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171.
The transformation mechanism of hexagonal delta phase from the disordered bcc gamma phase has not been reported before in the Zr-rich U–Zr alloy system. With the help of X-ray diffraction, transmission electron microscopy (TEM) and high-resolution TEM analyses it was shown that the gamma to delta conversion takes place by the lattice collapse mechanism of omega transformation. It was also ascertained that a higher aging temperature or time promotes the growth of all four variants of the delta phase within a parent gamma grain. In addition, ab initio electronic structure calculations showed that the bcc to hexagonal transformation, involving partial ordering of the parent bcc phase followed by (111) plane collapse, is energetically favorable. 相似文献
172.
173.
吴伟雄 《应用数学和力学(英文版)》1994,(8)
FINITEELEMENTANALYSISFORTHEUNSTEADYNEARSHORECIRCULATIONDUETOWAVE-CURRENTINTER-ACTION(I)——NUMERICALMODELWuWei-xiong(吴伟雄)(Tongj... 相似文献
174.
Wu Wei-xiong 《应用数学和力学(英文版)》1994,15(8):749-754
In this paper, a numerical model for predicting the unsteady nearshore circulation due to wave-current interaction was proposed.
In addition to the traditional continuity, momentum and energy equations, the dispersion and refraction relations were included
in the governing equations. Moreover, the effects of lateral shears, wind, radiation and bottom stresses were analysed in
the governing equations. Therefore, we expect that this model may more completely and exactly reflect the law of wave-current
interaction.
In part (II) we will adopt the selective lumping two-step explicit finite element method to solve the model, and some examples
will be presented. 相似文献
175.
M.A. Bees 《Applied Scientific Research》1997,59(2-3):141-158
A deterministic mechanism for the production of plankton patches within a typical medium scale oceanic structure is proposed and investigated. By direct numerical simulation of a simple model of Langmuir circulation we quantify the effects of unsteady flows on planktonic communities and demonstrate their importance. Two qualitatively different zones within the flow are identified: chaotic regions that help to spread plankton and locally coherent regions, that do not mix with the chaotic regions and which persist for long periods of time. The relative importance of these regions to both phytoplankton and zooplankton is investigated, taking into account variations in plankton buoyancy. In particular, species-specific retention zone structure is discussed in relation to variations in environmental forcing. 相似文献
176.
本文介绍了床面固体颗粒随水流绕过圆柱体时,将在圆柱周围的床面上形成一个无粒子运动区的试验现象。水槽试验结果表明,当固体颗粒的粒径减小时,无粒子区的范围将增大;无粒子区的范围随圆柱直径的增大而增大;水流条件的变化直接影响着床面固体颗粒的运动情况,同无粒子区的形成、消失及范围大小有密切的关系。根据试验资料,结合量纲分析,建立了无粒子区的无量纲经验关系式 相似文献
177.
In developing a method for possible low level isotopic enrichment, which uses to advantage the equilibrium isotope effect
observed during U(1V)-U(VI) electron exchange reaction in sulphate solutions, details of a solvent extraction process involving
high concentration of a mixture of U(IV) and U(VI) and at low acid concentrations, are described. The extraction behaviour
of uranium under these conditions is discussed. During the extraction with amines, U(IV) tended to get oxidised in sulphate
solutions. 相似文献
178.
179.
Mary E. Garner Dr. Stephan Hohloch Prof. Dr. Laurent Maron Prof. Dr. John Arnold 《Angewandte Chemie (International ed. in English)》2016,55(44):13789-13792
Actinide complexes demonstrate unparalleled reactivity towards small molecules. However, utilizing these powerful transformations in a predictable and deliberate manner remains challenging. Therefore, developing actinide systems that not only perform noteworthy chemistry but also demonstrate controllable reactivity is a key goal. We describe a bis(NHC)borate thorium‐bpy complex ( 1 ) that is capable of reductively cleaving the R?NC bond in a series of organic isocyanides. In contrast to most actinide‐mediated bond activations, the dealkylation event mediated by 1 is remarkably general and yields very well‐defined products that assist in mechanistic elucidation. Synthesis of the rearranged but‐3‐enyl product from the reaction of 1 and cyclopropylmethyl isocyanide supports the notion of a radical‐based mechanism. 相似文献
180.