陶瓷材料疏水性能的研究进展

本文简述了疏水性表面的基本原理,分别从低表面能物质修饰和表面微细粗糙结构的构建两个方面,对疏水性陶瓷材料的制备技术和最新的成果进行了总结,介绍了其潜在的应用并对未来的研究方向作了展望.     

Paramagnetic Properties and Moderately RapidConformational Dynamics in the Cobalt(II) Calix[4]arene Complex by NMR

¹H NMR measurements are reported for the CD₂Cl₂/CDCl₃ solutions of the Co(II) calix[4]arenetetraphosphineoxide complex (I). Temperature dependences of the ¹H NMR spectra of I have been analyzed using the line shape analysis, taking into account the temperature variation of paramagnetic chemical shifts, within the frame of the dynamic NMR method. Conformational dynamics of the 2:1 Co(II) calix[4]arene complexes was conditioned by the pinched cone ↔pinched cone interconversion of I (with activation Gibbs energy ΔG^≠(298K) = 40 ± 3 kJ/mol. Due to substantial temperature dependence of paramagnetic shifts, complex I can be used as model compound for designing an NMR thermosensor reagent for local temperature monitoring.     

Numerical Study on Entropy Generation of the Multi-Stage Centrifugal Pump

The energy loss of the multi-stage centrifugal pump was investigated by numerical analysis using the entropy generation method with the RNG k-ε turbulence model. Entropy generation due to time-averaged motion and velocity fluctuation was mainly considered. It was found that the entropy generation of guide vanes and impellers account for 71.2% and 23.3% of the total entropy generation under the designed flow condition. The guide vanes are the main hydraulic loss domains and their entropy generation is about 9 W/K, followed by impellers. There are vortices at the tongue of the guide vane inlet as well as flow separations in the impellers, which lead to entropy generation. The fluid impacts the outer surface of the guide vanes, resulting in the increase in entropy generation. There are refluxes near the guide vane tongues which also increase the entropy generation of this part. The entropy generation distribution of the guide vanes and impellers was investigated, which found that the positive guide vane has more entropy generation compared with the reverse guide. The entropy generation of the blade suction surface is higher compared with the pressure surface. This study indicated that the entropy generation method has distinct advantages in the assessment of hydraulic loss.     

光阴极注入器型能量回收射频加速器

光阴极注入器型能量回收射频加速器（PERL）是新一代加速器,在高平均功率自由电子激光和下一代高亮度光源等研究中有很好的应用前景。分析了PERL的强流与高平均功率特性,对注入器输出束流品质的要求及光阴极注入器、超导加速腔等关键技术进行了研究,设计分析了一种特殊结构的高压DC Gun光阴极注入器,能有效地提高DC加速腔中的加速场强,当高压为1MV和加速场达到10MV/m时,产生的电子束流能够基本满足PERL应用要求。同一超导加速段中的束流加速和能量回收的数值模拟计算结果表明,能获得高效率电子束流能量回收效果。     

水合硼酸锶的制备及脱水热分解动力学

以氯化锶和硼酸氢铵为原料,采用液相沉淀法制备了片状水合硼酸锶（SrB6O10•5H2O）粉体,并用XRD、FT-IR及SEM进行了表征。利用热重分析法对片状纳米硼酸锶粉体的脱水热分解动力学进行了研究,分别采用 Coats- Redfern 方程和 Flynn-Wall-Ozawa（FWO）法对热重分析数据进行了处理和拟合,初步确定了水合硼酸锶的四步脱水过程及相应的热分解反应机理,得到各步反应的表观活化能和指前因子。     

Analysis of electron energy distribution function in a magnetically filtered complex plasma

The electron energy distribution function (EEDF) for a magnetically filtered dusty plasma is studied in a dusty double plasma device where the electron energy can be varied from 0.15 eV to ～ 2.8 eV and plasma density from 10 6 cm-3 to 10 9cm-3 . The characteristics of EEDF for these ranges of plasma parameters are investigated in a pristine plasma as well as in a dusty plasma. The results show that in the presence of dust, there is a drastic modification in EEDF patterns in a plasma with higher electron temperature and density than those in a low temperature and low density plasma produced by the magnetic filter.     

Fluid-Fluid Phase Separation by Molecular Dynamics

Abstract

Miscibility of several binary fluid systems, placed in an external gravitational field, has been studied by Molecular Dynamics calculation. The results show inmiscibility and phase separation to appear as a consequence of differences in the Lennard-Jones energy parameter of molecular interaction. Two situations are primarily considered: The case of a big difference in the energy parameters of pure components and the case of a weak interaction between unlike molecules.     

Phipps's lagrangian and hamiltonian

In this work it is derived Phipps's Lagrangian function and Phipps's Hamiltonian function. This allows the utilization of Phipps's interaction in the Lagrangian and Hamiltonian frameworks.Dedicated to Thomas E. Phipps, Jr. on the occasion of his 70th birthday (1995).     

Light level control in birefringent fibres through thermal stress effects caused by the absorption of broadside incident light: a single-ended fibre-optic system

In this paper, light level control is demonstrated using optically induced thermal stress effects in a polarization-maintaining optical fibre. The controlling light beam is absorbed by a blackened segment of the fibre and produces local heating. Light control is demonstrated in the single-ended sensor configuration, which displays a response that cannot be explained from phase delays only, but requires the addition of the coupled mode theory.