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在脉冲梯度场基础上研究了进一步缩短COSY类2D NMR实验数据采集时间的新方法.利用主动屏蔽梯度场线圈的梯度场恢复时间仅为100μs数量级这一特点,提出一类基于脉冲梯度场消除弛豫假峰的脉冲序列.并以DQF-COSY脉冲序列为例加以验证.实验结果表明:采用文中的方法,取序列重复时间远小于T1和T2是切实可行的;梯度场技术能很好地抑制弛豫假蜂以达到2D NMK数据的快速采集. 相似文献
65.
The Fraunhofer diffraction pattern of an aperture formed between a knife edge and a smooth surface of a turned metal cylinder or half cylinder is different from the diffraction pattern of an ideal slit aperture. The diffraction pattern is simulated by adding the light reflected by the cylinder surface to the pattern formed by a slit, and is measured using a cylinder that has been partly cut away so that it can represent either a full or half cylinder. The theoretical and measured patterns agree well with each other. 相似文献
66.
Anthony D. Dutoi 《Molecular physics》2014,112(1):1-11
As experimental techniques begin to probe electronic motions in increasing detail, the need is arising for compact and informative visualisations of simulations of such processes. The inherent challenge is that a full many-electron wavefunction is a high-dimensional object, representing the complicated correlations of strongly repulsive bodies in a small molecular volume. A general procedure is needed to distill this to a smaller amount of information that does not rely on any specific level of approximation. The result should allow for easy and intuitive interpretation while drawing out nontrivial aspects of the underlying many-body dynamics, such as the complex phase information inherent of a nonstationary state. Current visualisation schemes based on physical observables or the qualitative information contained in simple wavefunctions, such as time-dependent configuration-interaction-singles (TD-CIS) and time-dependent self-consistent-field (TD-SCF), are discussed. This information is compared to an analysis based on the one-body reduced density operator (1-RDO), which is well-defined for general wavefunctions. It is seen that the distinction between two paradigms of many-body dynamics, electron transport and energy transport, is reflected in the coherences of a difference-1-RDO, or lack thereof. 相似文献
67.
Quantization of electromagnetic field in quadratic continuous nonlinear absorptive dielectrics 下载免费PDF全文
This paper reports that in the quantization of
electromagnetic field in the dielectrics, the wave equation with
regard to the Green function is analytically solved by a direct integral
method for a quadratic continuous nonlinear absorptive dielectric
medium. The quantization of the electromagnetic field in such a
nonlinear absorptive dielectric is carried out for which the
material dielectric function is assumed as a separable variable about
the frequency and the space coordinate. The vacuum field
fluctuations for different spatial continuous variations of
dielectric function are numerically calculated, which shows that the
present result is self-consistent. 相似文献
68.
XU Xue-Fen 《理论物理通讯》2008,50(10):979-982
In similar to the derivation of phase angle operator conjugate to the number operator by Arroyo Carrasco- Moya Cessay we deduce the Hermitian phase operators that are conjugate to the two-mode number-difference operator and the three-mode number combination operator. It is shown that these operators are on the same footing in the entangled state representation as the one of Turski in the coherent state representation. 相似文献
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70.
We consider the short-time heat content asymptotics for oblique boundary conditions. The first few coefficients in the asymptotic expansion are calculated. 相似文献