Summary: A rather simple but yet effective way to achieve a superhydrophobic film by extending a Teflon film is proposed. The water‐contact angle can be increased from 118 to 165° by extending to ca. 190%. The fibrous crystals and the increasing distance between the fibrous crystals are believed responsible for the high water‐contact angle. It indicates that the density of the aligned microstructures is very important for the superhydrophobicity.
Water‐contact angle and the corresponding shapes of water droplets as a function of extension ratio of Teflon tape. 相似文献
With the aim of creating a new avenue for the real applications of the superhydrophobic surface, we succeeded in fabricating metal hexadecanoate (e.g., zinc hexadecanoate) based superhydrophobic coatings on virtually any substrates by the simple spray-coating. Hierarchical rough surface morphology was achieved on the coating with the contact angle of about 160° and the sliding angle of about 6°. The advantages of the present approach include the cheap raw materials, environmentally benign solvents, an industrial implementation method, and easy repairability and applicability so as to make a great application potential in practice. Water repellency of the fabricated coating was demonstrated by visible experiment results and contact angle measurements. The robustness and repairability of the superhydrophobic coating were also investigated by the designed experiments. 相似文献
In order to produce pH‐ and voltage‐switchable superhydrophobic surfaces, PEDOT derivatives containing various proportions of a EDOT monomer containing carboxylic groups (EDOT? COOH) and EDOT monomer‐containing dodecyl chains (EDOT? O? H12) are elaborated. The surface morphology and roughness depend highly on the proportion of the monomers. Superhydrophobic properties are reached for a mol % of EDOT? COOH between 0 and 25 %. It is possible to switch from superhydrophobic to hydrophilic (θwater until about 45°) by electrochemical reduction at low voltage (?1 V vs SCE) to remove the doping anions, following by treatment with NaOH to change the carboxylic groups into carboxylate. By elaborating smooth surfaces of each polymer, the effect of each treatment is reported. The reversibility of the reactions is also reported. 相似文献
The robust nonsticky superhydrophobicity of aligned nanoneedle films is reported. A facile, efficient, cheap, and available method based on the diffusion‐limited crystal growth principle is proposed for controlling the tapering of ZnO nanorods, the profiles of which can be tuned effectively by synergetic control over reaction time and temperature in an extremely strong alkaline reaction system. The synthesized nanoneedle, nanopencil, and nanorod arrays are chosen for studying the effects of nanoscale topography on anti‐droplet‐sticking ability. After silanization, all of them show excellent quasi‐static anti‐droplet‐stickiness, and water adhesion along the normal and lateral directions can be greatly reduced by the tapering of nanorods and eliminated by sharp nanoneedles. However, their antisticking stability is distinct under the droplet impact: the nanoneedle sample is still nonsticky but the nanorod sample loses its antisticking ability. Only ensuring the liquid/air interface is in the suspended nonwetting state is insufficient to obtain robust nonsticky surfaces, which also require extremely low solid–liquid van der Waals attraction. 相似文献