We report a detailed reinvestigation of the ν2?+?2ν3 combination band of methane 12CH4 centred at (7510.3378?±?0.003)?cm?1 ((225.154263?±?0.0001)?THz) within the icosad of the overtone absorption. A new experimental setup is described, allowing us to carry out cw-laser cavity ring-down spectroscopy (cw-CRDS) at instrumental resolution in the MHz range in seeded supersonic jet expansions down to rotational temperature of 7?K compared to previous cw-CRDS measurements in our group achieving about 50?K in expansions of neat CH4. We provide a careful re-analysis on the basis of our new experimental results for the Q and R branch transitions including data obtained between about 7 and 300?K under various conditions. We resolve previously observed discrepancies of assignments and are able to present a definitive assignment for lines involving angular momentum quantum numbers up to J?=?4. The analysis of relative intensities in spectra taken at rotational and effective translational temperatures between about 50?K and less than 10?K indicate conservation of nuclear spin symmetry upon supersonic jet expansion, in agreement with previous results using other techniques and covering other spectral ranges. 相似文献
We used an electromagnetic microwave cavity sensor for real time measurement of the glycemia in goat-blood for three animals. We could determine the concentration of d-glucose in blood in the range of 90–550 mg/dl at the resonance frequency near 4.76 GHz with a bandwidth of 300 MHz. The change in microwave reflection coefficient S11 (due to the variation of d-glucose concentration in blood) was about 16.33 dB, 23.92 dB, 7.66 dB and resonance frequency shift was about 21.78 MHz, 36.29 MHz, 20.77 MHz, respectively, for the three different samples. The in vitro results show the measured signal-to-noise ratio of about 32 dB, and the minimum detectable signal level of about 0.025 dB/(mg/dl). The results clearly show the sensitivity and usefulness of this microwave sensor for these types of biological investigations. This proposed system provides a unique approach for real contactless glucose monitoring and, it may serve as a bloodless glucometer for the calibration of different glucose levels. 相似文献
Abstract The structure factor for liquid lead at the temperatures 613 K, 643 K, 863 K and 1163 K are measured by neutron diffraction. Extensive comparisons to earlier measurements are made as well as comparisons to different hard-core models. 相似文献
We study deviation from the Poissonian statistics of the frequency spacing distribution, appearing due to coupling of polarizational and transverse degrees of freedom in a perfectly square vertical cavity surface emitting laser. The deviation can be controlled by strength of the intracavity anisotropy and its alignment to the device boundaries. 相似文献
A novel scheme to multiply the repetition rate of a monolithic self‐mode‐locked laser for generating sub‐terahertz pulse sources is successfully demonstrated. A coated Yb:KGW crystal is designed to achieve a self‐mode‐locked operation at a repetition rate of 24 GHz with an average output power exceeding 1.0 W at a pump power of 4.8 W. A partially reflective mirror is utilized to combine with the output surface of the gain medium to constitute an external Fabry‐Perot cavity. It is theoretically and experimentally verified that adjusting the external cavity length to satisfy the commensurate condition can lead to the frequency spacing to be various order harmonics of the mode spacing of the monolithic cavity. The maximum pulse repetition rate of the laser output can be up to 216 GHz and the pulse duration is as short as 330 fs. More importantly, the overall characteristics of the first‐order temporal autocorrelation traces obtained by sequentially scanning the external cavity.length display an intriguing phenomenon of temporally fractional revivals, similar to the feature of spatial Talbot revivals.
An optimization method in RF coil array design for SENSE imaging is described. Using this method the optimized RF coil geometries can be calculated numerically given the required SENSE imaging performance. Although this method can be applied to optimize the RF coil arrays for both 1D and 2D SENSE imaging, to demonstrate the potential applications of this method, we designed RF coil arrays for 2D SENSE imaging and compared their performance by simulation. An optimized 4-channel receive-only RF coil array designed for 2D SENSE imaging was implemented and tested to demonstrate the feasibility of the proposed technique. Imaging results showed reasonable agreement with the simulations, thus the method can be applied to RF coil array designs for SENSE imaging when optimum imaging performance is desired. 相似文献
Split RF coils offer improved patient access by eliminating the need for the coil to be slid over the region of interest. For unshielded birdcage coils, the presence of end ring currents necessitates a direct electrical connection between two halves of the coil. For high-field (>3T) shielded birdcage coils, both the shield and the coil must be split and reliably connected electrically. This problem can be circumvented by the use of split TEM volume coils. Since the elements of a TEM coil are coupled inductively, no direct electrical connection between the halves is necessary. In this work we demonstrate that the effects of splitting the shield for head and knee TEMs can be compensated for, and performance retained. For the knee, the improved access allowed the coil diameter to be reduced, enhancing the sensitivity by 15-20%. 相似文献