Study on the photodegradation and microbiological degradation of pirimicarb insecticide by using liquid chromatography coupled with ion-trap mass spectrometry

The intermediates of photodegradation and microbial degradation of pirimicarb insecticide were investigated by liquid chromatography coupled with ion-trap mass spectrometry (LC–IT-MS). Different intermediates were detected in the photodegradation and microbial degradation of pirimicarb. In the photodegradation of pirimicarb in aqueous solution 2-dimethylamino-5,6-dimethyl-4-hydroxypyrimidine (MW = 167), 2-methylamino-5,6-dimethylpyrimidin-4-yl-dimethylcarbamate (MW = 224) and 2-formylamino-5,6-dimethylpyrimidin-4-yl-dimethylcarbamate (MW = 252) were the main products. It was found that 2-dimethylamino-5,6-dimethyl-4-hydroxypyrimidine (MW = 167) was the major product in the microbial degradation of pirimicarb in soil.     

Markov-modulated风险模型中盈余过程零点数的分布

基于保险公司在首次破产后仍能继续运转的情形,讨论并得到了Markovmodulated风险模型中盈余过程零点数的分布.     

Banach空间的Chung-Teicher型大数律

设{Xn，n≥1}是实可分Banach空间独立随机变量，讨论了在弱大数律的假设下使得Chung-Teicher型强大数律也成立，即bn^-1｜｜∑k=1^n（Xk-EXkI（｜｜Xk｜｜≤bk））｜｜→^p0当且仅当bn^-1｜｜∑中k=1^n（Xk-EXkI（｜｜Xk｜｜≤bk））｜｜→^a.s.0.     

Application of nanodiamonds in human body fluid analysis by matrix-assisted laser desorption/ionization mass spectrometry

Direct mass spectrometric analysis of complex biological samples is very important and challenging. In this paper, nanodiamonds have been successfully used in matrix-assisted laser desorption/ionization mass spectrometric analysis of human serum and urine. As a practical tool and platform, it can be widely used in the field of humoral proteomics, and it plays a very promising role in clinical diagnosis, including identification of novel disease-associated biomarkers.     

喷水室典型空气处理过程中空气流速的实验研究

针对纺织厂空调系统的核心-喷水室,研究喷水室内处理空气的冷却减湿和等焓加湿两个典型热湿交换过程。提出Re准数对传热传质有显著作用,而Re数的大小取决于流体速度。通过实验研究当空气流速从3m/s提高到5m/s时对喷水室热湿交换性能的影响,从而确定空气流动速度因素对两个热湿交换效率的影响趋势。根据拟合的数学曲线,总结出当空气的流动速度提高后,热湿交换效率相应提高。从而推动高速喷水室在实际工程中的应用。     

Robust and accurate inference for generalized linear models

In the framework of generalized linear models, the nonrobustness of classical estimators and tests for the parameters is a well known problem, and alternative methods have been proposed in the literature. These methods are robust and can cope with deviations from the assumed distribution. However, they are based on first order asymptotic theory, and their accuracy in moderate to small samples is still an open question. In this paper, we propose a test statistic which combines robustness and good accuracy for moderate to small sample sizes. We combine results from Cantoni and Ronchetti [E. Cantoni, E. Ronchetti, Robust inference for generalized linear models, Journal of the American Statistical Association 96 (2001) 1022–1030] and Robinson, Ronchetti and Young [J. Robinson, E. Ronchetti, G.A. Young, Saddlepoint approximations and tests based on multivariate M-estimators, The Annals of Statistics 31 (2003) 1154–1169] to obtain a robust test statistic for hypothesis testing and variable selection, which is asymptotically χ²-distributed as the three classical tests but with a relative error of order O(n⁻¹). This leads to reliable inference in the presence of small deviations from the assumed model distribution, and to accurate testing and variable selection, even in moderate to small samples.     

