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71.
George Pitsevich Elena Shalamberidze Alex Malevich Valdas Sablinskas Vytautas Balevicius Lars G. M. Pettersson 《Molecular physics》2017,115(20):2605-2613
The frequencies and intensities of vibration–rotational transitions of water molecules in an argon matrix were calculated for temperatures of 6 and 30 K. The rigid asymmetric top approximation was used with available literature values of the effective rotational constants in the ground and excited vibrational states. The calculations were carried out by taking into account the existence of a non-equilibrium population distribution between the rotational levels of ortho- and para-water isomers. It was assumed that the temperature relaxation of the population of rotational levels is independent of the ortho- and para-isomers. Comparison of the results of the theoretical calculations with experimental literature data shows good agreement for the majority of the rotational structure lines for symmetric and antisymmetric stretching vibrations both in the frequency values and in the values of the relative intensities. 相似文献
72.
The dynamic string motion, which displacement is unilaterally constrained by the rigid termination condition of an arbitrary geometry has been simulated and analyzed. The treble strings of a grand piano usually terminate at a capo bar, which is situated above the strings. The apex of a V-shaped section of the capo bar defines the end of the speaking length of the strings. A numerical calculation based on the traveling wave solution is proposed for modeling the nonlinearity inducing interactions between the vibrating string and the contact condition at the point of string termination. It was shown that the lossless string vibrates in two distinct vibration regimes. In the beginning the string starts to interact in a nonlinear fashion with the rigid terminator, and the resulting string motion is aperiodic. Consequently, the spectrum of the string motion depends on the amplitude of string vibrations, and its spectral structure changes continuously with the passage of time. The duration of that vibration regime depends on the geometry of the terminator. After some time of aperiodic vibration, the string vibrations settle in a periodic regime where the resulting spectrum remains constant. 相似文献
73.
We study the nonlinearity for the zigzag graphene nanoribbons (ZGNRs) with zigzag triangular holes (ZTHs). We show that in the presence of an external uniform magnetic field, a two-dimensional f-deformed Dirac oscillator can be used to describe the dynamics of the electrons in the ZGNRs with ZTHs. It is shown for the first time that the magnetic field direction has effect on the chirality of charge carriers in the ZGNRs punched with triangular holes. We also obtain the Landau-level spectrum in the weak and strong magnetic field regimes. Additionally, we compare Landau-level spectrum of this graphene-based device in the f-deformed scenario and original one. Our results provide a general viewpoint for the development of the zigzag graphene nanoribbons. 相似文献
74.
Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and wide angle X-ray diffraction (WAXD) were employed to study the microstructure of self-reinforced high-density polyethylene (HDPE) prepared by conventional injection molding (CIM) and a low frequency vibration-assisted injection molding (VAIM). SEM micrographs following permanganic etching showed the self-reinforcement of HDPE is mainly due to the existence of shish-kebab morphology within the core region for VAIM-processed HDPE samples. Pronounced molecular alignment was identified by the WAXD data. An approximate 9% increase in the crystallinity was confirmed by DSC. Both preferred molecular orientation and increased crystallinity serve to yield stronger VAIM-processed injection moldings. 相似文献
75.
Hao Zhang Dr. Xu Liu Ting-Ting Lu Peng Lv Prof. Wen-Yong Lai 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(15):3909-3917
A series of monodisperse six-armed conjugated starbursts ( Tr1F , Tr2F , and Tr3F ) containing a truxene core and multibranched oligofluorene bridges capped with diphenylamine (DPA) units has been designed, synthesized, and investigated as robust gain media for organic semiconductor lasers (OSLs). The influence of electron-rich DPA end groups on their optoelectronic characteristics has been discussed at length. DPA cappers effectively raise HOMO levels of the starbursts, thus enhancing the hole injection and transport ability. Solution-processed electroluminescence devices based on the resulting six-armed starbursts exhibited efficient deep-blue electroluminescence with clear reduced turn-on voltages (3.2–3.5 V). Moreover, the resulting six-armed molecules showed stabilized electroluminescence and amplified spontaneous emission with low thresholds (27.4–63.9 nJ pulse−1), high net gain coefficients (80.1–101.3 cm−1), and small optical loss (2.6–4.4 cm−1). Distributed feedback OSLs made from Tr3F exhibited a low lasing threshold of 0.31 kW cm−2 (at 465 nm). The results suggest that the construction of truxene-centered six-armed conjugated starbursts with the incorporation of DPA units can effectively enhance EL properties by precisely regulating the HOMO energy levels, and further optimizing their optical gain properties. 相似文献
76.
77.
The secondary radiation after resonant excitation of F center and its linear polarization P correlated to the polarization of resonant light have been measured for five alkali halides at low temperatures. In KC1, the spectrum of P over the whole Stokes region is divided into three successive regions, the depolarization range at the one-phonon Raman scattering, the near plateau range, and the depolarization range down to vanishing. The former two have common relevance to resonant energy and symmetries of coupled phonons. These relevances are interpreted adopting a configuration coordinate model for 2s- and 2p-like excited states. 相似文献
78.
We studied deformation-induced defects in semi-insulating CdTe and CdZnTe by infrared photoluminescence (PL), contact less photoconductivity and resistivity. Plastic deformation increased the concentrations of grown-in defects, namely, those of an important midgap level EC−0.74 eV in CdTe and Cd1−xZnxTe (x<0.1), the materials of choice in today’s X-ray and gamma ray detector technology. We confirmed the direct correlation between Y-emission and the dislocation density in both compounds. The Y-band intensified near an indenter deformation or near a scribing line, but was barely visible in low-dislocation areas (etch pit density <2×105 cm−2). Our results correlate with recent findings that dislocation-induced defects and their clusters degrade charge collection in radiation detectors. Photoluminescence of midgap levels can serve as a tool to identify areas of degraded performance in semi insulated CdTe and CdZnTe crystals for radiation detectors. 相似文献
79.
《合成通讯》2013,43(11):2117-2126
Abstract Solvent‐free reactions of C60 and C70 with diethyl bromomalonate in the presence of various inorganic bases were investigated under the high‐speed vibration milling (HSVM) conditions, and are shown to give methanofullerenes 1 and 2 in good to excellent yields based on consumed fullerenes. Several weak inorganic bases were found to be quite effective in promoting the solvent‐free mechanochemical Bingel reactions of C60 and C70 under the HSVM conditions. Among the studied bases, sodium acetate gave the highest yield of monoadducts, while potassium carbonate afforded a considerable amount of bisadducts for both C60 and C70. 相似文献
80.
Andreas Braeuer Robert Fabian Hankel Markus Konstantin Mehnert Julian Jonathan Schuster Stefan Will 《Journal of Raman spectroscopy : JRS》2015,46(11):1145-1149
We report a Raman technique applicable for the in situ analysis of the development of hydrogen bonds in the liquid water‐rich phase just before the onset of gas hydrate formation. Herewith, the phase transition as well as the working principle of hydrate formation inhibitors and promoters can be analyzed. © 2015 The Authors. Journal of Raman Spectroscopy published by John Wiley & Sons Ltd. 相似文献