到迅速降低的过程, 而正一价离子谱线强度呈现逐步增强的特征.在气压低于0.3 atm (1 atm=101325 Pa)时, 出现了正二价态的离子谱线. 给出了低压N₂等离子体对于飞秒激光传输和能量吸收的物理特性, 并初步讨论了低压等离子体通道特性.这些结果有助于加深了解飞秒激光等离子体的特性和机理, 特别是给出了在实验上测量不同价态离子光谱的条件, 为今后的研究提供了有益的实验依据. 关键词： 飞秒激光 气压 等离子体光谱 激光传输     

吸收谱交迭的双组分混合液的荧光谱校正研究

荧光内滤效应以及样品池中荧光物质对激发光的吸收分布会直接影响荧光谱的强度和谱形,共同制约荧光分析法的应用。使用吸收谱及荧光谱存在交迭的双组分混合溶液,研究一种新的基于物理吸收模型的校正方法,以校正荧光内滤效应及吸收分布对荧光强度的影响。对三聚噻吩和五聚噻吩混合液的光谱研究表明,使用所述校正方法可以达到较为理想的校正效果, 误差小于5%。     

Au/SiO2纳米多层薄膜的制备及其性质表征

利用多靶磁控溅射技术制备了Au/SiO₂纳米颗粒分散氧化物多层复合薄膜.研究了在保持Au单层颗粒膜沉积时间一定时薄膜厚度一定、变化SiO₂的沉积时间及SiO₂的沉积时间一定而改变薄膜厚度时，多层薄膜在薄膜厚度方向的微观结构对吸收光谱的影响.研究结果表明：具有纳米层状结构的Au/SiO₂多层薄膜在560 nm波长附近有明显的表面等离子共振吸收峰，吸收峰的强度随Au颗粒的浓度增加而增强，在Au颗粒浓度相同的情况下，复合薄膜 关键词： 2纳米复合薄膜')" href="#">Au/SiO₂纳米复合薄膜 多靶磁控溅射 吸收光谱 有效介质理论     

Optical Properties of Films of Cu x Ag1−x InSe2 Solid Solutions Obtained by Laser Evaporation

The structure and optical properties of the films of ternary compounds AgInSe₂, CuInSe₂ and Cu _x Ag_1–x InSe₂ solid solutions obtained by pulsed laser evaporation are investigated. It has been established that the films like bulk crystals have the structure of chalcopyrite. By the transmission and reflection spectra near the edge of natural absorption the refractive index and coefficient of optical absorption are calculated and the energies of interband transitions and the crystalline and spinorbit splitting are determined.     

Properties of isolated DNA bases, base pairs and nucleosides examined by laser spectroscopy

The vibronic spectra of laser desorbed and jet cooled guanine (G) adenine (A), and cytosine (C) consist of bands from four, two and two major tautomers respectively, as revealed by UV-UV and IR-UV double resonance spectroscopy. The vibronic spectrum of adenine around 277 nm consists of weak nπ^* and strong ππ^* transitions, based on IR-UV and deuteration experiments. Precise ionization potentials of G and A were determined with 2-color, 2-photon ionization. We also measured vibronic and IR spectra of several base pairs. GC exhibits a HNH ^... OH/NH ^... N/C=O ^... HNH bonding similar to the Watson-Crick GC base pair but with C as enol tautomer. One GG isomer exhibits non-symmetric hydrogen bonding with HNH ^... N/NH ^... N/C=O ^... HNH interactions. A second observed GG isomer has a symmetrical hydrogen bond arrangement with C=O ^... NH/NH ^... O=C bonding. Two CC isomers were observed with symmetrical C=O ^... NH/NH ^... O=C bonding and nonsymmetrical C=O ^... HNH/NH ^... N interaction, respectively. Guanosine (Gs), 2-DeoxyGs und 3-DeoxyGs each exhibit only one isomer in the investigated wavelength range around 290 nm with a strong intramolecular sugar(5-OH) ^... enolguanine(3-N) hydrogen bond. Received 16 June 2002 / Received in final form 15 July 2002 Published online 13 September 2002     

