Effect of frequency on sonochemical reactions. I: Oxidation of iodide

The effect of continuous sonication on the kinetics of iodine formation in aqueous iodide solutions was studied in the presence of air and argon at two frequencies, 20 and 900 kHz. Most workers in this area assume that frequency has a negligible effect on sonochemical reactions. The present results indicate, however, that there is a significant effect in the above solutions. The rate of sonochemical oxidation of iodide in aqueous solution is 3.1 times greater in presence of air than argon at 900 kHz, in contrast to the situation at 20 kHz, where the ratio is 0.9 A 900 kHz apparatus was specially designed to make it possible to measure the absolute acoustic power delivered into the solution. The rate of oxidation per unit power in this new 900 kHz apparatus can be more than 30 times greater than that at 20 kHz for the oxidation of iodide in the presence of air.     

Optoacoustic interaction in uniaxial gyrotropic quartz crystals

The specific features are considered of the noncollinear optoacoustic interaction in uniaxial gyrotropic quartz crystals in an intermeadiate regime of diffraction close to the Bragg regime. A system of equations of coupled waves is presented which describes the optoacoustic interaction in uniaxial gyrotropic crystals in the Raman-Nath, intermedaite, and the Bragg regimes of diffraction. The dependences of the diffraction efficiency on the ultrasonic wave intensity, the optoacoustic interaction length, and on the incident light polarization are investigated. A multispike structure of the Bragg maximum is studied that appears in accounting for the crystal gyrotropy. A good agreement between the theoretical calculations and the known experimental results for a quartz crystal is shown. Mozyr State Pedagogical Institute, 28, Studencheskaya Str., Mozyr, 247760, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 2, pp. 278–281, March–April, 1999.     

石油醚在流体静高压下的超声声速、衰减、密度和绝热压缩系数

 专门设计了用脉冲-回波-重合法在不同静水压下测量液体声速的装置，并对石油醚在0.1~650 MPa流体静压力范围内测量了其超声声速和衰减系数。还通过测量体积压缩量和质量得到石油醚密度ρ随流体静压力的变化。最后，给出了石油醚的绝热压缩系数β与流体静压力的关系。     

Monocrystal elastic constants in the ultrasonic study of welds

For studying welds ultrasonically, the importance of knowing the material's single-crystal elastic constants, the C_ijs, is explained. Where these constants are not known, some guidelines are given for estimating them from polycrystalline elastic constants such as Young's modulus and the shear modulus.The important case of [001] fibre texture is considered. Being transversely isotropic, this case exhibits five macroscopic elastic constants, which are related to the three cubic elastic constants: C₁₁, C₁₂, C₄₄. From these five constants the angular variations of Young's modulus, the torsional modulus, and the sound velocities can be computed. For the same [001] fibre texture, results are given for a standard well-characterized material — copper, where the C_ijs are well known.     

超声降解处理水体污染物的研究状况与发展

利用超声产生的空化效应来降解水体中的污染物,是近几年来国外研究者关注的热点领域之一。文章就超声在污染水体降解的原理、理论、降解效果以及主要的影响因素作扼要的综述介绍,对存在的问题和发展的趋势提出见解和看法。     

Elastic constants of sodium chlorate from 77 K to 350 K

The elastic constantsC ₁₁,C ₁₂ andC ₄₄ of sodium chlorate single crystal have been evaluated using 10 MHz ultrasonic pulse echo superposition technique. The values areC ₁₁=4.90,C ₁₂=1.39,C ₄₄=1.17 (× 10¹⁰ N/m ²) at 298 K and 6.15, 2.16, 1.32 (×10¹⁰ N/m ²) at 77 K. The data agree well with the values measured earlier up to 223 K. Brief mention is also made of the low temperature bonding problems in these soft crystals.     

Non-linearity parameter B/A of binary liquid mixtures at elevated pressures

When sound waves of high amplitude propagate, several non-linear effects occur. Ultrasonic studies in liquid mixtures provide valuable information about structure and interaction in such systems. The present investigation comprises of theoretical evaluation of the acoustic non-linearity parameter B/A of four binary liquid mixtures using Tong and Dong equation at high pressures and T=303.15 K. Thermodynamic method has also been used to calculate the non-linearity parameter after making certain approximations.     

超声波专题设计性实验

在测量超声波在空气中传播速度实验基础上,开设了超声波专题设计性实验,分别增加了测量压电换能器的共振频率、超声波在空气中的损耗系数、超声波在水中的传播速度等实验内容,丰富了大学物理实验教学内容,拓展了学生视野.     

微小层片型缺陷的超声非线性区域检测技术*

针对微小层片型缺陷的超声检测效率低、检测能力弱、易受主客观因素干扰的问题,提出弹簧扁钢中微小层片型缺陷的非线性超声区域检测技术。首先,优化探头夹持装置并提出区域检测方法,提取稳定可靠的检测信号;其次,提出相对非线性系数均值及波动系数表征缺陷分布;最后,基于斯皮尔曼次序相关系数分析扁钢各类缺陷与非线性超声系数均值的相关性。研究结果显示:两种非线性超声特征参数中的波动系数具有更高的缺陷敏感度,可表征扁钢中缺陷分布;波动系数与扁钢中微小层片型缺陷的相关系数比与体积型缺陷的相关性系数大得多,特别适用于微小层片型缺陷的检测。     

Application of laser ultrasonic technique for non-contact detection of drilling-induced delamination in aeronautical composite components

The detection of drilling-induced delamination in composite components is a vital and challenging task in aviation industry. Numerous key components of aircrafts are made of composite materials, and drilling is often a final operation during assembly. Drilling-induced delamination is a very serious defect that significantly reduces the structural reliability, but it is rather difficult to be detected effectively due to its special location. A novel application of laser ultrasonic technique for the detection of drilling-induced delamination in composites is presented in this paper. A carbon fiber reinforced plastic laminate with drilling holes was made as specimen. A laser ultrasonic system was constructed and experiments were performed to detect the drilling-induced delamination, based on propagation characteristic of ultrasonic waves generated by pulse laser with a wavelength of 1064 nm and pulse duration of 10 ns. A laser interferometer based on two wave mixing is used to measure ultrasonic wave signals, and the morphology features of the delamination are imaged clearly by laser ultrasonic C-scan testing. The results proved that the laser ultrasonic technique is a feasible and effective method for the detection of drilling-induced delamination in composite components.