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81.
    
Ever since the laser's invention, there has been great interest in increasing beam output power without detriment to its coherence. Despite great advances having been obtained through the use of a diverse range of approaches, steady‐state beam powers above ten kilowatts remain a significant challenge for solid‐state lasers due to the heightened impact of detrimental nonlinear effects such as thermal lensing. Multiplexing several lasers using beam combination represents a method for surpassing the power barriers of single lasers. Here we propose and demonstrate a novel approach to beam combination and power scaling based on Raman conversion in diamond. Power from multiple non‐collinear pump beams is efficiently transferred onto a single Stokes beam in a single‐pass amplifier. Using three mutually‐independent nanosecond pulsed beams from a free‐running‐linewidth 1064 nm laser, 69% of the total peak pump power of 6.7 kW was transferred onto a TEM00 Stokes seed pulse at 1240 nm in a 9.5 mm long diamond crystal. Compared to other beam combination techniques, diamond beam combination has advantages of relaxed constraints on pump beam mutual coherence, while enabling narrowband output. Thermal considerations for extending from low duty‐cycle to continuous wave operation and higher power levels are discussed.

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82.
    
In this work, we demonstrate the combined use of a pump‐probe Raman–Raman technique and the naturally occurring process of vibration‐to‐vibration (V V ) collisional relaxation to populate and obtain high‐resolution Raman spectra of vibrationally excited states that cannot be easily accessed by other means. First, a stimulated Raman pump stage is used to promote population to a v i = 1 excited state. This is followed by a time interval whose length is chosen so that, at the working pressure, significant V V collisional energy transfer takes place and the quanta of vibrational excitation initially placed in v i = 1 naturally reach other excited states. Finally, after this delay, the probe stage is used to obtain high‐resolution Raman spectra of hot bands departing from these collisionally populated states. The technique has been demonstrated on two isotopologues of acetylene, 12C2H2 and 12C2D2, and has allowed the observation of transitions departing from the 2ν 2 ( ) and 2ν 4 + ν 5 (IΠu ) collisionally populated states. Accurate values of the spectroscopic parameters for the v 2 = 3 vibrationally excited states for both isotopologues were obtained, for the first time, from the least‐squares analysis of the assigned transitions. In addition, the observation of Q branch lines of v 2 = 1, v 4 = 2, v 5 = 1 (IΠu ) ← v 4 = 2, v 5 = 1 (IΠu ) band for 12C2H2 allowed the spectroscopic characterization of the upper state. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
83.
    
Raman microscopy, which offers chemical‐specific imaging, has important applications in geological sciences. Conventional Raman imaging, however, is challenged by long acquisition times and can be overwhelmed by sample fluorescence. Here, we present the first applications of stimulated Raman scattering (SRS) microscopy, a nonlinear optical Raman technique, to samples of mineralogical interest. Combined with second harmonic generation microscopy, SRS offers a multimodal tool for rapid imaging of mineral samples with chemical specificity, structural sensitivity, and excellent three‐dimensional resolution. Our spectral focusing implementation allows for very rapid scanning of Raman spectral lineshapes, with an adjustable spectral resolution (set here to 25 cm−1) and an overall tuning range of 400–4500 cm−1. In mineralogical applications, this wide‐tuning range offers hyperspectral imaging of both trapped organics, via the CH region (~2900 cm−1), and the lower frequency (<1000 cm−1) ‘fingerprint’ modes important for mineral identification. The simultaneously acquired second harmonic generation image reveals details of the local crystallinity of non‐centrosymmetric minerals such as quartz. As opposed to single‐spectral‐point imaging, we emphasize the importance of tuning over the Raman lineshape while imaging, to unambiguously distinguish the resonant Raman response from nonresonant background signals. Based on the range of samples studied here, we believe that multimodal SRS microscopy will become a valuable imaging tool in the earth sciences, particularly in mineralogy, petroleum, and mineral resources research. ©2017 Her Majesty the Queen in Right of Canada Journal of Raman Spectroscopy ©2017 John Wiley & Sons, Ltd.  相似文献   
84.
    
We introduce a high-sensitivity broadband stimulated Raman scattering (SRS) setup featuring wide spectral coverage (up to 500 cm−1) and high-frequency resolution (≈20 cm−1). The system combines a narrowband Stokes pulse, obtained by spectral filtering an Yb laser, with a broadband pump pulse generated by a home-built optical parametric oscillator. A single-channel lock-in amplifier connected to a single-pixel photodiode measures the stimulated Raman loss signal, whose spectrum is scanned rapidly using a galvanometric mirror after the sample. We use the in-line balanced detection approach to suppress laser fluctuations and achieve close to shot-noise-limited sensitivity. The setup is capable of measuring accurately the SRS spectra of several solvents and of obtaining hyperspectral data cubes consisting in the broadband SRS microscopy images of polymer beads test samples as well as of the distribution of different biological substances within plant cell walls.  相似文献   
85.
86.
    
