Environmentally green approach to synthesize azo dyes based on 1-naphthol using nano BF3·SiO2 under solvent-free conditions

A series of azo dyes were efficiently synthesized by mixing aromatic amines and NaNO₂ in the presence of nano silica supported boron trifluoride (nano BF₃·SiO₂) and then diazo coupling with 1-naphthol under solvent-free conditions at room temperature. The present methodology has proven to be simple, rapid, environmentally benign, green, and cost-effective compared with previous synthetic methods. Also, by using this procedure, aryl diazonium salts supported on nano BF₃·SiO₂ were very stable to be kept at room temperature for several months without any special conditions.     

超光滑加工精磨过程中损伤层与余量匹配的研究

对超光滑加工散粒研磨工序中采用的三级精磨法,进行了实验研究,通过改进差分化学刻蚀实验测出各级损伤层的厚度,利用损伤层厚度对加工余量匹配进行了优化。研究表明损伤层厚度与砂粒的粒径和压载之积成线性关系,与研磨时长无关;实验测得W28、W10、W5号磨料在实验条件下研磨加工产生的损伤层厚度分别为12.4μm、8.2μm、5.8μm;并根据损伤层厚度提出了加工余量的匹配建议方案。损伤层的相关研究为超光滑加工中提高生产效率以及减少麻点产生几率的研究提供了参考。     

Luminescent Mechanochromic Porous Coordination Polymers

Three 2D luminescent isomeric porous coordination polymers are synthesized and characterized. Their luminescence properties can be modified by grinding and they can act as mechanochromic materials and their properties are probably related to the weak interactions of cuprophilicity and π–π interactions.     

特殊工件磨削加工问题研究

对特殊工件的磨削加工过程进行抽象、建模和求解.将砂轮和底座看成刚性坐标系,将工件所在的下台、中台、上台看成可平移旋转的变换坐标系,基于工件母线方程,以砂轮和工件母线相切为紧约束,运用平面坐标变换理论设计加工方案,并对方案进行了误差分析,最后考虑砂轮的实际磨损,分别提出圆柱形和轮式砂轮修整磨削策略.     

Substructure of Titanium Dioxide Agglomerates from Dry Ball-milling Experiments

The calciner discharge of TiO₂ white pigments from the sulphate process is ground batchwise in a planetary ball mill, varying the energy of comminution between 0 and 5.1 times the earth's gravitational constant. Particle sizes and specific surfaces of the ground products reveal that the calciner discharge consists of aggregates of 430nm diameter built from 160–210nm TiO₂ crystals. The contact area of a primary particle in an aggregate is about 15% of its surface. The success in comminution of aggregates as a function of grinding energy follows Kick's law. The theory by Rose and Weichert is used to quantify the mechanical strength of the aggregates. Ca. 20% of the aggregates are further agglomerated to granules of ca. 35µm. At all energy levels above a certain threshold, agglomerates break directly into aggregates.     

数字光处理背投电视色度学特性的研究

以色度学的基本理论为基础,结合数字光处理光学引擎的工作原理,探讨了单片式数字光处理光学引擎的彩色显示原理和色温调节原理.提出了单片式数字光处理光学引擎色度学特性的理论计算公式,并利用该公式对夏新DL52HWT型投影电视光学引擎的显示三原色色度坐标、白场平衡的色度坐标和相关色温以及颜色复现误差等色度学特性进行了计算和分析,并对理论计算公式进行了验证.     

Efficient algorithms for machine scheduling problems with earliness and tardiness penalties

In this paper, we study the multi-machine scheduling problem with earliness and tardiness penalties and sequence dependent setup times. This problem can be decomposed into two subproblems—sequencing and timetabling. Sequencing focuses on assigning each job to a fixed machine and determine the job sequence on each machine. We call such assignment a semi-schedule. Timetabling focuses on finding an executable schedule from the semi-schedule via idle-time insertion. Sequencing is strongly NP-hard in general. Although timetabling is polynomial-time solvable, it can become a computational bottleneck if the procedure is executed many times within a larger framework. This paper makes two contributions. We first propose a quantum improvement to the computational efficiency of the timetabling algorithm. We then apply it within a squeaky wheel optimization framework to solve the sequencing and overall problem. Finally, we demonstrate the strength of our proposed algorithms by experiments.     

基于水滑石前驱体制备ZnCr_2O_4-ZnO复合光催化剂及产氢性能

以研磨水热法合成ZnCr_2O_4-ZnO异质结型光催化剂,对所得样品进行了TG-DTA、XRD、SEM、HRTEM、DRS和N2吸附-脱附表征分析;在模拟太阳光下,以草酸为牺牲剂对样品的光催化产氢活性进行评价,并分别与共沉淀法、尿素回流法和尿素水热法制备的ZnCr_2O_4-ZnO样品进行比较,探讨了异质结型ZnCr_2O_4-ZnO复合光催化剂的产氢机理。结果表明,四种方法制备的Zn-Cr前驱体都具有一定的水滑石结构,经500℃焙烧后,均为球形纳米粒子,但团聚情况各异,比表面积和孔结构参数有较大差别。其中,研磨水热法所得样品ZnCr_2O_4-ZnO粒子均匀,光电流响应强度最大,产氢效率最高,为0.956 mmol/(h·gcat),分别是共沉淀法、尿素回流法和尿素水热法制备样品产氢量的2.3、1.5和3.0倍。     

五轴加工中心范成铣磨离轴非球面研究

离轴非球面作为非球面的一部分,是空间光学系统、天文学和高精度测量系统不可或缺的光学器件.针对空间光学对离轴非球面光学元件制造技术的重大需求,开展了离轴非球面反射镜的精密铣磨加工技术研究.分析了五轴联动范成法铣磨离轴非球面的原理,将离轴非球面所在的同轴母镜离散为一系列不同半径的球面环带,将工件坐标系建立在待加工离轴非球面...     

多模跟踪技术在轮式侦察车图像处理器的应用

为解决目标旋转形变、遮挡、光照变化等目标跟踪的难题,对粒子滤波和尺度不变特征变换（SIFT）算法进行了改进,结合两种算法提出了决策主导模式的多模跟踪技术。该技术采用粒子滤波预测目标位置进行粗定位,SIFT特征匹配进行精定位的方法,在解决上述难题上有很好的鲁棒性。将该技术应用于轮式侦察车图像处理器,并进行了各种实验验证,结果证明了提出算法的有效性。