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51.
The determination of the internal strains on the coupling parameter approach becomes very involved particularly when the number
of atoms per unit cell is very large. It is shown in this paper that a knowledge of the site symmetry of the atoms helps one
in determining the number of non-vanishing internal strain coefficients easily. The internal strain coefficients of two symmetry
connected atoms can also be related. Examples are shown to illustrate these ideas. 相似文献
52.
We develop a uniaxial optimal perfectly matched layer (opt PML) method for solving the time-harmonic scattering problems by choosing a particular absorbing function with unbounded integral in a rectangular domain. With this choice, the solution of the optimal PML problem not only converges exponentially to the solution of the original scatting problem, but also is insensitive to the thickness of the PML layer for sufficiently small parameter ε0. Numerical experiments are included to illustrate the competitive behavior of the proposed optimal method. 相似文献
53.
Zhipeng Qiu 《Applied mathematics and computation》2010,216(5):1553-1565
In this paper, a 3(n+1) dimensional sexually transmitted disease model is studied. The model involves two competing strains 1 and 2, where females are divided into n different groups based on their susceptibility to two distinct pathogenic strains. The first and second reproduction numbers , which have their biological meaning, are defined for strain , respectively. With the non-degeneracy assumption (H), a complete classification for dynamics of this model in terms of is presented, which is based on the theory of type-K monotone dynamical systems. 相似文献
54.
M. Giffhorn B. Becker A. A. Menovsky J. A. Mydosh G. J. Nieuwenhuys S. Ramakrishnan 《高压研究》2013,33(1-6):159-163
Abstract An uniaxial pressure cell for low temperature use is described in detail. Then we present data of the electrical resistance of single crystals of Lu5Ir4Si10, which is known to show a charge-density-wave transition around 83 K and to become superconducting near 3.8 K, both phenomena being anticorrelated under pressure. Since the CDW in Lu5Ir4Si10 is a quasi one-dimensional phenomenon because of a chain-like structure, it responds to uniaxial pressure in a specific way. 相似文献
55.
Yutaka Koike 《Journal of Macromolecular Science: Physics》2013,52(1):13-37
The uniaxial deformation behavior of three polypropylene films with isotacticity indices varying from 43 to 95 was investigated in the partially molten state using real time, true stress, true strain, and birefringence measurement system. These polymers generally exhibit three regime stress‐birefringence behaviors during stretching. The unmelted crystalline regions act as physical junctions. If the films contain crystallinity that is too low (less than ca. 10%) the Regime I disappears. Under these conditions, the films were found to exhibit large linearity in strain and stress optical behavior. If, however, too low a deformation rate is employed, these relationships become non‐linear. The increase of isotacticity increases the magnitude of the birefringence at all deformation levels primarily as a result of the increase in crystallinity that helps in establishing a long‐range physical network. This increase in the long‐range connectivity was found to promote not only the orientation in crystalline domains but also in the amorphous domains. The increased long‐range connectivity in high isotacticity films was also found to result in destruction of local initial structures that generate a large fraction of the oriented amorphous chain regions. This translates into larger stress decrease and birefringence increase changes during the holding stage where the oriented amorphous chains undergo complex relaxation/oriented crystallization processes. 相似文献
56.
Extensive experimental results are presented to reveal the relaxations of polystyrene surface deformed by rubbing with a velvet
cloth. We found that surface topographic features, such as ditches and ridges created by rubbing, relax at temperatures at
about 20°
C below the bulk glass transition temperature of the polystyrene for a molecular weight of 442 kg/mol, even though we estimate
the Laplace Pressure driving the relaxation to be 1/500 of the yield limit. The relaxation is independent of the thermal history
before the rubbing process, and post rubbing thermal history below 55°
C . In other words, physical-aging processes at 23°
C for up to 7 days and at 50°
C for 2 days, which would have drastic effects on the relaxations of bulk polymers, have little effects on the relaxations
of rubbed surfaces. This is consistent with the mobility enhancement in the surface layer previously reported in the literature. 相似文献
57.
