全文获取类型
收费全文 | 9320篇 |
免费 | 1156篇 |
国内免费 | 494篇 |
专业分类
化学 | 6419篇 |
晶体学 | 81篇 |
力学 | 513篇 |
综合类 | 45篇 |
数学 | 496篇 |
物理学 | 3416篇 |
出版年
2024年 | 10篇 |
2023年 | 78篇 |
2022年 | 180篇 |
2021年 | 205篇 |
2020年 | 251篇 |
2019年 | 284篇 |
2018年 | 228篇 |
2017年 | 227篇 |
2016年 | 384篇 |
2015年 | 320篇 |
2014年 | 413篇 |
2013年 | 839篇 |
2012年 | 469篇 |
2011年 | 529篇 |
2010年 | 428篇 |
2009年 | 526篇 |
2008年 | 559篇 |
2007年 | 609篇 |
2006年 | 563篇 |
2005年 | 416篇 |
2004年 | 455篇 |
2003年 | 438篇 |
2002年 | 360篇 |
2001年 | 263篇 |
2000年 | 269篇 |
1999年 | 204篇 |
1998年 | 239篇 |
1997年 | 138篇 |
1996年 | 137篇 |
1995年 | 110篇 |
1994年 | 120篇 |
1993年 | 94篇 |
1992年 | 84篇 |
1991年 | 64篇 |
1990年 | 46篇 |
1989年 | 70篇 |
1988年 | 54篇 |
1987年 | 37篇 |
1986年 | 30篇 |
1985年 | 25篇 |
1984年 | 40篇 |
1983年 | 16篇 |
1982年 | 31篇 |
1981年 | 21篇 |
1980年 | 17篇 |
1979年 | 21篇 |
1978年 | 16篇 |
1977年 | 9篇 |
1976年 | 13篇 |
1973年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
延迟和相关效应对Ne原子2p53s1,3P10-2p6 1S0跃迁的影响 总被引:1,自引:0,他引:1
利用多组态Dirac-Fock(MCDF)方法,系统地研究了延迟和相关效应对中性Ne原子2p53s1,3P01-2p61S0电偶极共振和复合跃迁的能量以及跃迁几率(寿命)的影响,给出了相应的跃迁能和辐射寿命,并与最新的实验观测和其他理论计算结果进行了比较. 相似文献
42.
T.M. Mishonov N. Chéenne D. Robbes J.O. Indekeu 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(3):291-296
The generation of harmonics of the voltage response is considered when an AC current is applied through a superconducting
film above Tc. It is shown that almost at all temperatures the mechanism of the temperature oscillations created by the AC current and
the temperature dependence of the resistance dominates over the isothermal nonlinear electric conductivity. Only in a narrow
critical region close to Tc the latter is essential for the generation of the harmonics. A detailed investigation of harmonics generation provides an
accurate method for measuring the thermal boundary conductance between the film and the insulating substrate. The critical
behaviour of the third harmonic will give a new method for the determination of the lifetime of metastable Cooper pairs above
Tc. The comparison of the calculated fifth harmonics of the voltage with the experiment is proposed as an important test for
the applicability of the employed theoretical models.
Received 8 September 2001 相似文献
43.
S. Zschocke G. Plunien G. Soff 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,19(2):147-156
The renormalization method of Bogoljubov-Parasiuk-Hepp-Zimmermann (BPHZ) is used in order to derive the renormalized energy
shift due to the gauge invariant K?llén-Sabry diagram of the two-photon vacuum polarization (VPVP) as well as the self energy
vacuum polarization S(VP)E beyond the Uehling approximation. It is outlined, that no outer renormalization is required for
the two-photon vacuum polarization and that only the inner renormalization has to be accomplished. It is shown that the so-called
nongauge invariant spurious term is absent for a wide class of vacuum polarization (VP) diagrams if one applies the widely
used spherical expansion of bound and free-electron propagator. This simplifies significantly calculations in bound state
quantum electrodynamics. As one result of our paper the use of the BPHZ-approach in bound state QED is established.
Received 28 September 2001 相似文献
44.
