大口径旋转偏摆棱镜径向支撑优化设计

支撑方式对大型光学元件的镜面变形及应力集中具有重要影响。以大口径、非均匀质量分布、二维旋转棱镜为研究对象,综述了多点支撑和面支撑方式,提出了可调分段面支撑方法,并给出具体的方案设计。系统地分析了面支撑方式下棱镜的运动过程,得到最危工况。采用两步优化方法对该工况下的支撑夹角进行优化,优化后棱镜运动过程中的最大变形峰谷值与最大等效应力值相比优化前分别减小了7.40%和11.45%,支撑效果得到了明显改善,验证了该支撑方式的合理性及可行性。     

The influence of interfacial barrier engineering on the resistance switching of In₂O₃:SnO₂/TiO₂/In₂O₃:SnO₂ device

The I–V characteristics of In2O3:SnO2/TiO2/In2O3:SnO2 junctions with different interfacial barriers are inves- tigated by comparing experiments. A two-step resistance switching process is found for samples with two interfacial barriers produced by specific thermal treatment on the interfaces. The nonsynchronous occurrence of conducting filament formation through the oxide bulk and the reduction in the interfacial barrier due to the migration of oxygen vacancies under the electric field is supposed to explain the two-step resistive switching process. The unique switching properties of the device, based on interfacial barrier engineering, could be exploited for novel applications in nonvolatile memory devices.     

多孔阳极氧化铝膜形成机理的研究

为了探讨多孔阳极氧化铝膜的形成机理,在0．3mol／L的草酸溶液中,通过二次阳极氧化法制备了多孔氧化铝膜．X射线衍射和扫描电镜测量表明,本实验制备了高度有序的、非晶态结构的多孔氧化铝膜．通过分析阳极氧化过程中的电解电流随时间变化的关系,研究了多孔氧化铝膜的形成机理．     

制备工艺对多孔阳极氧化铝特性的影响

通过对草酸溶液中制备的多孔阳极氧化铝(PAA)的形貌、晶态结构和光致发光(PL)特性的表征和机理分析,研究了草酸电解液浓度、阳极氧化电压和退火等丁艺对PAA的形成及特性的影响.PAA的孔径在50～120 nm之间,且随着阳极氧化电压的升高而增大,而受电解液浓度的影响较小.X射线衍射结果表明:PAA为非晶态结构,退火之后结晶,并有多相共存.PL测试表明PAA在375～500 nm之间有一较宽的蓝色发光带,发光峰在425 nm左右,是由氧空位引起的,且其峰强可通过改变阳极氧化电压和草酸浓度等参数来调制.     

解不适定算子方程的一个定常二步隐式迭代法

１．引言 设Ｘ,Ｙ是两个Ｈｉｌｂｅｒｔ空间,Ａ：Ｘ→Ｙ是有界线性算子,考虑算子方程 Ａｘ＝ｙ（１．１）如果Ａ的值域Ｒ（Ａ）在Ｙ中非闭,则方程（１．１）是不适定的［１］．许多应用科学中都归结出这一类方程,特别地,许多反问题是不适定的［２,３］．本文考虑方程（１．１）的 Ｍｏｏｒｅ－Ｐｅｎｒｏｓｅ广义解,这里Ａ是算子Ａ的Ｍｏｏｒｅ－Ｐｅｎｒｏｓｅ广义逆［１］．Ａ＋ｙ存在当且仅当本文均作这一假设．在实际中,通常代替（１．１）的是扰动方程这里右端项,为一给定的误差水平,Ｑ是Ｙ到Ｒ（Ａ）的正交投影算子．对扰…     

多孔铝激光染料镶嵌膜的荧光光谱研究

以多孔阳极氧化铝为基底,将激光染料分子RhB有效地嵌入多孔铝的孔中,获得多孔铝激光染料镶嵌膜。镶嵌膜的荧光光谱类似于低浓度液相染料的荧光光谱,但光谱线型更趋于对称。通过改变多孔铝孔的直径和深度及染料溶液深度,研究光谱的变化关系,初步提出了多也铝镶嵌染料膜的理想模型。     