On an initial‐boundary value problem for a wide‐angle parabolic equation in a waveguide with a variable bottom

We consider the third‐order Claerbout‐type wide‐angle parabolic equation (PE) of underwater acoustics in a cylindrically symmetric medium consisting of water over a soft bottom B of range‐dependent topography. There is strong indication that the initial‐boundary value problem for this equation with just a homogeneous Dirichlet boundary condition posed on B may not be well‐posed, for example when B is downsloping. We impose, in addition to the above, another homogeneous, second‐order boundary condition, derived by assuming that the standard (narrow‐angle) PE holds on B, and establish a priori H² estimates for the solution of the resulting initial‐boundary value problem for any bottom topography. After a change of the depth variable that makes B horizontal, we discretize the transformed problem by a second‐order accurate finite difference scheme and show, in the case of upsloping and downsloping wedge‐type domains, that the new model gives stable and accurate results. We also present an alternative set of boundary conditions that make the problem exactly energy conserving; one of these conditions may be viewed as a generalization of the Abrahamsson–Kreiss boundary condition in the wide‐angle case. Copyright © 2008 John Wiley & Sons, Ltd.     

Investigation of critical influential speed for moving mass problems on beams

A traveling mass due to its mass inertia has significant effects on the dynamic response of the structures. According to recent developments in structural materials and constructional technologies, the structures are likely to be affected by sudden changes of masses and substructure elements, in which the inertia effect of a moving mass is not negligible. The transverse inertia effects have been a topic of interest in bridge dynamics, design of railway tracks, guide way systems and other engineering applications such as modern high-speed precision machinery process. In this study an analytical–numerical method is presented which can be used to determine the dynamic response of beams carrying a moving mass, with various boundary conditions. It has been shown that the Coriolis acceleration, associated with the moving mass as it traverses along the vibrating beam shall be considered as well. Influences regarding the speed of the moving mass on the dynamic response of beams with various boundary conditions were also investigated. Results illustrated that the speed of a moving mass has direct influence on the entire structural dynamic response, depending on its boundary conditions. Critical influential speeds in the moving mass problems were introduced and obtained in numerical examples for various BC’s.     

Determination of As,Cd, Pb,and Hg in urine using inductively coupled plasma mass spectrometry with the direct injection high efficiency nebulizer

The application of the large-bore direct injection high efficiency nebulizer (LB-DIHEN) for the determination of arsenic (As), cadmium (Cd), lead (Pb), and mercury (Hg) in urine by inductively coupled plasma mass spectrometry (ICP-MS) is described. The LB-DIHEN is compared with the standard method using a concentric pneumatic nebulizer and cyclonic spray chamber. In addition to the toxicological significance of As, Cd, Pb, and Hg, these elements represent a cross-section of analytical issues including spectral interferences (e.g., ⁴⁰Ar³⁵Cl⁺ on ⁷⁵As⁺ and ⁹⁸Mo¹⁶O⁺ on ¹¹⁴Cd⁺) and memory effects (Hg). In this study, the low sample consumption of the LB-DIHEN is used to reduce the volume of urine needed for analysis, and to reduce the volume of final diluted sample required for analysis. Eliminating the spray chamber and reducing the dead volume of the nebulizer reduces memory effects, especially for analytes such as Hg. The Dynamic Reaction Cell (DRC) is used in this study to attenuate the background level of ArCl⁺ in spite of the increase in the solvent load and, in turn, the urine matrix (chloride) delivered to the plasma by the LB-DIHEN. This is the first report on coupling the LB-DIHEN to a standard autosampler for unattended sample analysis. The robustness of direct injection nebulization for routine analysis and the issues associated with automation of the sample introduction process are discussed. Although the figures of merit (sensitivity, limit of detection, and precision) determined for both nebulizers are slightly poorer for the LB-DIHEN than for the concentric pneumatic nebulizer, there is not a clinically significant difference between the results for both sample introduction systems. The accuracy of results is assessed using archived urine materials that are circulated by several different proficiency testing (PT) programs and external quality assessment schemes (EQAS). Results obtained using the LB-DIHEN were within the acceptable range established by a consensus pool generated using different methods, none of which are likely to be using direct injection nebulization. Internal quality control sample results obtained using the LB-DIHEN were compared to those obtained using the conventional nebulizer. Reported results were similar for both nebulizers. Thus, these results show that the LB-DIHEN is certainly feasible for the analysis of urine specimens.