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71.
The enhanced lanthanide white-emission in solid by cucurbituril-based supramolecular assembly may provide a new strategy for smart light-emitting materials. 相似文献
72.
采用柠檬酸盐硝酸盐燃烧法,在较低的温度(900℃)下成功地合成单一晶相Gd3Al5O12∶Eu3+发光粉体,紫外激发荧光光谱分析表明,粉体615 nm和593 nm荧光发射源于Eu3+的5D0-7F2和5D0-7F1跃迁.该方法中各工艺条件(如pH值、柠檬酸/金属离子比、煅烧温度)对Gd3Al5O12∶Eu3+发光性能均有影响,通过试验得出了获得最佳发光性能荧光粉体的工艺参数. 相似文献
73.
Luminescentmaterialshavinglongdecayperi0dhaveat-IIactedmuchinterestduetotheirpotentialwidespreadaPplicati0ns.Recently,alongdecayluminescentp0wderhavingthecomPositionofSrAl2O4activatedwithEu' wasreportedandregardedasthebestcandidateforpracticalaPPlicationbecauseofitsuniqueadVantages0veritsprecursors.l'2Inthispaper,wereportthesynthesisofthelongdecayluminescentpowderandtheinnuence0fthemolarratioofAlt0sr0ntheethessioncolor.Toproducethelundnescentp0wder,amixtureofSrCO3,Al2O3,Eu2O3andsomesol… 相似文献
74.
Polycrystal Li2B4O7 (LBO) doped with Cu and In was prepared and then sintered at different temperatures. X-ray diffraction (XRD) was applied
to get the parameters of the LBO structure, thermoluminescence (TL) and optically stimulated luminescence (OSL) were measured,
and a second-order exponential decay model was fitted to the OSL decay curves. The results indicate that the original number
of OSL traps that have captured electroncs is linearly related with the sum of TL decay during the OSL process. Mean decay
constant of OSL is related to the sintered temperature. The possible reason is that the sintered temperature affects the crystal
sizes of the polycrystal, and consequently affects the stimulating lights’s intensity and the photoionization cross-section
of the electrons, which have been captured by the traps.
__________
Translated from Acta Scientiarum Naturalium Universitatis Sunyatseni, 2005, 44(4) (in Chinese) 相似文献
75.
The triplet nature of rare long-lived states of d0 metallocenes formed upon ligand-to-metal energy transfer was confirmed by studies of triplet-triplet charge transfer in biscyclopentadienyl
complexes Cp2MCl2 (M = Zr (1), Hf (2)). The interaction between precatalysts and substrates of catalytic polymerization systems, viz., complexes 1 and 2 and unsaturated hydrocarbons (alkenes and dienes), was studied in the region of concentrations close to catalytic values.
For organometallic π-complexes, it has been shown for the first time that, in the case of the unsaturated hydrocarbons, the
efficiency of energy transfer obeys the Perrin equation. The process occurs at distances R
0 close to the diameter of the interacting molecules and is well described by the exchange-resonant mechanism of interaction.
In the case of the cyclopentadiene-Cp2MCl2 (M = Zr, Hf) systems, R
0 = 14.6 Å. A linear relationship between the critical radius of the quenching sphere R
0 and the number of carbon atoms in a linear α-olefin has been revealed for the first time and evidences the formation of a
π-complex between the precatalyst and substrate molecules.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 35–39, January, 2007. 相似文献
76.
77.
《Chemphyschem》2002,3(12):1014-1018
In general, sensitization of lanthanide(III ) ions by organic sensitizers is regarded to take place via the triplet state of the sensitizers. Herein, we show that in dansyl‐ and lissamine‐functionalized Nd3+ complexes energy transfer occurs from the singlet state of the sensitizers to the Nd3+ center. No sensitized emission was observed in the corresponding complexes with Er3+, Yb3+, and Gd3+ ions. Furthermore, the fluorescence of the sensitizers was quenched only in the Nd3+ complex and not in the complexes with the other ions. Only Nd3+ centers can accept energy from the singlet state of the dyes, because the excited states of Nd3+ have a high spectral overlap with the fluorescence of the dansyl and lissamine sensitizers, and because the selection rules allow a fast energy transfer, which apparently is competitive with the fluorescence. 相似文献
78.
IntroductionLanthanidecomplexeshaveattractedmuchattentionbecauseoftheirimportantapplications .1InparticularEu(III)andTb(III)canbecharacterizedbylong lived(mstimescale)andstrongluminescentelectronicallyex citedstates ,whichmakesthemimportantinanalyticalchem… 相似文献
79.
IntroductionMononuclear ,dinuclearandpolymerictypesofcrys talstructuresforlanthanidecomplexeswithbenzoicacidanditsderivativeshavebeenobtainedbecauseofthevari ationofbridgingformsforcarboxylategroupandcoordina tionabilityofdiammineligands ,suchas 1,10 phena… 相似文献
80.
Nicola Armaroli Gianluca Accorsi JohnN. Clifford Jean‐Franois Eckert Jean‐Franois Nierengarten 《化学:亚洲杂志》2006,1(4):564-574
Oligophenylenevinylene (OPV)‐terminated phenylenevinylene dendrons G1 – G4 with one, two, four, and eight “side‐arms”, respectively, were prepared and attached to C60 by a 1,3‐dipolar cycloaddition of azomethine ylides generated in situ from dendritic aldehydes and N‐methylglycine. The relative electronic absorption of the OPV moiety increases progressively along the fullerodendrimer family C60G1 – C60G4 , reaching a 99:1 ratio for C60G4 (antenna effect). UV/Vis and near‐IR luminescence and transient absorption spectroscopy was used to elucidate photoinduced energy and electron transfer in C60G1 – C60G4 as a function of OPV moiety size and solvent polarity (toluene, dichloromethane, benzonitrile), taking into account the fact that the free‐energy change for electron transfer is the same along the series owing to the invariability of the donor–acceptor couple. Regardless of solvent, all the fullerodendrimers exhibit ultrafast OPV→C60 singlet energy transfer. In CH2Cl2, the OPV→C60 electron transfer from the lowest fullerene singlet level (1C60*) is slightly exergonic (ΔGCS≈0.07 eV), but is observed, to an increasing extent, only in the largest systems C60G2 – C60G4 with lower activation barriers for electron transfer. This effect has been related to a decrease of the reorganization energy upon enlargement of the molecular architecture. Structural factors are also at the origin of an unprecedented OPV→C60 electron transfer observed for C60G3 and C60G4 in apolar toluene, whereas in benzonitrile, electron transfer occurs in all cases. Monitoring of the lowest fullerene triplet state by sensitized singlet oxygen luminescence and transient absorption spectroscopy shows that this level is populated through intersystem crossing and is not involved in photoinduced electron transfer. 相似文献