定量体积排除色谱测定高分子双水相系统的组成和分子量分布

利用定量体积排除色谱研究葡聚糖-聚乙二醇双水相系统相分离后上下两相中2种高分子组分的含量、分子量和分子量分布.由定量体积排除色谱法得到的两相组成(即系线端点)与用浊点滴定法得到的浊点曲线几乎完全重合,二者仅在靠近临界点的聚乙二醇富集相有一定偏差.同时,利用体积排除色谱测得两相中葡聚糖和聚乙二醇的分子量和分子量分布.结果表明,由系线端点得到的体系两相共存线与浊点曲线的偏差是由于相分离过程中,不同分子量的高分子组分在两相的非均匀分配造成的.聚乙二醇分子量分布较窄,发生相分离后,在两相的分子量和分子量分布相差不大.而葡聚糖分子量分布较宽,在相分离后两相中的分子量和分子量分布具有较大差异,即葡聚糖组分在葡聚糖富集相中的分子量显著高于其在聚乙二醇富集相中的分子量.随着葡聚糖-聚乙二醇体系初始浓度的增加,两相中葡聚糖的分子量差异变大.定量体积排除色谱可以准确得到高分子双水相系统的相平衡数据及两相中2组分的分子量和分子量分布信息,其结果不仅为深入理解葡聚糖-聚乙二醇-水三元溶液的相平衡提供基础,而且为双水相系统在萃取分离中的应用提供理论指导.     

The flow structure of dilute gas-particle suspensions behind a shock wave moving along a flat surface

The asymptotic and numerical investigations of shock-induced boundary layers in gas-particle mixtures are presented.The Saffman lift force acting on a particle in a shear flow istaken into account.It is shown that particle migration across the boundary layer leads tointersections of particle trajectories.The corresponding modification of dusty gas model isproposed in this paper.The equations of two-phase sidewall boundary layer behind a shock wave moving at aconstant speed are obtained by using the method of matched asymptotic expansions.Themethod of the calculation of particle phase parameters in Lagrangian coordinates isdescribed in detail.Some numerical results for the case of small particle concentration aregiven.     

Stress concentration and stress intensity factors fop an infinite plane with several rows of elliptic holes and cracks

This paper deals with the stress concentration in plane with swveral arbitrarily distributed elliptic holes. By using the functions of complex variables, the stress functions in which the interactions of neighbouring holes are taken into consideration can be constructed. By applying the conformed mapping method to satisfy the boundary conditions of each hole, the governing equations can then be transformed into a set of simultaneous equations through boundary integrals. Moreover, the problems with crack can be derived by changing the elliptical rates of the ellipses, thereby an approximate solution of cracking problem may be obtained. Some computing examples are given in the paper.     

用改进的随机轨道模型数值模拟突扩液固两相流动

用改进的随机轨道模型数值模拟了突扩湍流液固两相流动。两相的轴向速度和湍动能的预报结果与实验符合得很好,同时还给出了不同计算截面上颗粒数密度和质量流量合理分布．预报结果对计算颗粒数敏感程度的研究表明：与通常的随机轨道不同,改进的随机轨道模型只需要很少的计算颗粒就可以给出合理正确的颗粒相分布。     

垂直并联管内高压汽水两相流压力降型脉动的研究

本文在宽广的参数范围内,对垂直并联管内高压汽水两相流压力降型脉动特性进行了试验研究,得出了系统参数对脉动起始点、周期和振幅的影响。根据两相流的均相模型,对压力降型脉动的周期和振幅进行了数值计算。此方法考虑了系统非线性的影响,与试验结果符合较好。     

气液两相瞬变流数值计算及试验研究

在气液两相流计算中,人们通常给出气泡在液体中均匀分布的,与工程实际不符的假设,致使计算与试验结果之间相差较大。两相瞬变流计算也常看作均质的单相流来处理．本文由试验求得不同空间系数与波逐关系曲线,取消了均匀分布假设,改进了特性曲线法以适用于非均质的两相流计算,并将计算值与试验值进行比较,结果表明两者吻合得较好。     

N80钢CO2腐蚀产物膜在水/砂两相流介质中的磨损性能

采用高温高压静态釜对N80油套钢在CO2中的腐蚀行为进行了模拟腐蚀试验;利用自制的磨损试验装置对比分析了腐蚀产物膜在水/砂两相介质中的磨损性能同成膜温度、CO2压力、流速及砂粒度之间的关系;用扫描电子显微镜分析了N80钢表面CO2腐蚀产物膜及其磨损表面形貌,用表面形貌仪测定了磨损试验前钢表面CO2腐蚀产物膜的粗糙度.结果表明:成膜温度和压力对钢表面腐蚀产物膜的表面粗糙度具有显著影响;N80钢表面CO2腐蚀产物膜磨损表面形貌沿深度方向存在差异,对应的抗磨性能亦有所不同;两相介质中的砂粒度越大或流体相对流速越大,则腐蚀膜的磨损越剧烈.     

分支通道内液-液自发渗吸规律研究

自发渗吸过程中两相界面在分支通道内的破裂和汇合为强非稳态过程, 难以用经典理论及常规数值计算方法准确描述。本文采用格子玻尔兹曼方法研究孔隙结构分支通道基本单元内的液-液自发渗吸行为, 对比出入口通道大小、两相黏度差异对液-液自发渗吸行为的影响。入口通道的大小对两相界面破裂进入分支通道内的竞争自发渗吸行为起控制作用, 而两相流体黏度控制了自发渗吸整体行为。本研究为复杂孔隙结构内液-液自发渗吸行为定量表征提供研究基础。     

The interaction of background ocean air bubbles with a surface ship

A two-fluid model suitable for the calculation of the two-phase flow field around a naval surface ship is presented. This model couples the Reynolds-averaged Navier–Stokes (RANS) equations with equations for the evolution of the gas-phase momentum, volume fraction and bubble number density, thereby allowing the multidimensional calculation of the two-phase flow for monodisperse variable size bubbles. The bubble field modifies the liquid solution through changes in the liquid mass and momentum conservation equations. The model is applied to the case of the scavenging of wind-induced sea-background bubbles by an unpropelled US Navy frigate under non-zero Froude number boundary conditions at the free surface. This is an important test case, because it can be simulated experimentally with a model-scale ship in a towing tank. A significant modification of the background bubble field is predicted in the wake of the ship, where bubble depletion occurs along with a reduction in the bubble size due to dissolution. This effect is due to lateral phase distribution phenomena and the generation of an upwelling plume in the near wake that brings smaller bubbles up to the surface. © 1998 John Wiley & Sons, Ltd.