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151.
A new N,N-dimethyl-d-glucosamine ligand has been developed for the copper-catalyzed Ullmann-type coupling of N-H heterocycles (e.g., indoles, benzimidazoles, pyrazoles and triazoles) with aryl halides. This method was accomplished not only featuring excellent yields, mild reaction conditions and simple operation, but also showing eco-friendly and broad-spectrum substrates, and could be widely used in the construction of N-aryl heterocyclic systems. 相似文献
152.
Yilmaz Muslu 《Applied biochemistry and biotechnology》1992,37(2):209-224
Mass transfer within microbial films is described using Monod type biological kinetics in terms of the properties of packing
material and the feed solution. For this purpose computer techniques have been first developed for the numerical evaluation
of the normalized biofilm mathematical model. A second-order partial differential equation describing the mechanism of dispersion
phenomena inside the liquid layer is then solved to determine the mass transfer coefficient. The application of the theory
to experimental data reported in literature has also been demonstrated using the values of mass transfer coefficients and
the computer programs developed. 相似文献
153.
根据古典阴阳互补和现代对偶互补的基本思想,通过早已提出的一条简单而统一的新途径,系统地建立了Reissner夹层板动力学的各类非传统Hamilton型变分原理.这种新的非传统Hamilton型变分原理能反映这种动力学初值-边值问题的全部特征.文中首先给出一个Reissner夹层板广义虚功原理的表式.然后从该式出发,不仅能得到Reissner夹层板动力学的虚功原理,而且通过所给出的一系列广义Legendre变换, 还能系统地成对导出五类变量、 二类变量和一类变量非传统Hamilton型变分原理的互补泛函.同时,通过这条新途径还能清楚地阐明这些原理的内在联系. 相似文献
154.
155.
CVD金刚石薄膜涂层衬底预处理方法 总被引:4,自引:1,他引:3
概述了CVD金刚石薄膜涂层衬底预处理的基本方法,并对一些主要方法作了评述.对于硬质合金类衬底预处理、铜衬底表面预处理、钢铁衬底表面预处理、硅表面预处理,提高膜基结合力的途径除有研磨、超声清洗、植晶、化学腐蚀、等离子体刻蚀、沉积中间过渡层等方法外,还有优化衬底形状、通过表面扩散感应促进成核等手段. 相似文献
156.
K. Tsuji Z. Spolnik K. Wagatsuma 《Spectrochimica Acta Part B: Atomic Spectroscopy》2001,56(12):1381-2504
The energy distribution of the background radiation originating from two kinds of substrate materials has been studied using Electron Probe X-Ray Microanalysis (EPMA) at grazing-exit angles. The different behavior between tendencies of background reduction for the silicon and the gold substrates at the grazing exit angle is explained using a critical energy concept. It is also shown experimentally that a gold substrate results in a lower background intensity than a silicon substrate in the energy region 5–7 keV, while on the other hand, for elements with X-ray lines of 2–3 keV, it is advantageous to perform the analysis when such elements are deposited on the silicon substrate. 相似文献
157.
158.
159.
《Analytical letters》2012,45(16):1863-1876
Abstract The electrochemical activity determination of γ-glutamyl-transpeptidase is described using the electrogenic L-γ-glutamyl paraaminodiphenylamide substrate. In order to correlate the results with classical measurements involving chromogenic substrates, linear calibration curves for the amperometric detection of the released free amine, the kinetics of the catalysis and the enzyme level in one plasma sample have been compared to photometric experiments effectuated in parallel runs, in the same conditions, with L-y-glutamyl paranitroanilide as the substrate. Results show that this new technique applies successfully to such evaluations. 相似文献
160.
Bi-min Zhang Newby Elham Malekzadeh Abdullah Alghunaim 《Journal of polymer science. Part A, Polymer chemistry》2020,58(19):2728-2740
This study explored the possibility of polymer interdiffusion for retaining thermoresponsive poly(N-isopropylacrylamide) (pNIPAAm) on polycarbonate (PC). It was hypothesized that interdiffusion could be facilitated either by increasing the annealing temperature or by treating PC using air plasma (AP) and ultra-violet ozone (UVO). The results showed that increasing annealing temperature only moderately improved pNIPAAm retention. Treating PC with AP led to an increase in surface-active groups and a greatly enhanced retention of pNIPAAm. UVO treatment, however, severely damaged the PC layer with no noticeable enhancement on pNIPAAm retention. The retained pNIPAAm films on PC exhibited thermoresponsive behavior as evidenced by water contact angle and desired cell attachment/detachment behaviors. These results illustrate the simplicity of using polymer interdiffusion to successfully retain pNIPAAm films on a polymer, and the resulting substrates would be less expensive and more versatile than those retained on brittle supports (e.g., glass) for applications that require resilient thermoresponsive substrates. 相似文献