Spontaneous Raman (SR) microscopy allows label‐free chemically specific imaging based on the vibrational response of molecules; however, due to the low Raman scattering cross section, it is intrinsically slow. Coherent Raman scattering (CRS) techniques, by coherently exciting vibrational oscillators in the focal volume, increase signal levels by several orders of magnitude under appropriate conditions. In its single‐frequency version, CRS microscopy has reached very high imaging speeds, up to the video rate; however, it provides information which is not sufficient to distinguish spectrally overlapped chemical species within complex heterogeneous systems, such as cells and tissues. Broadband CRS combines the acquisition speed of CRS with the information content of SR, but it is technically very demanding. In this Review, the current state of the art in broadband CRS microscopy, both in the coherent anti‐Stokes Raman scattering (CARS) and the stimulated Raman scattering (SRS) versions are reviewed. Different technical solutions for broadband CARS and SRS, working both in the frequency and in the time domains, are compared and their merits and drawbacks assessed.  相似文献   
87.
A novel and simple two-frequency Brillouin fiber laser is presented. It is based on a fiber Fabry-Perot cavity with fiber Bragg gratings as reflectors. The model of stimulated Brillouin scattering in fiber grating-based Fabry-Perot resonator is investigated. The laser allows conversion efficiency of close to 100% and suppresses the higher-order Stokes waves. The theoretical prediction is presented and the experimental demonstration is realized.  相似文献   
88.
用单纵模Nd∶YAG二倍频激光[波长532 nm,线宽Δνp<100 MHz,脉宽(半峰全宽)6.5 ns]抽运CH4气体,观察到很强的后向一级斯托克斯(BS1)受激拉曼散射,这与前人采用脉宽30 ns的单纵模抽运激光得到的绝大部分为后向受激布里渊散射(SBS)完全不同,其原因是脉宽6.5 ns与本实验条件下CH4的受激布里渊散射声子寿命接近,受激布里渊散射处于瞬态。理论计算表明,这时的受激布里渊散射瞬态增益系数已略小于后向一级斯托克斯的增益系数,而被其竞争抑制。当脉冲重复频率为2 Hz,抽运能量为95 mJ时,在1.1 MPa CH4中,后向一级斯托克斯的量子转换效率高达73%,其时间波形出现张弛振荡,脉宽被压窄到1.2 ns,从而使后向一级斯托克斯峰值功率达到了抽运激光功率的2.7倍,而且其光束质量要大大优于抽运激光的光束质量。用编制的准二维计算机模型程序相当好地再现了实验中后向一级斯托克斯的时间波形张弛振荡。  相似文献   
89.
对脉冲Nd∶YAG激光(355 nm)在H2和H2∶He-Ar混合气体中的受激拉曼散射(SRS)进行了研究。在0.5 MPa的氢气中,同时测量到从二级反斯托克斯到三级斯托克斯的多波长输出,其总转化效率达88%;而高压下只剩下一级和二级斯托克斯输出,其中二级斯托克斯最大能量转化效率达44%(对应量子效率为63%)。由于高级斯托克斯的竞争,纯氢气中一级斯托克斯的最大能量转换效率不超过43%。通过向3 MPa氢气中掺入2 MPaAr气后,很好地抑制了二级斯托克斯的产生,从而获得了能量转换效率高达71%(对应量子效率为83%)的一级斯托克斯输出。对四波混频和级联受激拉曼散射在氢气多级斯托克斯产生中的作用以及惰性气体对它们的影响进行了讨论。  相似文献   
90.
After the laser was invented in 1960, a phase conjugation mirror has been respected to be the most fantastic one for the laser resonator composition because it can compensate any distortions of the laser beams occurred by the many inhomogenuities of the laser media and optical components. Among the many phase conjugation configurations, the stimulated Brillouin scattering phase conjugation mirror is the most simple one and many researchers have tried to utilize it to develop high power/energy laser systems. For realizing a high energy/power laser system the thermal problem is the most difficult to solve, and some researchers suggested a beam combination technique to reduce the thermal load of the big laser media to many small sized ones. To accomplish the beam combination using stimulated Brillouin scattering phase conjugation mirrors (SBS-PCMs), it is necessary to lock/control the phases of the SBS-PCMs. And some researchers have developed several ways for it, but they can lock the phases of a limited number of beams overlapped at the foci less than 5, or lock the phases by back-seeding technique but it loses the phase conjugation characteristics. For realization of the laser fusion driver, it is necessary to combine more than 10 or 100 beams. And the authors have developed recently a new phase controlling/locking technique which is isolated and independent totally from other beams and it can be applied to an unlimited number of beams in principle.  相似文献   
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