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31.
Alp E. E. Sturhahn W. Toellner T. S. Zhao J. Hu M. Brown D. E. 《Hyperfine Interactions》2002,144(1-4):3-20
Nuclear resonant inelastic X-ray scattering of synchrotron radiation is being applied to ever widening areas ranging from
geophysics to biophysics and materials science. Since its first demonstration in 1995 using the 57Fe resonance, the technique has now been applied to materials containing 83Kr, 151Eu, 119Sn, and 161Dy isotopes. The energy resolution has been reduced to under a millielectronvolt. This, in turn, has enabled new types of
measurements like Debye velocity of sound, as well as the study of origins of non-Debye behavior in presence of other low-energy
excitations. The effect of atomic disorder on phonon density of states has been studied in detail. The flux increase due to
the improved X-ray sources, crystal monochromators, and time-resolved detectors has been exploited for reducing sample sizes
to nano-gram levels, or using samples with dilute resonant nuclei like myoglobin, or even monolayers. Incorporation of micro-focusing
optics to the existing experimental setup enables experiments under high pressure using diamond-anvil cells. In this article,
we will review these developments.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
32.
P. Paasche T. Valenzuela D. Biswas C. Angelescu G. Werth 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(3):295-300
We have examined experimentally the motional spectrum of an electron cloud confined in a Penning trap. When the axial oscillation
is excited by a radio frequency field the resonance exhibits a double structure. Both components depend differently on the
number of trapped electrons and have different shape and width. We conclude that one of them corresponds to the excitation
of the individual electrons while the other is the center-of-mass mode of the cloud. The threshold behaviour of the center-of-mass
resonance suggests that it is a parametric instability of a Mathieu type equation of motion.
Received 11 July 2001 and Received in final form 12 November 2001 相似文献
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35.
Mark E. Filipkowski Edwin E. Hach III Michael Offenbacker 《Journal of magnetism and magnetic materials》2006
We show, via a straightforward calculation, that it is feasible to detect nuclear spin echoes in a ferromagnetic thin film by electrical means. The detection scheme is based on the deflection of the electronic magnetization when the nuclear magnetization reforms during an echo. This deflection is observed as a time-dependent magnetoresistive signal. 相似文献
36.
用硼氢化钠作还原剂,制备出两种相对稳定的含银纳米颗粒的水溶胶,用透射电镜(TEM)和光学吸收谱对这些颗粒进行了表征.当被还原的银离子较少时,所形成的银纳米颗粒较小,吸收峰呈现二极等离子体共振吸收峰.当被还原的银离子较多时,银纳米颗粒尺寸变大,并出现二极和四极共振吸收峰.在Ag纳米颗粒形成后,对其溶液稀释,发现其峰形保持不变,而峰位会出现红移,最大红移量可达到10 nm.透射电镜研究表明,低浓度溶胶中的Ag纳米颗粒尺寸较为均匀,平均直径12 nm.高浓度溶胶中的纳米颗粒尺寸呈双尺寸分布特点,少量颗粒直径小于14 nm,大部分颗粒直径大于20 nm. 相似文献
37.
《Magnetic resonance in chemistry : MRC》2003,41(8):585-588
A novel, radical responsive MRI contrast agent based on a gadolinium chelate conjugated to a liposome through a disulfide linker was synthesized, with the aim of pursuing the in vivo mapping of radicals. The liposome was prepared by incorporating a thiol‐activated phospholipid, which was subsequently reacted with a gadolinium chelate containing a free thiol group. The long reorientational motion of the supramolecular adduct endows the paramagnetic agent with a relaxivity significantly higher than that of the free complex. The disulfide bond represents a radical‐sensitive moiety and a large decrease in contrast efficacy (T1 relaxivity) is shown upon its cleavage. A preliminary assessment of the system was made by means of in vitro gamma‐irradiation and thiol–disulfide bond exchange with dithiothreitol. Both methods showed a clear dose‐dependent decrease in T1‐relaxivity. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
38.
Electron paramagnetic resonance (EPR) investigations has been carried out on the new family of molybdenum doped vanadium sesquioxides (V1−xMox)2−δO3. The oxidation effects were monitored from the rate of paramagnetic V4+ created when the sample is exposed to the air. The effects of the oxidation time, sample temperature, and annealing at 1000 °C under a diluted hydrogen atmosphere on the EPR signal features are analyzed. The V4+ concentration in the oxidized samples is determined and the relaxation effects driven by the conduction electrons are pointed out from the thermal behaviour of the EPR line features. EPR spectra of all the oxidized samples also reveal a small ferromagnetic contribution strongly correlated with the V4+ content. 相似文献
39.
Infrared and nuclear magnetic resonance (NMR) spectroscopies have been applied for quantitative comparison on unsaturated bonds in tetrafluoroethylene (TFE)-propylene (P)-vinylidene fluoride (VdF) terpolymers. These spectroscopies have led to consistent results while they are based on completely different principles. It is shown that the absolute concentration can be evaluated from NMR measurements. The behavior of unsaturation has been discussed in terms of after-treatment such as wet and dry treatments. The result obtained here can give the important information to improve the performance of fluoroelastomer based on TFE-P-VdF terpolymers. 相似文献
40.