Synthesis of [Ring‐3H] Dopamine and Fluoro Analogues at High Specific Activity

Dopamine and several fluoro analogues were labeled with tritium at high specific activity by a catalytic tritium dehalogenation of polybromo precursors.     

Radiation effect of neutrons produced by D–D side reactions on a D–3He fusion reactor

One of the most important characteristics in D–³He fusion reactors is neutron production via D–D side reactions. The neutrons can activate structural material, degrading them and ultimately converting them into high-level radioactive waste, while it is really costly and difficult to remove them. The neutrons from a fusion reactor could also be used to make weapons-grade nuclear material, rendering such types of fusion reactors a serious proliferation hazard. A related problem is the presence of radioactive elements such as tritium in D–³He plasma, either as fuel for or as products of the nuclear reactions; substantial quantities of radioactive elements would not only pose a general health risk, but tritium in particular would also be another proliferation hazard. The problems of neutron radiation and radioactive element production are especially interconnected because both would result from the D–D side reaction. Therefore, the presentation approach for reducing neutrons via D–D nuclear side reactions in a D–³He fusion reactor is very important. For doing this research, energy losses and neutron power fraction in D–³He fusion reactors are investigated. Calculations show neutrons produced by the D–D nuclear side reaction could be reduced by changing to a more ³He-rich fuel mixture, but then the bremsstrahlung power loss fraction would increase in the D–³He fusion reactor.     

基于运行反馈的压水堆氚排放量研究北大核心CSCD

以压水堆核电厂中氚的产生机理和氚源项计算模型为基础,结合对国内外大量压水堆核电厂的氚排放运行数据的系统性分析,识别出冷却剂硼酸活化和次级中子源活化是压水堆氚排放量的主要来源,其中对中国广核集团运行机组,锑铍中子活化后的产氚量对氚年排放量的贡献可达到40%,而氚从完整的锆合金包壳的燃料棒中的释放是可以忽略不计的。由于优化次级中子源是降低压水堆氚排放量的唯一有效措施,通过分析建议压水堆核电厂采用双层不锈钢包壳的次级中子源或者取消次级中子源以降低压水堆氚排放。     

氚在锆合金包壳材料中的扩散行为模拟

基于氚扩散基本模型建立了氚扩散行为一维模拟程序,对模拟程序进行了典型实验验证,模拟结果与实验结果符合较好。分析了不同氚浓度、温度分布对锆合金包壳材料中氚的扩散行为的影响。分析结果表明：包壳-芯块间隙内氚浓度的升高会导致进出包壳的氚扩散通量提高,渗透通量增大;由于包壳氧化层相对较低的扩散系数,包壳氧化层的存在对氚渗透有较大的限制作用;温度对氚扩散速率的影响很显著,温度越高,扩散速度越快;锆合金外表面氧化层的相对低温限制了氚渗透出包壳管的速率,温度梯度导致的热致扩散有利于氚向包壳冷测扩散。     

随机填充增殖剂球床内载气流动特性数值模拟

固态氚增殖包层是聚变堆及聚变-裂变混合堆产氚包层的重要候选结构之一,其球床通道内载气流动特性将影响氚提取效率。利用离散元方法（DEM）生成随机填充增殖剂球床,通过径向孔隙率分布验证其合理性,计算流体力学（CFD）模拟计算其通道内气体流场特征。模拟得到：球床内吹扫氦气流速随孔隙率波动并随入口流速增大而均匀增大,通道内氦气流向及流速变化显著,Blake-Kozeny方程可良好预测该随机填充球床通道压降。     

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根据这几年HCCB-DEMO包层技术的发展,对原氦冷固态氚增殖包层进行相应设计改进.利用三维有限元软件CFX对该改进设计进行了热工水力学计算及分析.分析模型包括:第一壁,增殖单元,筋板以及三者集成模型.结果表明:各子部件在单独分析的情况下,材料最高温度低于设计要求限值;冷却剂进出口温度为300/500℃,满足设计需求.同时对比分析了集成计算及单独计算的结果,得出第一壁与铍球床之间的相互热作用较大,铍球床材料最大温度会高于设计限值.针对经集成计算后发现的问题,未来将对氦冷固态包层的设计进行进一步的优化.