Transamidation of Amides and Amidation of Esters by Selective N–C(O)/O–C(O) Cleavage Mediated by Air- and Moisture-Stable Half-Sandwich Nickel(II)–NHC Complexes

The formation of amide bonds represents one of the most fundamental processes in organic synthesis. Transition-metal-catalyzed activation of acyclic twisted amides has emerged as an increasingly powerful platform in synthesis. Herein, we report the transamidation of N-activated twisted amides by selective N–C(O) cleavage mediated by air- and moisture-stable half-sandwich Ni(II)–NHC (NHC = N-heterocyclic carbenes) complexes. We demonstrate that the readily available cyclopentadienyl complex, [CpNi(IPr)Cl] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene), promotes highly selective transamidation of the N–C(O) bond in twisted N-Boc amides with non-nucleophilic anilines. The reaction provides access to secondary anilides via the non-conventional amide bond-forming pathway. Furthermore, the amidation of activated phenolic and unactivated methyl esters mediated by [CpNi(IPr)Cl] is reported. This study sets the stage for the broad utilization of well-defined, air- and moisture-stable Ni(II)–NHC complexes in catalytic amide bond-forming protocols by unconventional C(acyl)–N and C(acyl)–O bond cleavage reactions.     

Effect of Particle Size on Electro-Optic Properties of Liquid Crystal Devices Doped with γ-Cyclodextrin Stabilized Barium Titanate Nanoparticles

Barium titanate stabilized by γ-cyclodextrin nanoparticles were prepared by using a microwave reactor equipped with ultrasonic nozzle mixing at 240°C in a tetraethylene glycol solution of barium ethoxide and titanium ethoxide in the presence of γ-cyclodextrin. Particles in γ-cyclodextrin-stabilized BaTiO₃ nanoparticles had an average diameter of 2.1 nm and mainly distributed within the range of about 1 to 4 nm. The γ-cyclodextrin-stabilized BaTiO₃ nanoparticles were mixed with 4-cyano-4′-pentylbiphenyl at room temperature resulting in a liquid crystal sol of 4-cyano-4′-pentylbiphenyl. The response time of liquid crystal devices in the presence of γ-cyclodextrin-stabilized BaTiO₃ nanoparticles was faster than that in the absence.     

高温超导线(带)材的研究进展

综述了高温超导线(带)材的最新研究进展。主要介绍了第一代铋系高温超导线材,第二代钇系高温超导涂层带材以及新型MgB2超导线材的研究现状,并探讨了其发展方向和研究重点。     

一种新型偶氮染料在扭曲向列相液晶显示取向中的应用

研究了一种新型偶氮材料sy03在光控取向中的应用。将sy03加入聚酰亚胺SE-3310(Nissan)与N,N-二甲基甲酰胺(DMF)的混合溶液中作为90°扭曲向列相液晶显示(Twisted nematic liquid crystal display,TN-LCD)的光取向材料,测量由它作为取向膜的扭曲向列型盒的电光特性与仅用SE-3310取向的扭曲向列型盒电光特性比较,发现sy03偶氮的加入使得扭曲向列型盒的响应时间短到98 ms、阈值电压也降低到1.7 V左右。而且随曝光时间的增加,响应时间和衬比度都有所提高,电光响应曲线也更为陡峭。加热到150℃后,其电光特性并没有明显变化,证明了它良好的热稳定性。最后通过测量偏振紫外吸收光谱,分析得出液晶分子易取向方向与激发光源偏振方向垂直。     

中药微量元素含量区间尺最佳分级问题的探讨

在深入研究中药微量元素含量区间尺的基础上，从统计学角度对区间尺的最佳分级问题作了详细探讨，提出用5级区间尺来衡量中药中不同元素含量间相对高低水平，理论上更合理。     

A Novel Coherent Multilevel Combined Phase and Polarization Shift Keying Modulation in Twisted Fibers

This article proposes a novel coherent multilevel modulation model that exploits polarization and phase of the field. This model is based on the possibility of coherent systems to use all the four degrees of freedom of the electromagnetic field. The proposed scheme is able, by applying a suitable twisting process to the optical fiber, to physically confine the polarization and the phase of the transmitted field within the phase sphere. In this way, with the same performances of existing systems, the receiver is considerably simplified because there is no longer need of birefringence tracking circuits.     

Electron Energies, Dipole Electric Moments, and Distribution of the Laurdan Molecule over the Conformation States of Methyl Groups

Using the methods of molecular simulation and HyperChem v.5.0 programs (PM3 method), we carried out calculations of the principal spectroscopic characteristics and of the structure of the laurdan molecule in the ground and the first excited electronic states. The thermal static distribution of molecules over various possible orientations of the plane of methyl groups relative to the plane of the naphthalene bicycle was taken into account. The energies and dipole moments of these electronic states have been calculated as functions of the torsion angle of methyl groups. The existence of an additional mechanism of electronic spectrum broadening is shown; it is associated with thermal mismatch of the equilibrium orientations of the rotational fragment of the molecule and with the dependence of the electron transition frequency on the degree of deviation of the angle from the equilibrium value. The dependence of dipole moments on this angle has been found and calculated. This dependence is the strongest for the ground state. The maximum values of dipole moments in the ground and excited states are 4.0 and 7.6 D.     

K1 of Twisted Rings of Polynomials

We prove that for an arbitrary endomorphism of a ring R the group K1(R[t]) splits into the direct sum of K1(R) and Ñil (r;). Moreover, for any such R and Ñil (R; ) is isomorphic to Ñil (R ; ) for some ring R with : R R – an isomorphism.     

On Some Rings of Arithmetical Functions

In this paper, we consider several constructions which from a given B-product * _B lead to another one We shall be interested in finding what algebraic properties of the ring are shared also by the ring . In particular, for some constructions the rings R _B and will be isomorphic and therefore have the same algebraic properties.     

Reduction of AC losses applying novel resistive interfilamentary carbonate barriers in multifilamentary Bi(2223) tapes

Hysteresis losses and coupling losses, a main component of the AC losses in Bi(2223) tapes, can effectively be reduced by enhancing the resistivity of the matrix material between the filaments and applying a filament twist. Since through alloying the sheath, as using AgAu(8 wt.%), the resistivity can only be raised by a factor <10 (77 K), a new conductor configuration with a quite novel composite matrix having resistive SrCO₃ barriers inside the Ag matrix between the filaments was developed. These new barriers, a cheap and commercial material, withstand the tape annealing, do not react with the superconductor, sinter dense and have a good bonding to Ag. Applying two different preparation techniques for 19 filament prototype tapes, critical current densities up to 20.7 kA cm⁻² were achieved. We report on tape preparation, the effect on the phase texture and the superconducting properties of such barrier tapes.