The Electrochemical Investigation of MEH-PPV in Ionic Liquid

Ionic liquids are a new kind of room-temperature molten organic salts. It can be used as solvents in the organic/polymeric syntheses, and some of them are called "green" solvents because of its recyclability1. Ionic liquids possess the superior properties, such as thermal stability up to 200(C, involatility and re-designability(for both cation and anion). The ionic liquid employed in this work is [bmim] [PF6]- ( butylmethylimidazolium hexafluorophosphate ) which is immiscible with water and h…     

Chiral recognition in the resolution of enantiomers by GLC

Summary Chiral recognition of many enantiomeric solutes by a chiral amide stationary phase is based mainly on hydrogen bonding. A chiral-recognition-factor CHI is proposed, given by the difference of the enthalpy change in the enantiomer discrimination, standardized with respect to the specific interaction of the solutes with the diamide core of the stationary phase. The r?le of the entropy part is also discussed. By extrapolation of the retention behaviour to elevated temperature, peak inversion of enantiomers is predicted. Presented at the 15th International Symposium on Chromatography, Nürnberg, October 1984     

Highly sensitive method for the determination of a new anthracycline: Pirarubicin

Summary A new and highly sensitive HPLC method for the simultaneous determination of pirarubicine (THP-doxorubicin) and its metabolites, adriamycin and adriamycinol, in human plasma, is described. Samples were treated by liquid-liquid extraction, the organic phase removed and the residue dissolved in methanol. Separation was on a Lichrocart Supersher RP 8 column, (250×4 mm) 4 m, with a mobile phase of acetonitrile/methanol/formate-buffer.     

CTBN-TOUGHENED EPOXY RESINS——EFFECT OF CURING MECHANISM ON NETWORK STRUCTURE OF THE RUBBER PHASE

Epoxy resins toughened with carboxyl-terminated butadieneacrylonitrile copolymers (CTBN) are two-phase thermosets. The network of the in situ formed rubber particles depends upon the curing mechanism of the resin. When a primary polyamine such as triethylene tetramine was used as curing agent, the network of the rubber phase was quite incomplete, whereas a perfect rubber network was formed with 2-ethyl-4-methyl imidazole as the curing agent.     

液体和非晶态Ni64B36合金结构的从头算分子动力学模拟

运用从头算分子动力学模拟了液体以及猝冷后形成的非晶态Ni₆₄B₃₆合金体系, 得到了它们的对相关函数、结构因子、键对分析方面的结构信息, 与实验结果相当一致; 结果表明, 猝冷得到的合金性质与液体合金性质相似, 为非晶态结构. B原子多数以B—B双原子成键形式分散于Ni原子构成的骨架中. 电子态密度分析表明, Ni 3d电子最活泼, 因此在合金中Ni为活性位. 轨道电荷分析从电子结构角度揭示了在NiB 催化剂中B作为修饰剂的机理.     

Reliable evaluation of temperature-independent parameters in correlation of vapour–liquid equilibrium data

A new algorithm/program has been elaborated for simultaneous processing of different sets of vapour–liquid equilibrium data. The program was tested with six binary hexane + isomeric pentanol systems, each of them measured at three different isobaric conditions and one isothermal system of tert-butyl-methyl-ether + 2-methyl-2-propanol measured at three different temperatures. The correlation uses the maximum likelihood method, taking into account real behaviour of vapour phase. The parameters obtained are valid within the whole temperature range of the data, and are consistent in comparison with those obtained from individual correlations of isobars or isotherms. Results are presented for the Wilson and NRTL equations.     

A Novel Green Preparation of a, a''''-Bis (substituted benzylidene)-cycloalkanones Promoted by FeCl_3 6H-2O in Ionic Liquid

a, a'-Bis(substituted benzylidene)cycloalkanones were efficiently prepared from cycloalkanones and benzaldehydes in [bmim][BF4] by using iron(III) chloride hexahydrate as a catalyst. It is shown that [bmim][BF4] and iron(III) chloride hexahydrate can be quantitatively recovered and be reused effectively for many times. Compared with the known methods, this novel process has the advantage of being an envkonmentally benign process together with good yields and mild reaction conditions.     

Synthesis and structure of anhydrodimers of salicylaldehydes

Anhydrodimers have been synthesized by reactions of salicylaldehyde and 3,5-di-tert-butylsalicylaldehyde with SOCl₂ or PCl₅. A mechanism of condensation has been proposed, and the molecular structure of dibenzo-2,6,9-trioxabicyclo[3.3.1]nona-3,7-diene has been determined by X-ray structural analysis.Deceased.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1549–1551, August, 1995.The work was supported by the Russian Foundation for Basic Research (Project No. 94-03-08653).     

核磁共振法测定高聚物的结构—核磁共振二维谱

介绍了核磁共振(NMR)波谱,尤其是核磁共振二维谱(2D NMR)在最近几年内的进展。内容包括怎样用NMR测定高聚物的序列分布、共聚物结构、聚合物的混溶性、聚合物液晶的取向度、分子量、短链度和长链支化度、凝聚态高聚物的多相结构等。     

高效液相色谱法测定精对苯二甲酸中微量杂质

建立了高效液相色谱法（HPLC）同时测定精对-苯二甲酸（PTA）中微量杂质4-羧基苯甲醛（4-CBA）、对-甲基苯甲酸（P-TOL）和苯甲酸（C7H6O2）含量的方法。采用的色谱柱为Shim-PackWAX-1柱，流动相为0.1mol/L NH3H2PO4 6%CH3OH，(pH4.5)，检测波长为254nm。PTA中微量杂质4-CBA、P-TOL和C7H6O2的含量分别为0.59-235.20mg/kg、4.52-392.00mg/kg和0.28-24.55mg/kg时线性关系良好，其线性相关系数分别为0.9998、0.9997和0.9999。苯甲酸加样平均回收率99.03％，RSD0.37％。