Amine‐blocked polyisocyanates. I. Synthesis of novel N‐methylaniline‐blocked polyisocyanates and deblocking studies using hot‐stage fourier transform infrared spectroscopy

A series of substituted N‐methylaniline‐blocked polyisocyanates based on 4,4′‐methylenebis(phenyl isocyanate) and poly(tetrahydrofuran) were prepared and characterized thoroughly with FTIR, ¹H NMR, and ¹³C NMR spectroscopy methods. Compared with unsubstituted N‐methylaniline, a blocking agent with an electron‐releasing substituent at the para position took a shorter time, whereas those with an electron‐releasing substituent at the ortho position or an electron‐withdrawing substituent at the ortho and para positions took longer times for the blocking reaction. The thermal dissociation reactions of blocked polyisocyanates were carried out with an FTIR spectrophotometer attached to hot‐stage accessories under dynamic and isothermal conditions. The dynamic method was used to determine the deblocking temperature, and the isothermal method was used to calculate the deblocking kinetics and activation parameters. The cure times of blocked polyisocyanates with hydroxyl‐terminated polybutadiene were also determined. The deblocking temperatures, the results of cure‐time studies, and the kinetic parameters revealed that the thermal dissociation of the N‐methylaniline‐blocked polyisocyanates was retarded by electron‐donating substituents and facilitated by electron‐withdrawing substituents. The action of N‐methylanilines as blocking agents for isocyanate was explained by the formation of a four‐center, intramolecularly hydrogen‐bonded ring structure during the thermal dissociation of the blocked polyisocyanates. The formation of such a hydrogen‐bonded ring structure was confirmed and supported by variable‐temperature ¹H NMR studies and entropy parameters, respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1557–1570, 2007     

On the limit cycles of a quintic planar vector field

This paper concerns the number and distributions of limit cycles in a Z_2-equivariant quintic planar vector field.25 limit cycles are found in this special planar polynomial system and four different configurations of these limit cycles are also given by using the methods of the bifurcation theory and the qualitative analysis of the differential equation.It can be concluded that H(5)≥25=5~2, where H(5)is the Hilbert number for quintic polynomial systems.The results obtained are useful to study the weakened 16th Hilbert problem.     

Pseudoaffinity, de Boor algorithm, and blossoms

In order to ensure existence of a de Boor algorithm (hence of a B-spline basis) in a given spline space with (n+1)-dimensional sections, it is important to be able to generate each spline by restriction to the diagonal of a symmetric function of n variables supposed to be pseudoaffine w.r. to each variable. We proved that a way to obtain these three properties (symmetry, n-pseudoaffinity, diagonal property) is to suppose the existence of blossoms on the set of admissible n-tuples, given that blossoms are defined in a geometric way by means of intersections of osculating flats. In the present paper, we examine the converse: do symmetry, n-pseudoaffinity, and diagonal property imply existence of blossoms?     

关于半线性热方程整体解的注记

利用Besov空间的热核刻画及压缩映射原理,研究半线性热方程ut-△u＝u|u|a的初值问题,得到了当初值u0∈Lp0(Rn)且||u0||(B·)p-n (1/p0-1/p),∞(Rn)(p0＝na/2,p＞p0)充分小时,整体解的存在性及在一定条件下解的惟一性.     

The equations of a holomorphic subspace in a complex Finsler space

In [Mu1] we underlined the motifs of holomorphic subspaces in a complex Finsler space: induced nonlinear connection, coupling connections, and the induced tangent and normal connections. In the present paper we investigate the equations of Gauss, H-and A-Codazzi, and Ricci equations of a holomorphic subspace. We deduce the link between the holomorphic curvatures of the Chern-Finsler connection and its induced tangent connection. Conditions for totally geodesic holomorphic subspaces are obtained. Communicated by János Szenthe     

Ag-Bi高温超导线材转变温度的测量

介绍了 Bi系银包套高温超导线材的电阻温度特性 ,用测电阻和电磁感应两种方法分别测量了材料的超导转变温度 ,电磁感应法测量曲线上台阶的出现表明材料中 Bi(2 2 2 3)和 Bi(2 2 12 )两相的存在。     

Separable anisotropic differential operators and applications

The nonlocal boundary value problems for anisotropic partial differential-operator equations with a dependent coefficients are studied. The principal parts of the appropriate generated differential operators are nonself-adjoint. Several conditions for the maximal regularity and the fredholmness in Banach-valued Lp-spaces of these problems are given. These results permit us to establish that the inverse of corresponding differential operators belongs to Schatten q-class. Some spectral properties of the operators are investigated. In applications, the nonlocal BVP's for quasielliptic partial differential equations and for systems of quasielliptic equations on cylindrical domain are studied.     

25MeV/u6He+9Be反应的轻粒子发射

在25MeV/u ⁶He与⁹Be靶的反应中,107°和128°处明显地观察到了轻粒子发射.粒子能谱形状与平衡热源蒸发相一致,分析得到热源的核温度为完全熔合条件下的5.6MeV或非完全熔合条件下的5.2MeV .实验发现发射氚的数量特别大,这可能与目前广泛研究的⁶He的集团结构和同位旋效应有关.     

On the Patterson–Sullivan Measure for Geometrically Finite Groups Acting on Complex or Quaternionic Hyperbolic Space

The goal of this paper is to provide a tool, the Global Measure Formula, that will facilitate the study of the limit set of discrete geometrically finite groups of isometries of the rank one symmetric spaces. We consider the shadow of a ball from a fixed reference point onto the boundary, and prove a formula that describes the measure of the shadow in terms of the center of the shadowed ball, generalizing a result from real hyperbolic geometry.     

不同温度均匀二半空间接触后产生的辐射场

 应用电磁线路中涨落耗散理论，推导了不同温度均匀二半空间接触后产生辐射场密度的公式。将此公式近似展开后，即得Grover和Urtiew所获得的表示式，不过多了一松弛项，该项如用非富里叶热传导理论推导，也是存在的。该结果和实验结果一致，不过这里的松驰时间可以应用介质性质进行计算。