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101.
102.
M. Maiani W. J. M. de Kruijf W. Ambrosini 《International Journal of Heat and Fluid Flow》2003,24(6):853-863
In this paper, an extension of previous analyses of natural circulation in a simple single-phase loop is presented. Assuming more general correlations for the friction factor and the heat transfer coefficient, an analytical model describing the system is obtained and a parametric representation of its dynamic behaviour is achieved. On this basis, stability maps can be drawn. A preliminary validation of the analytical model has been carried out by using an independent program developed for the analysis of stability in natural circulation loops. The aim of the present work is to provide a simple analytical tool devoted to the stability analysis of a reference single-phase loop. This model can be applied in a relatively wide range of conditions and regimes to provide benchmark solutions for thermal-hydraulic codes and related nodalisations. 相似文献
103.
A rectangular loop (thermosyphon) was used to measure the average heat transfer coefficients for water at atmospheric pressure under natural circulation conditions. A twenty-one tube bundle with tubes 1.65 m long and 9.55 mm in diameter, and a pitch-to-diameter ratio of 1.33, was used as a test heat exchanger in one of the vertical legs of the loop. A natural circulation flow in the loop developed due to buoyancy differences of the fluid in its two vertical legs. Flow visualization experiments were performed to determine the flow regimes associated with natural circulation flow longitudinal to a tube bundle. Empirical correlations for the average Nusselt number have been developed and are reported. Grid spacers arranged on tube bundles were shown to enhance heat transfer, especially for laminar flow, without any noticeable increase in pressure drop. 相似文献
104.
Kundan Tayade Amanpreet Kaur Sandesh Tetgure G. Krishana Chaitanya Narinder Singh Anil Kuwar 《Analytica chimica acta》2014
The (13E,19E)-N1′,N3′-bis[4-(diethylamino)-2-hydroxybenzylidene]malonohydrazide (L) has been developed for the detection of Th4+ ions using dual channel signalling system. The UV–vis absorbance and fluorescence spectroscopic data revealed the formation of L–Th4+ complex in 1:1 equilibrium. The density functional theory (DFT) also confirms the optimum binding cavity for the recognition of metal ion. The binding constant computed from different mathematical models for an assembly of L–Th4+. The detection limit of L for Th4+ recognition is to a concentration down to 0.1 μM (0.023 μg g−1). The present sensing system is also successfully applied for the detection of Th4+ ion present in soil near nuclear atomic plants. 相似文献
105.
Gardner BM Patel D Cornish AD McMaster J Lewis W Blake AJ Liddle ST 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(40):11266-11273
Four new uranium-ruthenium complexes, [(Tren(TMS))URu(η(5)-C(5)H(5))(CO)(2)] (9), [(Tren(DMSB))URu(η(5)-C(5)H(5))(CO)(2)] (10), [(Ts(Tolyl))(THF)URu(η(5)-C(5)H(5))(CO)(2)] (11), and [(Ts(Xylyl))(THF)URu(η(5)-C(5)H(5))(CO)(2)] (12) [Tren(TMS)=N(CH(2)CH(2)NSiMe(3))(3); Tren(DMSB)=N(CH(2)CH(2)NSiMe(2)tBu)(3)]; Ts(Tolyl)=HC(SiMe(2)NC(6)H(4)-4-Me)(3); Ts(Xylyl)=HC(SiMe(2)NC(6)H(3)-3,5-Me(2))(3)], were prepared by a salt-elimination strategy. Structural, spectroscopic, and computational analyses of 9-12 shows: i) the formation of unsupported uranium-ruthenium bonds with no isocarbonyl linkages in the solid state; ii) ruthenium-carbonyl backbonding in the [Ru(η(5)-C(5)H(5))(CO)(2)](-) ions that is tempered by polarization of charge within the ruthenium fragments towards uranium; iii) closed-shell uranium-ruthenium interactions that can be classified as predominantly ionic with little covalent character. Comparison of the calculated U-Ru bond interaction energies (BIEs) of 9-12 with the BIE of [(η(5)-C(5)H(5))(3)URu(η(5)-C(5)H(5))(CO)(2)], for which an experimentally determined U-Ru bond disruption enthalpy (BDE) has been reported, suggests BDEs of approximately 150 kJ mol(-1) for 9-12. 相似文献
106.
Multiobjective optimization scheme for industrial synthesis gas sweetening plant in GTL process
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In industrial amine plants the optimized operating conditions are obtained from the conclusion of occurred events and challenges that are normal in the working units. For the sake of reducing the costs, time consuming, and preventing unsuitable accidents, the optimization could be performed by a computer program. In this paper, simulation and parameter analysis of amine plant is performed at first. The optimization of this unit is studied using Non-Dominated Sorting Genetic Algorithm-II in order to produce sweet gas with CO 2 mole percentage less than 2.0% and H 2 S concentration less than 10 ppm for application in Fischer-Tropsch synthesis. The simulation of the plant in HYSYS v.3.1 software has been linked with MATLAB code for real-parameter NSGA-II to simulate and optimize the amine process. Three scenarios are selected to cover the effect of (DEA/MDEA) mass composition percent ratio at amine solution on objective functions. Results show that sour gas temperature and pressure of 33.98 ? C and 14.96 bar, DEA/CO 2 molar flow ratio of 12.58, regeneration gas temperature and pressure of 94.92 ? C and 3.0 bar, regenerator pressure of 1.53 bar, and ratio of DEA/MDEA = 20%/10% are the best values for minimizing plant energy consumption, amine circulation rate, and carbon dioxide recovery. 相似文献
107.
108.
基于密度泛函理论, 分别计算了α, γ铀的晶格常数、平衡态体积、体弹模量及其导数等, 与实验和其他第一性原理计算结果符合较好; 并根据焓-压强曲线得到了两相的相变压强~111GPa. 通过体心立方结构理想拉伸强度的计算, 分析其在极端加载条件下的结构行为. 另外, 计算了小应变情况下U-Nb (6.25at.%) 的能量-应变关系, 发现对应于剪切模量c’的应变会使得该结构的能量降低, 揭示了该结构的力学不稳定性.
关键词:
铀
相变
理想强度
结构稳定性 相似文献
109.
为搞好洞庭湖区洪涝灾害的预测和防灾减灾,促进湖区经济建设,本文对洞庭湖区洪涝灾害的形成机制进行了分析研究.结果表明:80 %特大洪涝灾害的发生在厄尔尼诺年的次年,其内在机制是厄尔尼诺事件所导致的全球气候异常.大气环流的异常是洪涝发生的根本原因,主要表现在有特大洪涝年汛期,位于110°~120°E的西太平洋副高脊线位置都稳定处于19°~24°N之间,且越过24°N的时间大致与城陵矶年最高水位出现时间相吻合;西风带形势稳定;印度低压偏强并持续稳定.洞庭湖区洪涝与湖区、四水流域、长江上游东部区和西部区等广泛地域的降水密切相关,汛期在这4个区域第一次大范围的强降水过程以后20 天各代表站降水量总和的平均值对洞庭湖的洪涝预测具有决定性意义. 相似文献
110.
用X射线光电子能谱(XPS)分析研究了不同氧化层结构的铀金属试样在CO(25℃)和H2(200℃)气氛中的表面反应。CO和H2与铀金属表层反应后,氧化物中氧含量均减少,O/U比值随气体进气量的增加而减少。CO对铀金属表面的还原效果随铀表层氧化程度的提高而增强,并且强于H2。当表层氧化物较少、氧化程度较低时,铀试样在H2气氛中发生氢化反应。 相似文献