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111.
QiaoHongYAO FuYouLI LuSHAN ChunHuiHUANG DongDongYIN 《中国化学快报》2003,14(11):1185-1188
A new photoresponsive D-π-A dye, mPS, has been designed and synthesized.Compared to the parent dye PS, IPCE values in the region from 400 nm to 560 nm was greatly improved upon changing the attaching group from the p- position to the o- position of the π-conjugation bridge. A solar cell based on mPS generated a remarkably high overall yield η of 5.4% under irradiation of 80.0 mW cm^-2 white light from a Xe lamp, Compared with PS, the overall yield η increased by 64%. 相似文献
112.
In this paper we describe the experimental analysis of a novel ion-exchange polymer metal composite (IPMC) actuator under
large external voltage. The experimental analysis is supplemented with a coupled thermodynamic model, which includes mass
transport across the thickness of the polymer actuator, chemical reactions at boundaries, and deformation as a function of
the solvent (water) distribution. In this paper, the case of large electrode potentials (over 1.2 V) has been analyzed experimentally
and theoretically. At these voltage levels, electrochemical reactions take place at both electrodes. These are used in the
framework of overpotential theory to develop boundary conditions for the water transport in the bulk of polymer. The model
is then simplified to a three-component system comprised of a fixed negatively charged polymeric matrix, protons, and free
water molecules within the polymer matrix. Among these species, water molecules are considered to be the dominant species
responsible for the deformation of the IPMC actuators. Experiments conducted at different initial water contents are described
and discussed in the context of the proposed deformation mechanism. Comparison of numerical simulations with experimental
data shows good agreement. 相似文献
113.
Jacquelyn A. Carioscia Lauren Schneidewind Casey O'Brien Robert Ely Caitlin Feeser Neil Cramer Christopher N. Bowman 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5686-5696
The ability to prepare high Tg low shrinkage thiol–ene materials is attractive for applications such as coatings and dental restoratives. However, thiol and nonacrylated vinyl materials typically consist of a flexible backbone, limiting the utility of these polymers. Hence, it is of importance to synthesize and investigate thiol and vinyl materials of varying backbone chemistry and stiffness. Here, we investigate the effect of backbone chemistry and functionality of norbornene resins on polymerization kinetics and glass transition temperature (Tg) for several thiol–norbornene materials. Results indicate that Tgs as high as 94 °C are achievable in thiol–norbornene resins of appropriately controlled chemistry. Furthermore, both the backbone chemistry and the norbornene moiety are important factors in the development of high Tg materials. In particular, as much as a 70 °C increase in Tg was observed in a norbornene–thiol specimen when compared with a sample prepared using allyl ether monomer of analogous backbone chemistry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5686–5696, 2007 相似文献
114.
Stan J. Surma 《Logica Universalis》2007,1(1):209-219
The connection presented in this paper mirror-links two metamathematical structures, the finitary closure operators, and the
compact consistency properties, in such a way that a specification of one structure induces a provably equivalent specification
of the other.
Mathematics Subject Classification (2000): Primary 06A15, Secondary 28E10 03B22 相似文献
115.
从等离子体动力学方程出发,采用玻尔兹曼碰撞项,在粒子分布函数偏离麦克斯韦分布甚小的情况下,作三级矩近似得到了等离子体迁移方程组。迁移方程组中忽略时间微分项后,得出了电子-离子等离子体的张量形式迁移系数,以及与磁场方向成平行(∥)、垂直(⊥)和交叉方向的迁移系数。导出的结果和文献[1]采用朗道碰撞项得出的结果进行了比较。结果表明,迁移系数和等离子体参数的依赖关系是一致的,但对磁场B和离子电荷Z_i值取定时,个别迁移系数要差一倍。此外,导出的迁移系数形式比文献[1]的要简单些。 相似文献
116.
本文研究弱一致Opial条件的性质;弱一致Opial条件与弱一致Opial条件的对偶性;证明当对偶空间有弱一致Opial条件时该Banach空间具有不动点性. 相似文献
117.
本文讨论一般非均匀凸介质所确定的迁移算子的本征值的分布问题,利用Hilbert空间的H算子理论,完整地解决了一般非均匀凸介质中迁移算子本征值的分布问题,若{λn}n=1^∞是迁移算子本征值的一种计数,我们证明了Σ↓n=1↑∞e^6Reλnτ〈+∞,其中τ是粒子的最大逃逸时间,并对本征值的发散程度以及本征值的个数函数作了相应的讨论。 相似文献
118.
Li Chen Ling Hsiao Gerald Warnecke 《应用数学学报(英文版)》2007,23(1):9-28
This paper considers a kind of strongly coupled cross diffusion parabolic system,which can be usedas the multi-dimensional Lyumkis energy transport model in semiconductor science.The global existence andlarge time behavior are obtained for smooth solution to the initial boundary value problem.When the initialdata are a small perturbation of an isothermal stationary solution,the smooth solution of the problem under theinsulating boundary condition,converges to that stationary solution exponentially fast as time goes to infinity. 相似文献
119.
本文用超声相比较方法测定了高Tc超导体La1.85Sr0.15CuO4,La2CuO4和YBa2Cu3O7的纵波和横波声速,进而导出了它们的纵向模量、切变模量、杨氏模量、泊松比、德拜温度及定体比热。在La1.85Sr0.15CuO4样品上,还进行了压力实验,发现所有弹性模量都是随压强增加而增加。定体比热cV和泊松比σ在高压下则略有下降。德拜温度是随压强增加而增加的。 相似文献
120.
Cellulose carbamate, an environmentally friendly material presents an interesting alternative to petroleum-based polymers because of its renewable, biodegradable, biocompatible nature and its solubility in conventional solvents. In synthesis process of cellulose carbamate, urea was firstly impregnated into the cellulose pulp by supercritical CO2(scCO2), followed by the esterification of cellulose. The structure of cellulose carbamate was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The rheological properties of these cellulose carbamates in 9% sodium hydroxide solution were investigated, using a range of the nitrogen content, concentrations and shear rates. 相似文献