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排序方式: 共有857条查询结果,搜索用时 31 毫秒
101.
Spectroscopic investigations and luminescence spectra of Nd and Dy doped different phosphate glasses
Spectral properties of Nd3+ and Dy3+ ions in different phosphate glasses were studied and several spectroscopic parameters were reported. Covalency of rare-earth-oxygen bond was studied in these phosphate glass matrices with the variation of modifier in host glass matrix. Using Judd-Ofelt intensity parameters (Ω2, Ω4 and Ω6), radiative transition probabilities (A) and radiative lifetimes (τR) of certain excited states of Nd3+ and Dy3+ ions are estimated in these glass matrices. From the magnitudes of branching ratios (βR) and integrated absorption cross-sections (Σ), certain transitions of both the ions are identified for laser excitation. From the emission spectra, peak stimulated emission cross-sections (σP) are evaluated for the emission transitions observed in all these phosphate glass matrices for both Nd3+ and Dy3+ ions. 相似文献
102.
Fengshan Liu Gregory J. Smallwood 《Journal of Quantitative Spectroscopy & Radiative Transfer》2010,111(2):302-550
This study concerns the effect of particle aggregation on laser heating rate of soot aggregates in laser-induced incandescence. Three aggregate absorption models were investigated: the Rayleigh-Debye-Gans approximation, the electrostatics approximation, and the numerically exact generalized multi-sphere Mie-solution method. Fractal aggregates containing 5-893 primary particles of 30 nm in diameter were generated numerically using a combined particle-cluster and cluster-cluster aggregation algorithm with specific fractal parameters typical of soot. The primary particle size parameters considered are 0.089, 0.177, and 0.354. The Rayleigh-Debye-Gans approximation neglects the effect of particle aggregation on absorption; so it underestimates the aggregate absorption cross-section area by approximately 10%, depending on the aggregate size and primary particle size parameter. The electrostatics approximation is somewhat better than the Rayleigh-Debye-Gans approximation, but cannot account for the effect of primary particle size parameter. The aggregate absorption submodel affects the calculated soot temperature in laser-induced incandescence mainly in the low laser fluence regime. At high laser fluences, the effect diminishes due to the enhanced importance of soot sublimation cooling and neglect of aggregation effect in the sublimation in the present numerical model of laser-induced incandescence. 相似文献
103.
Abdulaziz K. Alsharidi Ashfaq A. Khan John J. Shepherd Andrew J. Stacey 《Mathematical Methods in the Applied Sciences》2020,43(9):5729-5743
We construct the slowly varying limiting state solutions to a nonlinear dynamical system for anaerobic digestion with Monod-based kinetics involving slowly varying model parameters arising from slow environmental variation. The advantage of these approximate solutions over numerical solutions is their applicability to a wide range of parameter values. We use these limiting state solutions to develop analytic approximations to the full nonlinear system by applying a multiscaling technique. The approximate solutions are shown to compare favorably with numerical solutions. 相似文献
104.
105.
106.
Katerina Saneva 《Journal of Mathematical Analysis and Applications》2010,370(2):543-554
We develop a distribution wavelet expansion theory for the space of highly time-frequency localized test functions over the real line S0(R)⊂S(R) and its dual space , namely, the quotient of the space of tempered distributions modulo polynomials. We prove that the wavelet expansions of tempered distributions converge in . A characterization of boundedness and convergence in is obtained in terms of wavelet coefficients. Our results are then applied to study local and non-local asymptotic properties of Schwartz distributions via wavelet expansions. We provide Abelian and Tauberian type results relating the asymptotic behavior of tempered distributions with the asymptotics of wavelet coefficients. 相似文献
107.
In this paper we introduce the concepts of exponential exponents of discrete linear time varying systems. It is shown that these exponents describe the possible changes in the Lyapunov exponents under perturbation decreasing at infinity at exponential rate. Finally we present formulas for the exponential exponents in terms of the transition matrix of the system. 相似文献
108.
设(Xni:1≤i≤n,n≥1)为行间ND阵列,g(x)是R^+上指数为α的正则变化函数,{αni:1≤i≤n,n≥1}为满足条件max1≤i≤n|ani|=0((g(n))^-1)的实数阵列.本文采用截尾的方法,得到了使ND随机变量阵列加权乘积和完全收敛的条件,并推广了以前学者的结论. 相似文献
109.
本文测量了全反式β胡萝卜素在二甲基亚砜中81–25 ℃ 范围的紫外–可见吸收和拉曼光谱. 结果表明, 随温度降低, 紫外–可见吸收光谱、拉曼光谱都发生红移, 拉曼光谱线型变窄, 散射截面增加这些现象的发生是由于随温度降低, β胡萝卜素分子的热无序降低、分子结构有序性增加、π电子离域扩展, 有效共轭长度增加, 分子的电子能隙变窄. 另外, 随着温度的降低, 溶剂密度增加, 由Lorentz-Lorenz 关系得知相伴的折射率增加, 从而引起吸收光谱的红移. CC键键长增加, 使CC 键拉曼光谱红移; 振动弛豫时间变长, 各CC 键之间的键长差减小, 线宽变窄; 但由于声子, π电子耦合加强使CC键拉曼线型不对称程度增加, 低频端"肩"扩展, CC键的弱阻尼相干振动增加, 使拉曼散射截面增加.
关键词:
β胡萝卜素
分子结构有序
红移
拉曼散射截面 相似文献
110.
The stability of fullerenes (C60 and C70) under swift heavy ion irradiation is investigated. C60 and C70 thin films were irradiated with 120 MeV Ag ions at fluences from 1×1012 to 3×1013 ions/cm2. The damage cross-section and radius of damaged cylindrical zone were found to be higher for C60 than C70 as evaluated by Raman spectroscopy, which shows that the C70 molecule is more stable under energetic ion impact. The higher damage cross-section of the C60 molecule compared with that of the C70 molecule is explained on the basis of thermal conductivity in the framework of the thermal spike model. The surface morphology of pristine C60 and C70 films is studied by atomic force microscopy. UV-visible absorption studies revealed that band gap for C60 and C70 fullerenes thin films decreases with increasing ion fluence. Resistivity of C60 and C70 thin films decreases with increasing ion fluence but the decrease is faster for C60 than C70, indicating higher damage in C60. Irradiation at a fluence of 3×1013 ions/cm2 results in complete damage of fullerenes (C60 and C70) into amorphous carbon. 相似文献