Micromachined Uncooled IR Bolometer Linear Array Using VO2 Thin Films

Mixed vanadium oxide thin films, as VO₂ for the main composition are materials for uncooled microbolometer due to their high temperature coefficient of resistance (TCR) at room temperature. This paper describes the design and fabrication of 8-element linear array IR uncooled microbolometers using the films and micromachining technology. The characteristics of the array is investigated in the spectral region of 8–12 m. The fabricated detectors exhibit responsivity of up to 10 KV/W, typical detectivity of 1.89×10⁸ cmHz^1/2/W, and thermal time constant of 11 ms, at 296 K and at a frequency of 30 Hz. Furthermore, The uncorrected response uniformity of the linear array bolometers is less than 20%.     

From Surface‐Inspired Oxovanadium Silsesquioxane Models to Active Catalysts for the Oxidation of Alcohols with O2—The Cinnamic Acid/Metavanadate System

Silsesquioxane dioxovanadate(V) complexes were investigated with respect to their potential as a catalyst for the oxidative dehydrogenation of alcohols with O₂ as an oxidant. The turnover frequencies determined were comparatively low, but during the oxidation of cinnamic alcohol an increase in activity was observed in the course of the process, which was inspected more closely. It turned out that during the oxidation of cinnamic alcohol, not only was the aldehyde formed but also cinnamic acid, which in turn reacts with the silsesquioxane complex employed to give NBu₄[O₂V(O₂CC₂H₂Ph)₂], which can also be obtained from NBu₄VO₃ and cinnamic acid and represents a far more active catalyst, not only for cinnamic alcohol but also for other activated alcohols and hydrocarbons. The rate‐determining step of the conversion corresponds to an hydrogen‐atom abstraction from the C? H units, as shown by the determination of the kinetic isotope effect in case of 9‐hydroxyfluorene, and the reoxidation of the reduced catalyst proceeds via a peroxo intermediate, which is also capable of oxidizing one alcohol equivalent. Furthermore the influence of the organic residues at the carboxylate ligands on the catalyst performance was investigated, which showed that the activity increases with decreasing pK_s value. Moreover, it was found that during the oxidation the catalyst slowly decomposes, but can be regenerated by addition of excessive carboxylic acid.     

氢离子辐照纯钒中形成的位错环

钒合金作为聚变堆候选材料, 其辐照损伤行为一直是关注的重点. 研究辐照时形成的位错环的性质, 其意义在于揭示纯钒中辐照空洞的长大机理. 这种机理表现为不同类型位错环对点缺陷吸收的偏压不同, 从而影响金属的辐照肿胀. 本文利用加速器对纯钒薄膜样品进行氢离子辐照, 然后, 利用透射电镜的inside-outside方法分析氢离子辐照所形成的位错环的类型. 结果表明, 在氢离子辐照纯钒中没有发现柏氏矢量b=<110>的位错环, 只有柏氏矢量b=1/2<111>和b=<110>的位错环, 这两种位错环的惯性面处于{110}-{112}之间. 能确定性质的位错环全部为间隙型位错环, 未发现空位型位错环.     

6-甲基-4-羟基-喹啉酸盐羟基钒(Ⅴ)(英)

The central V atom in bis[6-methyl-4-hydroxy-3-quinolinecarboxylate] mono(oxo)mono-hydroxy-vanadium(Ⅴ) (1), synthesized by the hydrothermal treatment of ethyl 6-methyl-4-hydroxy-3-quinolinecarboxylate and V₂O₅, has a distorted octahedral coordination geometry formed by six oxygen atoms from two oxygen atom of two hydroxy groups and two oxygen atoms of two carboxylate groups as well as one oxo group and hydroxy group. CCDC: 285592.     

6-甲基-4-羟基-喹啉酸盐羟基钒(V)(英文)

V anadium髨coordination com pound1is achievedby the hydrotherm al reaction of V2O5and ethyl6-m ethyl-4-hydroxy-3-quinolinecarboxylate(em hq)w ithwater as solvent.X-ray single crystal diffraction studyof com pound1(Fig.1)shows that com pound1crystal-lizes …     

Synthesis and reactivity of metal-containing monomers. 21. Synthesis of TiCl4 and VCl4 complexes with azobisisobutyronitrile and studies of their thermal decomposition

Complexes of azobisisobutyronitrile (AIBN) with titanium tetrachloride and vanadium tetrachloride have been synthesized and characterized. It was demonstrated that Ti(IV) and V(IV) form equimolar complexes with AIBN, with nitrile ligands located incis positions in the coordination spheres of metal atoms. Kinetics of thermal decomposition of free and complexed AIBN were studied and compared. The gas evolution rate was measured in the presence of tetrabutoxytitanium, which does not react with AIBN. It was demonstrated that complexing leads to a marked increase of the rate constant of AIBN thermal decomposition.Institute of Chemical Physics, Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 8, pp. 1746–1754, August, 1992.     

商洛钒尾矿烧制轻质高强陶粒的研究

采用80wt;商洛钒尾矿为主要原料,加入钾长石、粘土为辅助原料,以SiC为发泡剂,制备性能优异的轻质高强陶瓷颗粒.采用单因素变量分析法研究钒尾矿含量、SiC添加量、烧成温度和保温时间对陶粒结构及性能的影响.研究结果表明:随着发泡剂SiC含量的增加、烧成温度的提高和保温时间的延长,陶粒的堆积密度和筒压强度均降低,吸水率均升高.最终加入2wt;SiC为发泡剂,在1125℃下保温30min制得堆积密度631kg/m3,筒压强度9.1MPa,吸水率3.1;的轻质高强陶瓷颗粒.     

钒的一个特别灵敏指示反应

本文研究了钒（V）在乙酸介质中催化溴酸钾氧化钙试剂羧酸钠盐的褪色反应。本方法的灵敏度为2.5×101?g/ml,与同类方法相比为最高,测定范围为0～4ngV/25ml。本法已用于水样中超痕量钒测定。     

介孔分子筛V-MCM-41的水热法制备与合成机理

 以十六烷基三甲基溴化铵为模板剂,廉价的工业级高模数比(3.3)的硅酸钠为硅源,通过水热法合成了V-MCM-41介孔分子筛. 考察了合成条件对产物织构的影响,并采用低温氮吸附法分析探讨了介孔分子筛V-MCM-41的合成机理. 结果表明,模板剂用量、 pH值、加料方式、晶化温度、晶化时间、陈化时间和焙烧气氛等合成条件对介孔分子筛的制备均有影响,其中晶化温度、 pH值和模板剂用量的影响最为明显. X射线衍射谱表明合成的介孔分子筛具有六方晶体结构. 红外光谱和紫外可见光谱表明V进入了介孔分子筛的骨架结构.