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201.
Fast and accurate peanut allergen detection with nanobead enhanced optical fiber SPR biosensor 总被引:2,自引:0,他引:2
This paper is the first report of a fiber optic SPR biosensor with nanobead signal enhancement. We evaluated the system with a bioassay for the fast and accurate detection of peanut allergens in complex food matrices. Three approaches of an immunoassay to detect Ara h1 peanut allergens in chocolate candy bars were compared; a label-free assay, a secondary antibody sandwich assay and a nanobead enhanced assay. Although label-free detection is the most convenient, our results illustrate that functionalized nanobeads can offer a refined solution to improve the fiber SPR detection limit. By applying magnetite nanoparticles as a secondary label, the detection limit of the SPR bioassay for Ara h1 was improved by two orders of magnitude from 9 to 0.09 μg/mL. The super paramagnetic character of the nanoparticles ensured easy handling. The SPR fibers could be regenerated easily and one fiber could be reused for up to 35 times without loss of sensitivity. The results were benchmarked against a commercially available polyclonal ELISA kit. An excellent correlation was found between the Ara h1 concentrations obtained with the ELISA and the concentrations measured with the SPR fiber assay. In addition, with the SPR fiber we could measure the samples twice as fast as compared to the fastest ELISA protocol. Since the dipstick fiber has no need for microchannels that can become clogged, time consuming rinsing step could be avoided. The linear dynamic range of the presented sensor was between 0.1 and 2 μg/mL, which is considerably larger than the ELISA benchmark. 相似文献
202.
203.
Numerical integration formulas in n-dimensional Euclidean space of degree three are discussed. In this paper, for the product regions a method is presented to construct numerical integration formulas of degree three with 2n real points and positive weights. The presented problem is a little different from those dealt with by other authors. All the corresponding one-dimensional integrals can be different from each other and they are also nonsymmetrical. In this paper an n-dimensional numerical integration problem is turned into n one-dimensional moment problems, which simplifies the construction process. Some explicit numerical formulas are given. Furthermore, a more generalized numerical integration problem is considered, which will shed light on the final solution to the third degree numerical integration problem. 相似文献
204.
Wei LiuQimin Zhang 《Applied mathematics and computation》2011,218(8):3973-3980
In general, most of stochastic age-structured system of three species do not have explicit solutions, thus numerical approximation schemes are invaluable tools for exploring their properties. The aim of this paper is to investigate the convergence of numerical approximation solution to the true solution for stochastic age-structured system of three species. 相似文献
205.
结合实测数据,以三个对数正态分布函数的和函数为拟合函数,以梯度下降法为主要方法,对沉积物粒度分布进行了数据拟合,通过数值实验我们发现:利用梯度下降法可以有效地优化分布函数的各参数,实现拟合残差的稳步持续减小,具有良好的可操作性,拟合效果是令人满意的,它为我们进行数据拟合提供了一条新的思路,同时此方法也可以推广到解决其他极值问题. 相似文献
206.
L. U. Ancarani K. V. Rodriguez G. Gasaneo 《International journal of quantum chemistry》2011,111(15):4255-4265
n1,3S (n = 1 ? 4) states for atomic three‐body systems are studied with the Angular Correlated Configuration Interaction method. A recently proposed angularly correlated basis set is used to construct, simultaneously and with a single diagonalization, ground and excited states wave functions which: (i) satisfy exactly Kato cusp conditions at the two‐body coalescence points; (ii) involve only linear parameters; (iii) show a fast convergency rate for the energy; and (iv) form an orthogonal set. The efficiency of the method is illustrated by the study a variety of three‐body atomic systems [m m m] with two negatively charged light particles, with diverse masses m and m, and a heavy positively charged nucleus m. The calculated ground 11S and excited n1,3S (n = 2 ? 4) state energies are compared with those given in the literature, when available. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
207.