金锥对靶背向超热电子分布的影响

 采用20 TW啁啾脉冲放大的ps激光辐照金锥靶和平面靶,对靶背向产生的超热电子角分布和能谱进行了实验研究。结果表明:金锥对超热电子的产生具有重要的影响。与平面靶情况相比,锥形靶靶背向产生的超热电子数量增加,电子能量为2.0~2.5 MeV的超热电子数目有大幅度增长;锥形靶背向超热电子的空间发散角大于平面靶,这是由于啁啾脉冲放大激光所固有的较高脉冲前沿产生的预等离子体造成的影响。     

Tb0.3Dy0.7(Fe0.9T0.1)1.95合金的结构、自旋重取向和穆斯堡尔谱

系统研究了室温下Tb_0.3Dy_0.7(Fe_0.9T_0.1)_1.95(过渡金属元素T=Mn，Fe，Co，B，Al，Ga)合金中ⅢA族金属和过渡金属元素T替代Fe对结构、自旋重取向和穆斯堡尔谱的影响.结果发现，不同金属T替代Fe，Tb_0.3Dy_0.7(Fe_0.9T_0.1)_1.95，合金具有相同的MgCu₂型立方Laves相结构；Al，Ga替代使Tb_0.3Dy_0.7(Fe_0.9T_0.1)_1.95合金的易磁化方向在{110}面逐渐偏离了立方晶体的主对称轴，即自旋重取向，B，Mn，Co替代未使易磁化轴发生明显转动；Al，Ga元素替代使超精细场H_hf略有下降，B，Mn替代对超精细场H_hf的影响不大，而Co元素替代使超精细场H_hf有较大增加；所有元素替代使同质异能移IS有所增加；B，Al，Ga和Mn替代使四极劈裂Q_s增加，而Co替代使四极劈裂Q_s下降. 关键词： 立方Laves相 自旋重取向 穆斯堡尔谱     

ZnSe: Fe2+中的动态Jahn-Teller效应和远红外光谱的研究

推导了3d^4/3d^6离子基态5D在立方晶体场，自旋－轨道耦合和动态Jahn-Teller效应作用下的哈密顿矩阵，并用对角化该哈密顿矩阵的方法研究了Fe^2+在ZnSe中的远红外光谱，理论计算与实验符合得好，研究表明，在ZnSe:Fe^2+中，比晶体场理论分析多出的分裂谱线是Fe^2+与ZnSe晶格间的动态Jahn-Teller效应引起的，还预测了其它Jahn-Teller效应分裂谱，所推导的哈密顿矩阵对研究3d^4/3d^6离子在立方晶体中的精细光谱，电子顺磁共振谱和动态Jahn-Teller分裂都是有用的。     

Time-resolved fluorescence spectra of a bichromophoric molecule, 2-methyl-1,2,3,4-tetrahydroisoquinoline in various media

Time-resolved fluorescence spectra of a title molecule (with benzene and aliphatic amine parts) in various media, after excitation by several lasers were observed to complement the previous work by conventional spectroscopy [N. Kanamaru, J. Tanaka, J. Phys. Chem. 95 (1991) 6441]. Though complex with many new features, the results were roughly consistent with the previous ones. The significant conclusions are as follows: (1) The emission to be ascribed to the amine (N) part, with more than one component (of nN and aN types) is observed not only for the acetonitrile solution (as previously reported) but also for all the other media. (2) Contrary to the case of a nonpolar hexane solution, both of N fluorescences in the other media reveal unusually long-lived decay components. This can be interpreted by assuming the so-called charge-transfer-to-solvent (CTTS) state that is nonfluorescent and lies just below the fluorescent state. (3) This observation in the protic media can also be taken as another evidence of the peculiar hydrogen bonding between this amine and the protic solvent molecules [N. Kanamaru, J. Tanaka, J. Phys. Chem. 95 (1991) 6441]. (4) Thus, the unexpectedly large quantum yields of N fluorescences in the polar media are now interpreted as arising due to the slow S₁^N→(CTTS)→S₀ internal conversions.     

Vibrational spectra of (NH4)3ZnCl5

IR and Raman spectra of (NH₄)₃ZnCl₅ have been recorded. The observed spectra have been analysed on the basis of the vibrations of ZnCl ₄ ²⁻ and NH ₄ ⁺ ions. The appearance of multiple Raman bands indicates the presence of two different types of ammonium ions. The effect of anisotropic crystalline field over the ZnCl₄ and NH₄ tetrahedra is also discussed. The assignment of internal modes has been verified by the potential energy distribution calculations.