Photoelectrochemical Properties of Annealed Anodic TiO2 Layers Covered with CuOx

In this work, we present a systematic study on the influence of Cu²⁺ ion concentration in the impregnation solution on the morphology, structure, optical, semiconducting, and photoelectrochemical properties of anodic CuO_x-TiO₂ materials. Studied materials were prepared by immersion in solutions with different concentrations of (CH₃COO)₂Cu and subjected to air-annealing at 400 °C, 500 °C, or 600 °C for 2 h. The complex characterization of all studied samples was performed using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), reflectance measurements, Mott–Schottky analyses, and photocurrent measurements. It was found that band gap engineering based on coupling CuO with TiO₂ (E_g~3.3 eV) is an effective strategy to increase the absorption in visible light due to band gap narrowing (CuO_x-TiO₂ materials had E_g~2.4 eV). Although the photoactivity of CuO-TiO₂ materials decreased in the UV range due to the deposition of CuO on the TiO₂ surface, in the Vis range increased up to 600 nm at the same time.     

Geodesic orbit and naturally reductive nilmanifolds associated with graphs

We study Riemannian nilmanifolds associated with graphs. We prove that such a nilmanifold is geodesic orbit if and only if it is naturally reductive if and only if its defining graph is the disjoint union of complete graphs and the left-invariant metric is generated by a certain naturally defined inner product.     

Numerical solution of a nonlinear parabolic control problem by a reduced SQP method

We consider a control problem for a nonlinear diffusion equation with boundary input that occurs when heating ceramic products in a kiln. We interpret this control problem as a constrained optimization problem, and we develop a reduced SQP method that presents for this problem a new and efficient approach of its numerical solution. As opposed to Newton's method for the unconstrained problem, where at each iteration the state must be computed from a set of nonlinear equations,in the proposed algorithm only the linearized state equations need to be solved. Furthermore, by use of a secant update formula, the calculation of exact second derivatives is avoided. In this way the algorithm achieves a substantial decrease in the total cost compared to the implementation of Newton's method in [2]. Our method is practicable with regard to storage requirements, and by choosing an appropriate representation for the null space of the Jacobian of the constraints we are able to exploit the sparsity pattern of the Jacobian in the course of the iteration. We conclude with a presentation of numerical examples that demonstrate the fast two-step superlinear convergence behavior of the method.     

两步液液萃取-固相萃取净化结合高效液相色谱-串联质谱法测定猪肉中11种磺胺类兽药残留

建立了猪肉中11种常见的磺胺类兽药残留的两步液液萃取-固相萃取净化-高效液相色谱-串联质谱（LC-MS/MS）检测方法。猪肉样品经乙酸乙酯（含2%（v/v）甲酸）及丙酮分两步液液萃取，正己烷脱脂，Oasis MCX混合阳离子固相萃取小柱净化，氮吹浓缩，定容，过滤膜后进行高效液相色谱-串联质谱分析。采用多反应监测正离子模式进行检测，以基质校准曲线外标法定量。结果表明，在20~400 μg/L范围内11种磺胺类药物均呈现良好的线性关系（相关系数（r²）≥ 0.99），检出限（LODs）（S/N=3）和定量限（LOQs）（S/N=10）分别为0.1~1.0 μg/kg和0.2~3.0 μg/kg。对阴性猪肉样品，在50、100、200 μg/kg 3个水平下分别进行加标回收试验，测得各待测物的平均回收率为79.3%~105.5%之间，相对标准偏差为1.3%~11.6%（n=6）。该方法比采用一步液液萃取法具有更高的提取效率，同时结合固相萃取净化方法进一步富集目标化合物，降低了基质干扰，提高了检测灵敏度。