Hong‐Jian Wang Paul v. R. Schleyer Judy I. Wu Yan Wang Hai‐Jun Wang 《International journal of quantum chemistry》2011,111(5):1031-1038
The resonance energies (REs) of neutral three membered ring analogs of the cyclopropenyl cation, computed using block localized wave function (BLW) methods, reveal considerable variations. The RE's of cyclopropenes substituted with exocyclic double bonded groups C?X, (X = O, NH, CH2, S, PH, SiH2) increase with the electronegativity of X in the same row (SiH2 < PH < S and CH2 < NH < O). The extra cyclic resonance energies (ECREs) (an energetic measure of aromaticity based on comparisons with the RE's of acyclic models) of these derivatives range from +10.5 kcal/mol for cyclopropenone (X = O) (somewhat aromatic; the benzene ECRE is 29.3 kcal/mol) to ?2.4 kcal/mol (slightly antiaromatic) for X = SiH2. Additional disubstitution of the C?C double bond by X′ groups (X′ = CH3, NH2, OH, SiH3, PH2, SH) increases the REs considerably, but has only small effects on the ECREs. Even the ECRE of deltic acid (X = O, X′ = OH) is only increased to +13.3 kcal/mol. The conclusion based on ECRE's, that all 12 of the three membered rings are only marginally aromatic/antiaromatic, is supported by the satisfactorily plot (R2 = 0.92) of ECRE against values of NICS(0)πzz (a superior nucleus chemical independent shift magnetic index of aromaticity), which range only from ?6.1 ppm (diatropic) for deltic acid (cf., ?35.5 ppm for benzene and ?14.2 ppm for the parent cyclopropenium ion) to +8.9 ppm (paratropic) for the silicon derivative, X = SiH2, X′ = SiH3. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
208.
Several important examples of the N-wave equations are studied. These integrable equations can be linearized by formulation of the inverse scattering as a local Riemann-Hilbert problem (RHP). Several nontrivial reductions are presented. Such reductions can be applied to the generic N-wave equations but mainly the 3- and 4-wave interactions are presented as examples. Their one and two-soliton solutions are derived and their soliton interactions are analyzed. It is shown that additional reductions may lead to new types of soliton solutions. In particular the 4-wave equations with ?2 × ?2 reduction group allow breather-like solitons. Finally it is demonstrated that RHP with sewing function depending on three variables t, x and y provides some special solutions of the N-wave equations in three dimensions. 相似文献
209.
The relationship between the transmitting spectra characteristic of a fused single mode fiber coupler (SMFC) and the performance of interferometric fiber-optic gyroscope (IFOG) is analyzed in theory firstly. Then the transmitting spectra-temperature characteristic of SMFC is experimented, and the influence of the spectrum-stability of the SMFC on IFOG is simulated and experimented. Through the theory analysis and experiment research, it is confirmed that the spectrum output from the SMFC's throughput port is more stable than that output from the coupled port, and the bias instability of the rotation errors induced by the variation of spectrum output from the SMFC's coupled port is 10 times of that output from the throughput port. Therefore, to choose the SMFC's throughput port as the input port for navigation-grade gyroscope is an effective method to improve the IFOG's performance. 相似文献
210.
Single crystals of pure, Ca2+ and Sr2+ doped NH4Sb3F10 are grown by slow evaporation technique. The effect of dopants on the growth and physicochemical properties also have been investigated and reported for the first time. The grown crystals are characterized with the aid of single crystal X-ray diffractometry to confirm the crystal structure. EDAX studies are done to confirm the presence of dopants in the crystal lattice. The vibrational frequencies of various group ligands in the crystals have been derived from the Fourier transform infrared (FT-IR) spectrum. From the optical absorption spectrum the band gap energy was calculated and it was found to be 5.76, 6.29 and 6.35 eV for pure, Ca2+ and Sr2+ doped NH4Sb3F10 crystals respectively. Thermal stability of the sample has been analysed using TG-DTA analysis. The activation energy of pure, Ca2+ and Sr2+ doped NH4Sb3F10 crystals were calculated from the dc conductivity measurements and it is found to be 0.2728, 0.2816 and 0.3622 eV Experimental results shows improved physicochemical properties when the dopant is added to the pure material. 相似文献