A. Shaporenko A. Terfort M. Grunze M. Zharnikov 《Journal of Electron Spectroscopy and Related Phenomena》2006
Analysis of photoemission spectra of complex thioaromatic self-assembled monolayers (SAMs) requires the knowledge and understanding of such spectra for the basic systems. Keeping this goal in mind, synchrotron-based high-resolution X-ray photoelectron spectroscopy was used to characterize SAMs formed from the simplest thioaromatic compounds, namely thiophenol, 1,1′-biphenyl-4-thiol and 1,1′;4′,1″-terphenyl-4-thiol on evaporated Au(1 1 1) and Ag(1 1 1) substrates. The acquired S 2p and C 1s spectra were analyzed in terms of fine structure and initial and final state effects in the photoemission process. The assignment of the individual spectral features was considered in detail. Conclusions on quality and chemical and structural homogeneity of the investigated SAMs were derived. 相似文献
45.
S.A. Masti A.K. Sharma P.N. Vasambekar A.S. Vaingankar 《Journal of magnetism and magnetic materials》2006
Magnetization and permeability of polycrystalline ferrites with general formula CdxMg1−xFe2−yCryO4 (x=0, 0.2, 0.4, 0.6, 0.8, 1.0; y=0, 0.05 and 0.10) were studied. Study of saturation magnetization reveals that the Neel's two-sublattice model exists upto x=0.4, for y=0, 0.05 and 0.1 and a three-sublattice model (YK-model) is predominant for x>0.4 and y=0, 0.05 and 0.10. The saturation magnetization and magnetic moment were found to decrease with the increase in Cr3+ contents, which is attributed to the dilution of B–B site interaction. Variation of initial permeability with temperature revealed the long-range ferromagnetic ordering in the compounds with x=0.4. The sample with x?0.4 and y=0, 0.05 and 0.10 showed peaking behavior near Curie temperature, which is attributed to the decrease of anisotropy constant K1 to zero. Low-frequency dispersion of initial permeability suggests domain wall displacement. Addition of Cd2+ resulted in a sharp decrease in Curie temperature. With the addition of Cr3+, initial permeability was found to decrease. 相似文献
46.
Hongrui Zhang Mingju Chao Mingyi Gao Liwen Zhang Jianquan Yao 《Optics & Laser Technology》2003,35(6):573-449
A fiber-coupled diode-single-end-pumped Nd:YVO4 laser with an Nd:YVO4 crystal of 0.3 at% doping concentration and 3×3×10 mm3 dimensions was reported. 14.850 W of continuous-wave output power in an M2 factor of 1.12 was obtained under pump power of 27.365 W, with an optical conversion efficiency of 60.49%, and a slope efficiency of 64.5%. 相似文献
47.
A new type of phosphino-phosphonium ylide ligand bearing a chiral sulfinyl center affords a P,C-chelated palladium(II) complex with a resolved asymmetric ylidic carbon atom. According to 31P NMR analysis of the crude material, the diastereoselectivity of the complexation at room temperature is ca. 7:1. In the crystal state, an X-ray diffraction analysis of one epimer reveals a quasi C2-symmetric chloro-bridged dinuclear structure, where the (S) configuration of the sulfur atom induces a (S) configuration of the ylidic carbon atom. A in situ Pd(0) catalyst generated from the phosphino-ylide and Pd(PPh3)4 promotes allylic substitution of 3-acetoxy-1,3-diphenylpropene by sodium malonate in 70% yield and 5% e.e. 相似文献
48.
Margherita De RosaMaria Rosaria Acocella Rosaria VillanoAnnunziata Soriente Arrigo Scettri 《Tetrahedron letters》2003,44(32):6087-6090
Initial concentration of enantioenriched or enantiopure catalysts proved to be an important factor for the achievement of a more pronounced amplification of ee's in the Ti(IV)/BINOL-catalyzed aldol reaction of an O-silyldienolate. 相似文献
49.
N. S. Kazak E. G. Katranji I. A. Utkin A. A. Ryzhevich A. N. Khilo 《Journal of Applied Spectroscopy》2004,71(5):697-701
The phenomenon of self-diffraction of Bessel light beams (BLB) in a nonlinear liquid medium has been studied experimentally and theoretically for the first time. Diffraction maxima which do not correspond to integer orders for an induced periodic structure have been registered. It has been shown that the appearance of these maxima is due to the initial BLB modulation, which can be caused by the departure of the axicon refracting surface from the ideal conical surface, as well as by the imperfection of the form of the Gaussian beam incident on the axicon. 相似文献
50.
本文利用比较原理以及一种特殊变换研究了一类非线性退化方程的混合问题,得到了这类复杂问题解的渐进性质。 相似文献