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41.
首次尝试将随机有限元法引入大体积混凝土结构随机温度徐变应力的计算.综合考虑各种随机因素,对于由材料物理参数随机性引起的随机温度场的影响,本文给出了相应于初应变隐式解法的随机有限元计算方法;对于周期平稳随机温度场对徐变应力场的影响,本文提出了复模量隐式解法,并首次视复频响应函数为材料参数的随机函数,给出了相应的复频响应-随机有限元列式;而对于一般非平稳绝热温升温度场的影响,本文提出了参数调幅逐段简化的方法.本文方法有效地克服了前人不能考虑材料参数随机性或需弹模不随时间变化的局限性 相似文献
42.
Greg M. Pearl M. C. Zerner Anders Broo John McKelvey 《Journal of computational chemistry》1998,19(7):781-796
A method for approximating the band shape of molecular electronic transitions based on a single geometric configuration is described. The band shape is modeled using an empirical parameter to estimate the width at half-height for each transition. In addition to generating a shape for allowed transitions, a procedure is developed for approximating the oscillator strength for the symmetry forbidden bands. The results obtained using these two approximations are then compared with experimental spectra and to the results obtained from stochastic methods for simple organic molecules, such as benzene, naphthalene, and the diazobenzenes. © 1998 John Wiley & Sons, Inc. J Comput Chem 19: 781–796, 1998 相似文献
43.
Raluca‐Ioana Stefan‐van Staden Alexandrina Moscalu‐Lungu Jacobus Frederick van Staden 《Electroanalysis》2020,32(1):178-184
Three stochastic sensors based on nanodiamond (nDP) paste modified with α, β, and γ‐cyclodextrin were designed and characterized for pattern recognition of aspartame, acesulfame K and sodium cyclamate in beverages, ketchup, and biological fluids. The linear concentration ranges obtained for acesulfame K (between 1.00×10?10 mol L?1and 1.00×10?3 mol L?1), for aspartame (between 1.00×10?12 mol L?1 and 1.00×10?3 mol L?1) and for sodium cyclamate (between 4.97×10?12 mol L?1 and 4.97×10?3 mol L?1) allow their assay in biological fluids, beverages and ketchup. The lowest limits of quantification were obtained using the stochastic sensor based on γ‐CD/nDP: for acesulfame K 1.00×10?10 mol L?1, for aspartame 1.00×10?12 mol L?1 and for sodium cyclamate 4.97×10?12 mol L?1. All three stochastic sensors revealed very high values of sensitivities. The proposed method was reliable for qualitative and quantitative assay of aspartame, acesulfame K and sodium cyclamate in beverages, ketchup, and in biological fluids such as urine. 相似文献
44.
Young Eun Jeun Joon Ho Park Joo Yeon Kim Prof. Hyun S. Ahn 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(18):4039-4043
Mixed-metal oxyhydroxides—especially those of Ni and Fe—are one of the most active classes of materials known for catalyzing the oxygen evolution reaction (OER). Here, nanoparticulate mixed metal oxyhydroxides (of Ni, Fe, and Co) were prepared on an electrode surface by electrochemical reaction of a precursor solution encapsulated in aqueous nanodroplets (AnDs), with each of the droplets containing 10 s of attoliters of fluid. Electrode reactions and synthesis can be monitored in situ by electrochemistry as single AnD stochastically lands and interacts with the working electrode. Resultant metal oxyhydroxide nanoparticles can be size and composition controlled precisely by modulating the precursor solution stored in the AnD. Nanoparticulate metal oxyhydroxides were implemented as catalysts for the OER and exhibited superior catalysis compared to their thin-film counterparts, demonstrating a hundred-thousand-fold enhancement in atom efficiency at comparable turnover rates. 相似文献
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A random vector (X1, …, Xn), with positive components, has a Liouville distribution if its joint probability density function is of the formf(x1 + … + xn)x1a1.1 … xnan.1 with theai all positive. Examples of these are the Dirichlet and inverted Dirichlet distributions. In this paper, a comprehensive treatment of the Liouville distributions is provided. The results pertain to stochastic representations, transformation properties, complete neutrality, marginal and conditional distributions, regression functions, and total positivity and reverse rule properties. Further, these topics are utilized in various characterizations of the Dirichlet and inverted Dirichlet distributions. Matrix analogs of the Liouville distributions are also treated, and many of the results obtained in the vector setting are extended appropriately. 相似文献
47.
I. Grabec 《The European Physical Journal B - Condensed Matter and Complex Systems》2001,22(1):129-135
A physical law is represented by the probability distribution of a measured variable. The probability density is described
by measured data using an estimator whose kernel is the instrument scattering function. The experimental information and data
redundancy are defined in terms of information entropy. The model cost function, comprised of data redundancy and estimation
error, is minimized by the creation-annihilation process.
Received 24 February 2000 and Received in final form 21 February 2001 相似文献
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Nakao’s stochastic integrals for continuous additive functionals of zero energy are extended from the symmetric Dirichlet forms setting to the non-symmetric Dirichlet forms setting.It? ’s formula in terms of the extended stochastic integrals is obtained. 相似文献