Yb3+:Er3+:Tm3+ co-doped borosilicate glasses are prepared.Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared,which are excited by a 978-nm laser diode,are measured,and the mechanisms of energy transfer among Yb3+,Er3+ and Tm3+ ions are discussed.The results show that there is an unexpected wavelength at 900-nm emission from Yb3+ Stark splitting levels to pump Tm3+ ions and there exists an optimum pump power.The concentration of the Tm3+ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the Yb3+:Er3+:Tm3+ co-doped borosilicate glasses. 相似文献
Near infrared (NIR) spectroscopy based on effective wavelengths (EWs) and chemometrics was proposed to discriminate the varieties of fruit vinegars including aloe, apple, lemon and peach vinegars. One hundred eighty samples (45 for each variety) were selected randomly for the calibration set, and 60 samples (15 for each variety) for the validation set, whereas 24 samples (6 for each variety) for the independent set. Partial least squares discriminant analysis (PLS-DA) and least squares-support vector machine (LS-SVM) were implemented for calibration models. Different input data matrices of LS-SVM were determined by latent variables (LVs) selected by explained variance, and EWs selected by x-loading weights, regression coefficients, modeling power and independent component analysis (ICA). Then the LS-SVM models were developed with a grid search technique and RBF kernel function. All LS-SVM models outperformed PLS-DA model, and the optimal LS-SVM model was achieved with EWs (4021, 4058, 4264, 4400, 4853, 5070 and 5273 cm−1) selected by regression coefficients. The determination coefficient (R2), RMSEP and total recognition ratio with cutoff value ±0.1 in validation set were 1.000, 0.025 and 100%, respectively. The overall results indicted that the regression coefficients was an effective way for the selection of effective wavelengths. NIR spectroscopy combined with LS-SVM models had the capability to discriminate the varieties of fruit vinegars with high accuracy. 相似文献
In this paper we study the excitation of photonic nanojets (PNJ) in 3D dielectric cuboids by surface plasmons at telecommunication wavelengths. The analysis is done using the effective refractive index approach. It is shown that the refractive index contrast between the regions with and without cuboid should be roughly less than 2 in order to generate jets at the output of the cuboid. The best performance at λ0 = 1550 nm is obtained when the height of the cuboid is 160 nm producing a jet just at the output interface with a subwavelength resolution of 0.68λ0 and a high intensity enhancement (×5) at the focus. The multi‐wavelength response is also studied demonstrating that it is possible to use the proposed structure at different wavelengths. Finally, the backscattering enhancement is numerically evaluated by inserting a metal particle within the PNJ region, demonstrating a maximum value of ~2.44 dB for a gold sphere of radius 0.1λ0.
Electric field patterns in finite two-dimensional wire photonics lattices are investigated by means of electromagnetic simulations. These studies reveal a strong analogy with the envelope wavefunction approach extensively used for semiconductor superlattices. Several propagating eigenmodes in the pass-band of the periodic structure as well as evanescent modes in the stop-bands are clearly identified. They are interpreted on the basis of the matching of the wavelength of electromagnetic field to the lattice dimensions with an envelope wavefunction resulting of a Fabry–Pérot effect in the cavity formed by the periodic structure. In terms of transmission coefficient, the calculated frequency dependence are in agreement with those measured in finite metallic rod arrays between 50 and 110 GHz. 相似文献