Poly(lactic acid) (PLA)/poly(propylene carbonate) (PPC)/mica composites with different amount of chain extender (CE) were melt compounded and then processed via two routes (compression molding and uniaxial stretching) into sheets and films. The tensile, thermal, and oxygen barrier properties of all the samples were investigated. Tensile test showed that the tensile strength and elongation at break of all films were much higher than that of all sheets, especially for PLA/PPC/mica with 0.9‐wt% CE composite (CM3(CE)0.9) film. The crystallinity of all films increased significantly after uniaxial stretching of sheet samples. The Fourier transform infrared spectroscopy (FTIR) results proved the chemical reactions occurred between PLA/PPC and CE. Scanning electron microscope (SEM) analysis revealed that compatibility and interfacial adhesion of all samples were improved after adding mica and CE, and they were further enhanced after uniaxial stretching. The addition of CE was not favorable to improve the oxygen barrier performance of PLA/PPC/mica sheet samples. However, the oxygen barrier performance of film samples was significantly improved after uniaxial stretching. In particular, the CM3(CE)0.9 film had the lowest oxygen permeability coefficient (1.4 × 10?15 cm3·cm/(cm2·s·Pa)), and this was the best oxygen barrier properties reported in the literature for PLA‐based composites, which was comparable with PA film. This study demonstrated the high efficiency of uniaxial stretching on improvement of properties of composites, which would promote the application of biodegradable polymers in oxygen sensitive food packaging. 相似文献
58.
ABSTRACT The electronic properties and electron transport of a sawtooth penta-graphene nanoribbon (SSPGNR) under uniaxial strains are theoretically studied by density-functional theory (DFT) in combination with the non-equilibrium Green's function formalism. We investigated the electronic structures and the current–voltage (I–V) characteristics of the SSPGNRs under a sequence of uniaxial strains in range from 10% compression to 10% stretch. In this strained range, carbon atoms still keep a pentagon network, but with the changing bond lengths. The C–C bond lengths change almost linearly with the tolerable strain. The value of the band gap of SSPGNRs can be depicted as a parabola under uniaxial strain. Our calculations show that the current is monotonous increase with compressive strain at the same applied bias voltage. In case of tensile strain, the variable rule of the current is different that it increases at first and decrease later. The fundamental physical properties (band structure, I–V characteristic) of SSPGNRs seem to be more sensitive to compressive strain than the stretch strain. The current intensity of the compressive-SSPGNR is by 2 orders of magnitude compared to that of the tensile-SSPGNR at the same strain in range from 6% to 10%. The results obtained from our calculations are beneficial to practical applications of these strained structures in SSPGNRs-based electromechanical devices. 相似文献
59.
BaTiO3 single crystals were grown by the melt-grown method. The effect of uniaxial pressure (0–1700 bar) on the dielectric properties of these crystals has been systematically studied. The external stress showed obvious effects on these properties. An increase in the difference between the Curie Tc and Curie–Weiss T0 temperatures induced by the applied pressure is observed. This could be ascribed to the inducing of non-ferroelectric cubic islands in the tetragonal phase by the applied compressive stress. On the other hand, the pressure behavior of thermal hysteresis and the ??/?T vs. T plot strongly suggests that the phase transition changes to second-order type with increasing pressure. The Curie–Weiss constant obtained from a modified Curie–Weiss law strongly decreases with increasing pressure, suggesting that the mechanism of phase transition is going to order–disorder type. An increase in the difference between the Curie Tc and Burn's TB temperatures with increasing pressure is observed. This could be ascribed to the narrowing of the temperature range on which the Curie–Weiss law is valid. In general, the obtained results are in good agreement with hydrostatic pressure data. Some kind of relaxation near Tc, which is strongly coupled with strain caused by applied compressive stress, is postulated. 相似文献
60.