首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10859篇
  免费   1957篇
  国内免费   1424篇
化学   5603篇
晶体学   383篇
力学   1036篇
综合类   153篇
数学   551篇
物理学   6514篇
  2024年   16篇
  2023年   67篇
  2022年   223篇
  2021年   301篇
  2020年   271篇
  2019年   262篇
  2018年   303篇
  2017年   421篇
  2016年   486篇
  2015年   381篇
  2014年   527篇
  2013年   960篇
  2012年   728篇
  2011年   698篇
  2010年   649篇
  2009年   691篇
  2008年   648篇
  2007年   705篇
  2006年   628篇
  2005年   589篇
  2004年   547篇
  2003年   492篇
  2002年   419篇
  2001年   374篇
  2000年   386篇
  1999年   348篇
  1998年   266篇
  1997年   236篇
  1996年   219篇
  1995年   178篇
  1994年   150篇
  1993年   176篇
  1992年   151篇
  1991年   95篇
  1990年   98篇
  1989年   82篇
  1988年   100篇
  1987年   69篇
  1986年   49篇
  1985年   31篇
  1984年   25篇
  1983年   12篇
  1982年   33篇
  1981年   30篇
  1980年   21篇
  1979年   30篇
  1978年   21篇
  1977年   13篇
  1976年   10篇
  1973年   6篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
111.
In this paper, we introduce an affine scaling algorithm for semidefinite programming (SDP), and give an example of a semidefinite program such that the affine scaling algorithm converges to a non-optimal point. Both our program and its dual have interior feasible solutions and unique optimal solutions which satisfy strict complementarity, and they are non-degenerate everywhere.  相似文献   
112.
 本文用超声相比较方法测定了高Tc超导体La1.85Sr0.15CuO4,La2CuO4和YBa2Cu3O7的纵波和横波声速,进而导出了它们的纵向模量、切变模量、杨氏模量、泊松比、德拜温度及定体比热。在La1.85Sr0.15CuO4样品上,还进行了压力实验,发现所有弹性模量都是随压强增加而增加。定体比热cV和泊松比σ在高压下则略有下降。德拜温度是随压强增加而增加的。  相似文献   
113.
Conductive composite films of poly(styrene‐con‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007  相似文献   
114.
By the measurements of the solvent and temperature effects of the fluorescence emission spectra and lifetime of N-phenyl phenothiazine (PHZ) and N-(2-pyridine) phenothiazine (PYZ),the existence of strongly twisted intramolecular charge transfer (TICT) state in PYZ emission spectra is proved.The exciplex formed by PHZ, PYZ and dimethyl terephthalate (DMTP) is investigated, and moreover, the transient absorption spectra of positive and negative ions as the results of the dissociation of the exciplex in the polar solvents is observed through the flash photolysis.  相似文献   
115.
116.
A new flow electrical conductance instrument was constructed and tested on dilute NaCl solutions up to 458 K, and on more concentrated solutions (maximum 0.436 mol⋅kg−1) at 373 K. The results of the new instrument agreed with those of previous authors within the estimated experimental errors. The model of Bernard et al. (J. Phys. Chem. 96, 3833–3840 (1992), MSA) was found to represent the high-temperature results without introducing an ion-pairing equilibrium constant. The Fuoss–Hsia conductance equation as given by Fernandez-Prini was found to represent the dilute concentrations with Λ° (NaCl) as the only adjustable parameter. It was found that Λ° (NaCl) could be expressed as a function of solvent viscosity and density by using three parameters found by regression of literature results between 278.15 and 523 K. This equation along with the FHFP theory permits the equivalent conductivity of dilute sodium chloride solutions to be calculated within the accuracy of the existing experimental measurements.  相似文献   
117.
High temperature scanning tunneling spectroscopy (HT-STS) was used to investigate the electronic structure of Au(1 1 1) at different temperatures in the energy range 0-1 eV below the Fermi level. We concentrated on the influence of temperature on the Shockley surface state (SS) appearing on noble metals surface due to a surface projected bulk bang gap in [1 1 1] direction. The influence of temperature on the projected band gap edge (BE) was also investigated. The experiment was carried out in the temperature range 294-580 K. As the result of the experiment a delicate shift of the SS and the BE in direction of the Fermi level was reported.  相似文献   
118.
The thermal decomposition in non-isothermal conditions of formates, acetates, propionates and butyrates of Mn, Co, Zn, Cd, Eu, Sm and Ni was studied. The observed compensation effect allows us to calculate the isokinetic temperature. A selective activation mechanism was suggested. This leads to a good agreement between kinetic and spectroscopic data. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
119.
Transverse flow transversely excited (TFTE) CO2 lasers are easily scalable to multikilowatt level. The laser power can be scaled up by increasing the volumetric gas flow and discharge volume. It was observed in a TFTE CW CO2 laser having single row of pins as an anode and tubular cathode that the laser power was not increasing when the discharge volume and the gas volumetric flow were increased by increasing the electrode separation keeping the gas flow velocity constant. The discharge voltage too remained almost constant with the change of electrode separation at the same gas flow velocity. This necessitated revision of the scaling laws for designing this type of high power CO2 laser. Experimental results of laser performance for different electrode separations are discussed and the modifications in the scaling laws are presented.  相似文献   
120.
本文分析计算了荧光光纤温度传感器的温敏元件——GsAlAs/GaAs双异质结半导体材料的荧光辐射效率与激励光波长的关系。讨论了温度测量范围及温敏元件GaAlAs层铝含量对激励光源的限制,在0~200℃测温范围内,若采用LED作激励光源,其峰值波长应在0.70~0.76μm之间选择。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号