理想气体在热力学中的作用

指出热力学理论是普遍的,不依赖于理想气体.理想气体为热力学理论提供了一个简单的实例,为测量热力学温度提供了一种简单的温度计.     

双氯芬酸钠与牛血清白蛋白结合反应的特征

在模拟人体生理条件下,采用荧光光谱和紫外 可见吸收光谱法研究了双氯芬酸钠与牛血清白蛋白的结合反应.实验结果显示,双氯芬酸钠对牛血清白蛋白有较强的荧光猝灭作用,该猝灭过程主要为静态荧光猝灭过程;二者结合常数KLB=2.167×105mol·L-1;二者的结合位置距212位色氨酸2.13nm;同时,由结合反应的热力学参数得出二者作用力主要是氢键或VanderWall's力.     

硅钨杂多酸与牛血红蛋白相互作用的研究

多金属氧酸盐作为抗艾滋病病毒、抗流感病毒和抗肿瘤的药物,引起了人们对多金属氧酸与蛋白质之间相互作用的极大关注。蛋白质空间结构的任何变化引起的构象变化都意味着蛋白质分子的活性改变,因此,蛋白质与内源性化合物及许多药物分子之间相互作用的研究一直受到人们关注[1￣3]。血红蛋白是动物及人体内执行输氧任务的蛋白质,是生命机体进行各种生理活动的主要承担者。血红蛋白分子中每条α链和β链含有的色氨酸(Trp)残基分别为α-14Trp、β-15Trp、β-37Trp。Alpert[4]等认为位于疏水腔内的β-37Trp是血红蛋白内源荧光的主要来源,同时β…     

Multi-element Saha–Boltzmann and Boltzmann plots in laser-induced plasmas

A multi-element Saha–Boltzmann plot method is proposed for the determination of the temperature and the relative number density in laser-induced plasmas, assuming local thermodynamic equilibrium and stoichiometry conservation. The method has been applied to the characterization of a plasma generated with a Cu–Fe–Ni–Mn alloy, using a Nd:YAG laser in air at atmospheric pressure. Spectra of the local emissivity have been obtained by spatial deconvolution of the intensity spectra, obtained with spatial resolution. Saha–Boltzmann plots obtained from the emissivities of 58 spectral lines of Fe I, Fe II, Ni I, Ni II, Mn I and Mn II have been fitted to linear behavior with high correlation, which shows the validity of the equation proposed. Radial distributions of the temperature and number densities of neutral atoms and ions have been determined. The results obtained reinforce the initial considerations of local thermodynamic equilibrium and conservation of stoichiometry. The proposed equation can also be applied to only one ionization species (multi-element Boltzmann plot). Spatially-integrated measurements of the plasma emission have also been performed to show that, in this case, the application of the method to the line intensities provides the two different apparent temperatures for neutral atoms and ions.     

Chemistry of borate in salt lake brine (XXXIV)

The crystallization processes of hydrated Mg-borates, boric, magnesium hydroxide and Mg-oxychloride from MgO-B₂O₃-18%MgCl₂-H₂O supersaturated solution at 20°C have been studied by kinetic method. The crystallization solid phases were characterized by X-ray powder diffraction, IR spectra, thermal analysis and chemical analysis. The liquid-solid phase diagram of thermodynamic nonequilibrium state has been given. In this phase diagram, there exist eight crystallization fields, boric acid(H₃BO₃), trigomagneborite(MgO · 3B₂O₃ · 7.5H₂O, MgO · 3B₂O₃ · 7H₂O), hungchaoite(MgO · 2B₂O₃ · 9H₂O), inderite(2MgO · 3B₂O₃ · 15H₂O), chloropinnoite(2MgO · 2B₂O₃ · MgCl₂ · 14H₂O), magnesium hydroxide(Mg(OH)₂) and magnesium oxychloride (5Mg(OH)₂ · MgCl₂ · 8H₂O).     

Thermodynamic properties of lithium chloride ammonia complexes for application inahigh-lifthigh temperature chemical heat pump

Ammonia absorption by and desorption from lithium chloride at different pressures has been studied using high-pressure differential scanning calorimetry, for application in a high-lift high temperature chemical heat pump. The measurements were performed under isobaric as well as under isothermal circumstances. Clausius–Clapeyron plots were constructed and used to calculate the thermodynamic parameters and to determine the stability regions of the different complexes. Controversies in literature as to the real existing phases are resolved.     

Intrinsic Flexibility of the Zeolitic Imidazolate Framework ZIF‐7 Unveiled by CO2 Adsorption and Hg Intrusion

ZIF‐7, built as an assembly of Zn^II centers and benzimidazolate ligands, shows prominent S‐shaped isotherms upon CO₂ adsorption that can be attributed to sorbate‐induced gate‐opening phenomena involving a narrow‐to‐large pore phase transition. This peculiar sorption pattern can be captured via the formulation of thermodynamic isotherms, providing a direct enthalpic and entropic view of the gate‐opening process. Relying on such an approach, an energy barrier with preferential enthalpic nature for CO₂ adsorption/desorption in the gate‐opening region could be unveiled. Moreover, the elastic energy involved during the gate‐opening process was revisited to 1.4–2.8 kJ mol^?1 of solid in the temperature range 273–323 K, matching the value measured by isostatic compression of a ZIF‐7_lp sample filled with DMF and showing a dominant entropic contribution.     

Entropy Generation for Negative Frictional Pressure Drop in Vertical Slug and Churn Flows

It is widely accepted that the frictional pressure drop is impossible to be negative for pipe flow. However, the negative frictional pressure drops were observed for some cases of two-phase slug and churn flows in pipes, challenging the general sense of thermodynamic irreversibility. In order to solve this puzzling problem, theoretical investigations were performed for the entropy generation in slug and churn flows. It is found that the frictional pressure drop along with a buoyancy-like term contributes to the entropy generation due to mechanical energy loss for steady, incompressible slug and churn flows in vertical and inclined pipes. Experiments were conducted in a vertical pipe with diameter as 0.04 m for slug and churn flows. Most of the experimental data obtained for frictional pressure drop are negative at high gas–liquid ratios from 100 to 10,000. Entropy generation rates were calculated from experimental data. The results show that the buoyancy-like term is positive and responsible for a major part of entropy generation rate while the frictional pressure drop is responsible for a little part of entropy generation rate, because of which the overall entropy generation due to mechanical energy loss is still positive even if the frictional pressure drop is negative in vertical slug and churn flows. It is clear that the negative frictional pressure drops observed in slug and churn flows are not against the thermodynamics irreversibility.     

Thermodynamic and Equilibrium Composition of Using Iron Oxide as an Oxygen Carrier Nonflame Combustion Technology Analysis in

本文介绍了一种新的燃烧体系--熔融盐循环热载体无烟燃烧技术。这种燃烧体系杜绝环境污染气体NOx和CO2的排放，可以实现真正零排放的目标。计算了以Fe2O3作为氧载体的无烟燃烧体系的热力学参数。用最小吉布斯自由能原则，分析了Fe2O3与CH4的平衡组成。分析表明，如果要想在产物中产生高纯度的CH4完全氧化产物CO2和H2O，Fe2O3与CH4必须达到高摩尔比，如果Fe2O3的量不足，就会产生较多的部分氧化产物如CO，H2甚至C