全文获取类型
收费全文 | 3322篇 |
免费 | 606篇 |
国内免费 | 819篇 |
专业分类
化学 | 2389篇 |
晶体学 | 27篇 |
力学 | 276篇 |
综合类 | 43篇 |
数学 | 162篇 |
物理学 | 1850篇 |
出版年
2024年 | 18篇 |
2023年 | 49篇 |
2022年 | 127篇 |
2021年 | 127篇 |
2020年 | 109篇 |
2019年 | 122篇 |
2018年 | 100篇 |
2017年 | 153篇 |
2016年 | 149篇 |
2015年 | 128篇 |
2014年 | 176篇 |
2013年 | 252篇 |
2012年 | 247篇 |
2011年 | 255篇 |
2010年 | 186篇 |
2009年 | 239篇 |
2008年 | 235篇 |
2007年 | 240篇 |
2006年 | 183篇 |
2005年 | 196篇 |
2004年 | 189篇 |
2003年 | 164篇 |
2002年 | 130篇 |
2001年 | 122篇 |
2000年 | 127篇 |
1999年 | 116篇 |
1998年 | 107篇 |
1997年 | 77篇 |
1996年 | 64篇 |
1995年 | 54篇 |
1994年 | 53篇 |
1993年 | 42篇 |
1992年 | 47篇 |
1991年 | 24篇 |
1990年 | 22篇 |
1989年 | 16篇 |
1988年 | 16篇 |
1987年 | 13篇 |
1986年 | 8篇 |
1985年 | 17篇 |
1984年 | 2篇 |
1983年 | 6篇 |
1982年 | 11篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1979年 | 13篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1973年 | 4篇 |
排序方式: 共有4747条查询结果,搜索用时 15 毫秒
51.
Calculation of the rotational barriers for the trans- and cis-forms of 2-(p-methoxy)-1-acetyl-pyrroline are presented in this paper. It is found that thetrans-isomer is slightly more favourable energetically, while the rotations of the cis-form are highly impeded. Hence the relevant rotations are in thetrans-form which stabilizes its energy by forming a weak inner proton bond between the carbonyl oxygen and the pyrroline ring. The acetyl rotational barrier is of the order of 8 kcal, which is well in accord with experimental data reported in the literature for other acetyl-amide derivatives.[/p]Work supported in part by Instituto Mexicano del Petróleo. 相似文献
52.
53.
A mathematical method for the calculation of the dead time (tm) in HPLC was evaluated using a computer simulation approach, in which artificial perturbations were introduced to Simulated homolog retention times. The calculation was based on a modified and extended Grobler and Bálisz (GB) method. Investigated wav how the precision of the calculated tM is affected by: statistical fluctuations in retention times and which, and how many homolog retention times are used. Based on these simulations a two-step procedure for the tM calculation is proposed: In the first step the linearity of log tR, n vs carbon number n is checked using as many homolog retention times as possible. The slope value bo of the first linear regression in the GB method is used for the selection of homolog retention times in the final tM calculation. In the second step the optimal selection of homologs is made and the final tM calculation is carried out. Guidelines for homolog selection are given. 相似文献
54.
B. F. Myasoedov L. A. Gribov A. I. Pavlyuchko I. V. Rybalchenko G. I. Sigeikin A. F. Kireev V. N. Suvorkin 《Journal of Structural Chemistry》2006,47(3):434-441
For highly toxic organophosphorus compounds on the limiting lists of the International Chemical Weapons Ban Treaty, fragment methods may be used for calculating their IR vibrational spectra; this is shown for O-alkyl alkylfluorophosphonates used as examples. The geometrical parameters and the parameters of the potential and electrooptic functions are found for the major fragments of these compounds. Due to this, fast predictive computation of IR spectra of O-alkyl alkylfluorophosphonates is possible, the accuracy of calculation being sufficient for spectral identification of these compounds; a database of the calculated IR spectra may be created. 相似文献
55.
Electrochemical properties of tetra(3,5-di-tert-butyl-4-hydroxyphenyl)dodecachlorophthalocyanine complexes of cobalt(II) and lutetium(III) in DMF solutions have been studied.
It was suggested that in the presence ofn-butyl bromide, the electrochemically generated monoanionic complexes undergo alkylation at the metal atom. The geometries
of the neutral and anionic complexes were calculated by the ZINDO/I semiempirical method.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 289–293, February, 1998. 相似文献
56.
A. Krauss 《Thermochimica Acta》2006,445(2):126-132
A transportable water calorimeter for the determination of the quantity of absorbed dose to water in radiotherapy beams has been developed at the PTB and is presented in detail in this investigation. Heat conduction effects occurring in the calorimeter are studied for different lateral sizes of high-energy photon beams, for different depth dose distributions of electron beams and for a scanned-beam irradiation with a heavy ion beam. The corresponding correction factors are calculated and arguments are given under which conditions these can adequately be applied. 相似文献
57.
简要总结了我们在C=C及C=O双键低温加氢双金属催化剂方面的最新研究成果. 首先, 我们以环己烯加氢为探针反应, 证明了平行使用多种研究手段的重要性, 包括单晶表面的基础研究与DFT计算, 多晶表面的合成与表征, 负载型催化剂的制备与性能测试等. 其次, 总结了双金属催化剂在其他加氢反应, 如丙烯醛C=O双键的选择性加氢, 苯的低温加氢, 以及乙炔的选择性加氢等反应中的应用. 最后, 讨论了利用金属碳化物代替贵金属Pt以减少双金属催化剂中Pt用量的可能性. 相似文献
58.
Using a very simple trial function and unperturbed electron densities calculated by a new procedure, the frequency-dependent dipole polarizability () of Ne, Ar, Kr and Xe has been calculated in the range 0 0.45 a.u., by a Karplus-Kolker-type variation-perturbation method. Results progressively worsen for larger systems so that, for Xe, (0) is only 75% of the experimental value. Probable reasons for this are discussed. 相似文献
59.
Tohru Nishinaga 《Tetrahedron》2004,60(15):3375-3382
A series of hexadehydro[18]annulenes fused with different numbers of p-benzoquinone, 4-6, were synthesized by stepwise transformation of the p-dimethoxybenzene moiety of the precursor dehydroannulene 3 fused with three 3,6-dimethoxy-4,5-dimethylbenzene units at 1,2-positions into p-benzoquinone using ceric ammonium nitrate. The UV-vis spectra of compounds 4 and 5, which have both electron-donating p-dimethoxybenzene unit(s) and electron-accepting p-benzoquinone unit(s) in the π-systems, showed the maximum absorption bands bathochromically shifted in comparison with 3 having only p-dimethoxybenzene units and 6 having only p-benzoquinone units. However, the solvatochromism expected for 4 and 5 was found to be quite weak possibly because the HOMO and LUMO (B3LYP/6-31G(d)) are not localized but rather delocalized over the whole π-systems. 相似文献
60.
Two methods are proposed, one for the location of saddle points and one for the calculation of steepest-descent paths on multidimensional surfaces. Both methods are based on a constrained simplex optimization technique that avoids the evaluation of gradients or second derivative matrices. Three chemical reactions of increasing structural complexity are studied within the PRDDO SCF approximation. Predicted properties of reaction hypersurfaces are in good overall agreement with those determined by gradient minimization and gradient following algorithms in connection with various ab initio SCF methods. Computational efforts required by the new procedures are discussed. 相似文献