LiF插层对有机发光二极管磁场效应的调控

制备了有LiF插层的有机发光二极管,以八羟基喹啉铝（Alq₃）作为电子传输层,N, N′-二苯基-N, N′-二(1-萘基)-1,1′-联苯-4,4′-二胺（NPB）作为空穴传输层.通过改变Alq₃与NPB间LiF插层的厚度,研究了不同温度下器件的光电特性及电致发光的磁场效应.测量结果表明:LiF插层可以影响器件内部载流子的输运和激发态的形成.较厚的插层阻碍了空穴的传输,使器件的电流效率变低.但实验中发现, 关键词： LiF插层结构 磁场效应 三重态激子     

PVK三线态激基复合物的发光及其受紫外光辐照的影响

用不同溶剂中的前驱物旋涂成PVK层,制备了ITO/PEDOT:PSS/PVK/Ca:Al器件,以及相同结构不同PVK分子量的器件。通过测试分析认为:器件的电致发光谱中590nm波长处的发光峰来自于PVK三线态的激基复合物,并且发现其强度依赖于PVK的分子构型,即在PVK分子中相邻咔唑基团重叠程度。通过比较不同紫外辐照剂量后的PVK器件的发光,发现适度的UV辐照后的PVK分子构型中相邻咔唑基团处于全重叠的状态增加,在电致发光时会形成更多的三线态激子,因而提高了PLED器件的发光效率。     

掺杂型有机电致发光二极管的研究进展

有机电致发光具有结构简单、成本低、平面光源、节省能源等优点,其中掺杂型电致发光二极管因可以同时利用单重态和三重态的激子来发光和理论上能使器件内量子效率达到100%而倍受关注。从掺杂型电致发光二极管发光机理、主体材料、掺杂剂材料、白光器件几个方面阐述了该领域的研究进展。     

Boundary relations and their Weyl families

The concepts of boundary relations and the corresponding Weyl families are introduced. Let be a closed symmetric linear operator or, more generally, a closed symmetric relation in a Hilbert space , let be an auxiliary Hilbert space, let

and let be defined analogously. A unitary relation from the Krein space to the Krein space is called a boundary relation for the adjoint if . The corresponding Weyl family is defined as the family of images of the defect subspaces , , under . Here need not be surjective and is even allowed to be multi-valued. While this leads to fruitful connections between certain classes of holomorphic families of linear relations on the complex Hilbert space and the class of unitary relations , it also generalizes the notion of so-called boundary value space and essentially extends the applicability of abstract boundary mappings in the connection of boundary value problems. Moreover, these new notions yield, for instance, the following realization theorem: every -valued maximal dissipative (for ) holomorphic family of linear relations is the Weyl family of a boundary relation, which is unique up to unitary equivalence if certain minimality conditions are satisfied. Further connections between analytic and spectral theoretical properties of Weyl families and geometric properties of boundary relations are investigated, and some applications are given.

     

Lepton-number-violating decays of singly-charged Higgs bosons in the type-（Ⅰ＋Ⅱ ） seesaw model

The lepton-number-violating decays of singly-charged Higgs bosons H^± are investigated in the minimal type-（ Ⅰ＋Ⅱ ） seesaw model with one SU（2）L Higgs triplet △ and one heavy Majorana neutrino N1 at the TeV scale. We find that the branching ratios B（H^＋ → 1α^＋υ^-） （for α = e,μ,τ） depend not only on the mass and mixing parameters of three light neutrinos υi （for i = 1, 2, 3） but also on those of N1. Assuming that the mass of N1 lies in the range of 200 GeV to 1 TeV, we figure out the generous interference bands for the contributions of υi and N1 to B（H^＋→ 1α^＋υ^-）. We illustrate some salient features of such interference effects by considering three typical mass patterns of υi, and show that the relevant Majorana CP-violating phases can affect the magnitudes of B（H^＋→ 1α^＋υ^-）） in this parameter region.     

Non-conservation of excitons in finite molecular chain

We have analyzed a linear molecular chain with exciton excitations when the number of excitons is not conserved. The dispersion law depends on two independent variables and it is surfaced in a 3D plot. The same conclusion is valid for the concentrations of excitons and exciton pairs. As it was expected, physical characteristics of the finite chain depend on spatial coordinates. All results are compared to the corresponding results of an infinite chain.     

Electron spin polarisation in the photoreduction of xanthone in alcohol: effect of concentration and temperature

Time-resolved EPR studies of the hydrogen abstraction reaction of photoexcited xanthone in 2-propanol were carried out as a function of the concentration of xanthone and the sample temperature. The temperature was varied from 22°C to about ?30°C, and the concentration from about 0.2 to 4.0?mM. At low temperature or concentration, the observed spectra of the xanthone ketyl radical and the propan-2-olyl radical could be simulated as a superposition of a hyperfine-independent component due to the emissive triplet mechanism and a hyperfine-dependent component due to the S–T₀ radical pair mechanism. However, with an increase in the concentration of xanthone, the relative contribution of TM decreases, and, concomitantly, the net absorptive component of only the xanthone ketyl radical increases. As the spin polarisation mechanisms do not predict any concentration dependence, this unusual behaviour is explained by invoking the enhancement of the spin–lattice relaxation rates due to Heisenberg spin exchange occurring at high local concentrations of the radicals. The net absorptive signal is attributed to thermally equilibrated radicals. The observed temperature dependence of the spin polarisation behaviour is similarly explained. The origin of the net absorptive signal in the TREPR spectra of the acetone?2-propanol system is also attributed to thermally equilibrated radicals. The self-quenching mechanism of xanthone is proposed to be an electron-transfer reaction from an excited xanthone molecule to another xanthone in the ground state.     

电场调谐InAs量子点荷电激子光学跃迁

在低温5 K下, 采用光致发光光谱及外加偏压调谐量子点电荷组态研究了InAs单量子点的精细结构和对应发光光谱的偏振性、不同带电荷激子的圆偏振特性. 得出如下结果: 1) 指认InAs单量子点中不同荷电激子的发光光谱和对应的激子本征态的偏振特性; 2) 外加偏压可以调谐量子点的荷电激子的发光光谱; 3) 伴随着电子、空穴的能量弛豫, 电子的自旋弛豫时间远大于空穴的自旋弛豫时间. 关键词： InAs量子点 激子 荧光光谱 电场调谐     

High-pressure spectroscopic studies of free and self-trapped excitons in alkali halides at low temperatures

Abstract

A brief survey of our studies of free and self-trapped excitons (FE and STE) in alkali halide crystals under hydrostatic pressure up to 12.5 kbar at 4.2–140 K is presented. Main attention is paid to the following effects observed: (1) the strong coupling of three energy levels of FE in CsI revealing itself as an exciton analog of pressure-scanned Fermi resonance; (2) emergence of a new emission band of STE in CsI under pressure; (3) a large pressure shift of the thermal quenching curve for STE emission in NaCl.