We report on solution‐processible polymer solar cells (PSCs) fabricated on a papery substrate using carton. Highly conductive PEDOT:PSS was used as a bottom anode and planarization layer, and a semi‐transparent top cathode was applied. This research could be an important approach to the development of all‐solution‐processible papery PSCs as well as paper electronics.
The title complex, [Co(DprS)2 (H2O)2]2(BF4)4 (DprS is di-2-pyrimidinyl sulfide), was obtained and characterized by elemental analysis, FT-IR and X-ray crystallography. The complex crystallizes in space group P21/c with a=11.742(1), b=22.439(2), c=20.538(2) , β=109.713(5)°, Z=4, V=5094.3(3)3 , Dc=1.692 g·cm-3 , μ=0.929 mm-1 , F(000)=2600, R=0.0756 and wR=0.1929. The asymmetric unit of the title complex is comprised of two isomeric cobalt(Ⅱ) centers (Co(1) and Co(2)) with a cis-[Co(DprS)2(H2O)2]2+ moiety. Each Co(Ⅱ) center exhibits a similar distorted N4O2-octahedral coordination geometry surrounded by a pair of DprS in a N,N’-chelate mode and two aqua ligands in a cis-relationship. Unconventional S···π(pyrimidinyl), N···π(pyrimidinyl), and anion(BF4-)···π(pyrimidinyl) are found to combine with the C H···F and O H···F interactions to stabilize a whole three-dimensional framework with the mononuclear units (Co(1) and Co(2)). The ligand conformation will be also discussed. 相似文献
Abstract A bienzymatic sensing layer containing two enzymes able to work sequentially, choline oxidase (ChOD) and phospholipase D (PLaseD), was used to design an electrochemical biosensor for the detection of either a water-soluble (choline) or insoluble (phosphatidylcholine) substrate. A photocrosslinkable polymer, poly(vinyl alcohol) bearing styrylpyridinium groups (PVA-SbQ), was used as host-matrix for enzyme immobilization. Controlled amounts of PVA-SbQ and of the two enzymes were directly coated on a platinum disk, then photopolymerized. The compatibility of working conditions for choline and phosphatidylcholine detection in the presence of Triton X-100 and CaCl2 was investigated. The effect of the activity ratio PLaseD / ChOD on the sensor performance was determined. The sensitivities to choline and to phosphatidylcholine were 18 mA.1mol?1 and 0.66 mA.1.mol?1 respectively, the detection limit being 1.5.10?8 M for choline and 1.5.10?6 M for phosphatidylcholine. The linear range extended up to ca. 10?4 M for choline and ca. 2.10?5 M for phosphatidylcholine and the response time was close to 30 seconds for choline and ca. 2 min for phosphatidylcholine. 相似文献
Vertically coupled quantum wires (QWRs) have been made by alternately stacking nominally 3.6 nm thick In0.53Ga0.47As self-organized QWR layers and 1 nm thick In0.52Al0.48As barrier layers on (2 2 1)A-oriented InP substrates by molecular beam epitaxy. The surface of In0.53Ga0.47As QWR layers was corrugated at an amplitude of 1.1 nm and period of 27 nm, and lateral confinement potential is induced by their thickness modulation. The wavelength of photoluminescence (PL) from the stacked QWRs at 15 K becomes longer from 1220 to 1327 nm with increasing total number of stacked QWR layers, NSL, from 1 to 9, while PL full-width at half-maximum is reduced from 22 to 8.6 meV. The PL intensity with the polarization parallel to the wire direction, I, is 1.30 times larger than that with the normal polarization, I, when NSL=1. The PL intensity ratio, I/I, reaches as large as 4 when NSL=9, indicating successful control of relative strength between vertical confinement and lateral confinement of carriers. The value of I/I obtained for the stacked QWRs with NSL=9 is the same value as cylindrical QWRs have. The results indicate that effectively cylindrical QWRs with the best uniformity and 1.3 μm range emission were realized by stacking of self-organized QWR layers. 相似文献
Surface-enhanced Raman scattering (SERS) is a potent tool in bioanalytical science because the technique combines high sensitivity
with molecular specificity. However, the widespread and routine use of SERS in quantitative biomedical diagnostics is limited
by tight requirements on the reproducibility of the noble metal substrates used. To solve this problem, we recently introduced
a novel approach to reproducible SERS substrates. In this contribution, we apply ultrafast time-resolved spectroscopy to investigate
the photo-induced collective charge-carrier dynamics in such substrates, which represents the fundamental origin of the SERS
mechanism. The ultrafast experiments are accompanied by scanning-near field optical microscopy and SERS experiments to correlate
the appearance of plasmon dynamics with the resultant evanescent field distribution and the analytically relevant SERS enhancement.
Figure Ultrafast time-resolved differential absorption spectroscopy combined with scanning near-field optical microscopy (left) and
atomic force microscopy (right) yields insight into the photoinduced charge-carrier dynamics in innovative reproducible SERS-substrates
Dana Cialla and Ronald Siebert contributed equally to this work. 相似文献
Surface-enhanced Raman scattering (SERS) enhancement and the reproducibility of the SERS signal strongly reflect the quality
and nature of the SERS substrates because of diverse localized surface plasmon resonance (LSPR) excitations excited at interstitials
or sharp edges. LSPR excitations are the most important ingredients for achieving huge enhancements in the SERS process. In
this report, we introduce several gold and silver nanoparticle-based SERS-active substrates developed solely by us and use
these substrates to investigate the influence of LSPR excitations on SERS. SERS-active gold substrates were fabricated by
immobilizing colloidal gold nanoparticles on glass slides without using any surfactants or electrolytes, whereas most of the
SERS-active substrates that use colloidal gold/silver nanoparticles are not free of surfactant. Isolated aggregates, chain-like
elongated aggregates and two-dimensional (2D) nanostructures were found to consist mostly of monolayers rather than agglomerations.
With reference to correlated LSPR and SERS, combined experiments were carried out on a single platform at the same spatial
position. The isolated aggregates mostly show a broadened and shifted SPR peak, whereas a weak blue-shifted peak is observed
near 430 nm in addition to broadened peaks centered at 635 and 720 nm in the red spectral region in the chain-like elongated
aggregates. In the case of 2D nanostructures, several SPR peaks are observed in diverse frequency regions. The characteristics
of LSPR and SERS for the same gold nanoaggregates lead to a good correlation between SPR and SERS images. The elongated gold
nanostructures show a higher enhancement of the Raman signal than the the isolated and 2D samples. In the case of SERS-active
silver substrates for protein detection, a new approach has been adopted, in contrast to the conventional fabrication method.
Colloidal silver nanoparticles are immobilized on the protein functionalized glass slides, and further SERS measurements are
carried out based on LSPR excitations. A new strategy for the detection of biomolecules, particularly glutathione, under aqueous
conditions is proposed. Finally, supramolecular J-aggregates of ionic dyes incorporated with silver colloidal aggregates are
characterized by SERS measurements and correlated to finite-difference time-domain analysis with reference to LSPR excitations.
Figure SPR and SERS images for isolated, elongated and two-dimensional gold nanostructures 相似文献
We study the use of the self-Kerr and cross-Kerr nonlinearities to realize strong photon blockade in a weakly driven, four-mode optomechanical system. According to the Born−Oppenheimer approximation, we obtain the cavity self-Kerr coupling and the inter-cavity cross-Kerr coupling, adiabatically separated from the mechanical oscillator. Through minimizing the second-order correlation function, we find out the optimal parameter conditions for the unconventional photon blockade. Under the optimal conditions, the strong photon blockade can appear in the strong or weak nonlinearities. 相似文献