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121.
四阶奇异摄动边值问题在自适应网格上的一致收敛分析 总被引:1,自引:0,他引:1
we study a difference scheme for the fourth-order singular pertur-bation differential equation on the Bakhvalov-Shishkin grid by Green‘‘s function.The method is shown to be uniformly convergent with respect to the perturbation parameter,of order N^-2 in the maxmum norm on Bakhvalov-Shishkin meshes.Numerical results support our theoretical results. 相似文献
122.
Ping Lin. 《Mathematics of Computation》2003,72(242):657-675
In many applications materials are modeled by a large number of particles (or atoms) where any one of particles interacts with all others. Near or nearest neighbor interaction is expected to be a good simplification of the full interaction in the engineering community. In this paper we shall analyze the approximate error between the solution of the simplified problem and that of the full-interaction problem so as to answer the question mathematically for a one-dimensional model. A few numerical methods have been designed in the engineering literature for the simplified model. Recently much attention has been paid to a finite-element-like quasicontinuum (QC) method which utilizes a mixed atomistic/continuum approximation model. No numerical analysis has been done yet. In the paper we shall estimate the error of the QC method for this one-dimensional model. Possible ill-posedness of the method and its modification are discussed as well.
123.
Some previous works show that symmetric fixed- and variable-stepsize linear multistep methods for second-order systems which do not have any parasitic root in their first characteristic polynomial give rise to a slow error growth with time when integrating reversible systems. In this paper, we give a technique to construct variable-stepsize symmetric methods from their fixed-stepsize counterparts, in such a way that the former have the same order as the latter. The order and symmetry of the integrators obtained is proved independently of the order of the underlying fixed-stepsize integrators. As this technique looks for efficiency, we concentrate on explicit linear multistep methods, which just make one function evaluation per step, and we offer some numerical comparisons with other one-step adaptive methods which also show a good long-term behaviour.
124.
通过几何过渡方法,结合重新标度连续概念,利用隐式曲面与参数曲面的各自等距曲面的交线,构成隐式曲面与参数曲面问的过渡面.用曲面的隐式与隐式、参数与参数形式,证明了所作的过渡面与给出的隐式曲面与参数曲面在连接线处是G^3连接的。 相似文献
125.
基于相对误差意义下的最小二乘法 总被引:5,自引:0,他引:5
最小二乘法一直广泛应用于科学技术各领域 ,但仅适用于等精度数据———因其评价依据是大致相同的绝对误差。而大多数科研及观测数据往往按被观测量的相对误差进行评价 ,即被观测量愈大 ,允许及实际测量误差也愈大。从这个意义上讲 ,若以相对拟合误差的平方和最小为条件 ,建立一套新的最小二乘法 ,那么当然可以期望新方法将具更广泛的用途和实际的意义。本文给出了新最小二乘法的实用结果 相似文献
126.
H. Ueba 《Surface science》2007,601(22):5212-5219
Adsorbate motions are discussed with a primary attention focused on the coupling between a vibrational mode excited by ultrafast laser heated hot-electrons or by inelastic tunneling electrons with scanning tunneling microscope and the reaction coordinate (RC) mode. Recent experimental results have demonstrated an efficient reaction pathways involving an indirect excitation of a frustrated translational mode, rather than its direct excitation for adsorbate hopping on surfaces. Elementary processes are briefly described for hopping of CO molecules on a laser heated stepped Pt surface, where excitation of the frustrated rotation mode has been found to plays an indispensable. Calculation of the inelastic tunneling current (ITC) for excitation of the C-O stretch mode of a CO molecule is combined with a theory of anharmonic mode coupling to activate the frustrated translation mode above the barrier. The hopping rate as a function of the bias voltage agrees with the experimental result. An unified theory of single-, and two-electron processes for ITC-induced motions induced by an indirect excitation of the RC-mode via mode coupling is also applied to reproduce a crossover from hopping to desorption of a single NH3 molecule on Cu(1 0 0) with an increase in the tunneling current. 相似文献
127.
Ailan Qu Xiufang Wen Pihui Pi Jiang Cheng Zhuoru Yang 《Applied Surface Science》2007,253(24):9430-9434
A superhydrophobic surface originated from quincunx-shape composite particles was obtained by utilizing the encapsulation and graft of silica particles to control the surface chemistry and morphology of the hybrid film. The composite particles make the surface of film form a composite interface with irregular binary structure to trap air between the substrate surface and the liquid droplets which plays an essential role in obtaining high water contact angle and low water contact angle hysteresis. The water contact angle on the hybrid film is determined to be 154 ± 2° and the contact angle hysteresis is less than 5°. This is expected to be a simple and practical method for preparing self-cleaning hydrophobic surfaces on large area. 相似文献
128.
The interactions between surfaces modified with grafted polymers is studied theoretically. The aim of this work is to find polymer surface modifications that will result in localized attractive interactions between the surfaces. The practical motivation of the work is to find means to control the distance between bilayers and solid supports in supported membranes. Two theoretical approaches are used, the analytical treatment of Alexander and a molecular theory. It is found that grafting each end of the polymer to each surface results in an interaction with a well defined minimum. The location of the minima is found to be very close to the thickness of the polymer layer when the chains are grafted to only one of the surfaces. The predictions of the analytical theory are in excellent agreement with the molecular approach in this case. It is found that increasing the surface coverage increases the strength of the interaction. However, increasing the polymer chain length at fixed surface coverage results in a decrease of the free energy cost associated with separating the surfaces from their optimal distance. For the cases in which grafting to both surfaces is not possible, the molecular theory is used to study the effect of functionalizing segments of the chain to achieve an attractive well. It is found that by functionalizing the free end-groups of the polymers with segments attracted to the membrane, the range of the attractive interaction is significantly larger than the thickness of the unperturbed layer. Functionlizing the middle segments of the chains results in a shorter range attraction but of the same strength as in the end-functionalized layers. The optimal polymer modification is found to be such that the functionlized groups are attracted to the bare surface but are not attracted to the grafting surface. The relevance of the results to the design of experimental surface modifiers is discussed. 相似文献
129.
We study phase separation in a system of hard-core particles driven by a fluctuating two-dimensional self-affine potential landscape which evolves through Kardar–Parisi–Zhang (KPZ) dynamics. We find that particles tend to cluster together on a length scale which grows in time. The final phase-separated steady state is characterized by an unusual cusp singularity in the scaled correlation function and a broad distribution for the order parameter. Unlike the one-dimensional case studied earlier, the cluster-size distribution is asymmetric between particles and holes, reflecting the broken reflection symmetry of the KPZ dynamics, and has a contribution from an infinite cluster in addition to a power law part. A study of the surface in terms of coarse-grained depth variables helps understand many of these features. 相似文献
130.