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101.
102.
103.
N-acetyltryptophan (NAT) has long been used as a stabilizer in some protein solutions, such as human serum albumin, to prevent oxidative protein degradation. However, the fate of NAT has not been discussed in literature. Two NAT degradation products have been observed in concentrated albumin solutions (20% and 25%) and identified as 1-acetyl-3a-hydroxy-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-2-carboxylic acid and 1-acetyl-3a,8a-dihydroxy-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-2-carboxylic acid. To monitor the levels of these two previously unidentified NAT degradation products in concentrated albumin solutions, a fully automated method, incorporating online size exclusion chromatography (SEC) trapping and reversed-phase high performance liquid chromatography-mass spectrometry (HPLC-MS) with multiple reaction monitoring (MRM) analysis, has been developed and validated for their quantitative analysis. The method does not require an internal standard. The only sample manipulation is to obtain an albumin concentration of 4% in all standards and test HPLC samples. A limit of quantitation (LOQ) as low as 20 ng/mL has been achieved for both compounds. This method can readily be adopted for the quantitative determination of other small molecules in concentrated protein solutions. 相似文献
104.
计及管道边界条件滑移的影响,研究微极流体蠕动泵,经由圆柱形管道输运的Stokes流动.壁面运动的控制方程为正弦波方程.使用润滑理论,得到了轴向速度、微转动向量、流函数、压力梯度、摩擦力和机械效率的解析数值解.用图形表示出构成参数,如像耦合参数、微极参数和表征蠕流泵特性的滑移参数、摩擦力和俘获现象的影响.数值计算表明,当耦合参数较大时,需要蠕动泵的压力更大,而微极参数和滑移参数正相反.俘获团块的大小随耦合参数和微极参数的减小而缩小,而随滑移参数的增大而缩小. 相似文献
105.
ABSTRACT On-line atom trapping inside a nickel flame furnace using chemical vapor generation for sample introduction was proposed for the determination of trace cadmium by flame atomic absorption spectrometry (AAS). Cadmium volatile species was generated upon reaction with potassium borohydride and then flushed into a flame furnace for on-line trapping by a flow of nitrogen carrier gas. The middle part of the flame furnace, where the carrier gas impacts, is cooled by the gas flow, and this provides a fine strategy for on-line atom trapping for the purpose of preconcentration. A stainless steel plate is put on the top of the flame burner in the middle to form a flame-free zone, which also greatly lowers the temperature of the flame furnace and facilitates the atom-trapping process. Due to the introduction of chemical vapor generation, matrix effect was greatly alleviated compared with direct pneumatic nebulization for on-line atom trapping in flame furnace AAS. With trapping time of 35 s, the current approach achieved an excellent limit of detection of 20 ng L?1. The proposed method was successfully applied for the quantification of cadmium in high-salinity samples. 相似文献
106.
对于硅薄膜太阳电池来说, 无论是PIN型还是NIP型太阳电池, 采用绒面陷光结构来提高入射光的有效利用率是提高太阳电池效率的重要方法之一.本文采用标度相干理论对PIN和NIP型电池的绒面结构的陷光性能进行了数值模拟. 结果表明: PIN电池中前电极和NIP电池中背电极衬底粗糙度分别为160和40 nm时可获得理想的陷光效果; 在不同粗糙度背电极衬底上制备a-SiGe:H电池发现, 使用40和61.5 nm 背电极可获得相当的短路电流密度, 理论分析和实验得到了一致的结果.
关键词:
陷光结构
光散射能力
标量相干理论
硅基薄膜太阳电池 相似文献
107.
K. Rerbal I. Solomon J.-N. Chazalviel F. Ozanam 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,51(1):61-64
We have investigated the temperature dependence of
photoluminescence in hydrogenated amorphous silicon-carbon alloys
a-Si1-xCx:H prepared by glow discharge in the low-power regime.
The radiative recombination process, due to photocarriers trapped on
band-edge states, is in competition with the thermal escape of the
photocarriers into the mobility bands. The model gives a quantitative fit
with experiment, without any adjustable parameter, provided the width of the
band-edge distribution of states is taken as the width of the conduction
band only (measured by “photo-induced infra-red spectroscopy”) and not as
the Urbach energy, as it is usually assumed. 相似文献
108.
C.F. Lo 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,1(1):93-95
Based upon the hidden Lie SU(1,1) symmetry, we have constructed the unitary decoupling transformation which diagonalizes the
multimode two-quantum Jaynes-Cummings model and provides us with an extremely convenient basis to gain a deeper understanding
of the dressing processes present in the matter-field interaction. This canonical transformation approach is very simple and
can be easily extended to other generalized Jaynes-Cummings models.
Received: 5 July 1997 / Revised: 3 November 1997 / Accepted: 14 November 1997 相似文献
109.
对聚焦光束通过有一定外加电场BaTiO3晶体时的自陷现象进行了理论分析,发现在正切割晶体中观察空间孤子是不合适的,因仅利用了很微小的电光系数γ33。对异型切割情况进行了讨论,给出了维持光束自陷的外加电场范围和实际观察的最佳角度。 相似文献
110.
M. Kajita 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(1):55-59
Collisions between linear polar molecules that were electrostatically trapped were investigated. The collisional transition
from a low to a high field seeking state (inelastic collision) causes trap loss. The efficiency of evaporative cooling is
improved at higher elastic collision rates. We calculated cross-sections of inelastic and elastic collision using a semi-classical
treatment.
Received 6 December 2001 / Received in final form 26 February 2002 Published
online 28 June 2002 相似文献