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排序方式: 共有576条查询结果,搜索用时 31 毫秒
121.
122.
ChundeNiu DaowenChong YuchunCheng ShurenHao 《天然气化学杂志》2003,12(2):135-138
The DS-1 catalyst for energy-saving natural gas steam reforming was prepared by using potash as a carbon-resistant additive and adding rare earth oxide. The catalyst demonstrated good reducibility,carbon resistance, activity and stability in aging tests and 500 h stability tests at low water/carbon ratios. 相似文献
123.
124.
The performance test of a shell-and-plate type evaporator (total surface area 21.95 m2, length 1450 mm, width 235 mm, 100 plates) for ocean thermal energy conversion (OTEC) plants is reported. Freon 22 (R22) and ammonia (NH3) were used as the working fluid. Empirical correlations are proposed for predicting the boiling heat transfer and the heat transfer coefficients on the water side. The water-side pressure drop is about 2.9 × 104 N/m2 when the warm water velocity is 0.7 m/s. The water-side friction factor is obtained. 相似文献
125.
The structure and catalytic properties of SrTi1-xMgxO3-δ perovskite-type catalysts for oxidative coupling of methane (OCM) have been studied by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Temperature-programmed desorption (O2-TPD) methods. It has been shown that doping Mg2+ cations to the B site of SrTi1-xMgxO3-δ perovskite-type catalysts results in the formation of oxygen vacancies in the lattices of oxide cata-lysts. With increasing the amount of Mg2+ doped in the B site of SrTi1-xMgxO3-δ, methane conversion and C2 selectivity first increase and then decrease remarkably. The SrTi1-xMgxO3-δ catalyst with x=0.1 has the highest methane conversion and C2 yield. It is suggested that the oxygen vacancies produced by Mg2+ cations doping are the sites responsible for oxygen activation, and the adsorbed oxygen species on the surface of SrTi1-xMgxO3-δ catalysts are the main active species for OCM reaction. However, the over high content of the adsorbed oxygen species on the surface results in the complete oxidation of methane. Introducing water steam into feedstock can improve the catalytic properties of SrTi1-xMgxO3-δ perovskite-type catalysts for OCM reaction at lower temperature. The SrTi0.9Mg0.1O3-δ catalyst has the methane conversion of 28.0 % with C2 hydrocarbons selectivity of 36.8 % under reaction temperature of 550 ℃. 相似文献
126.
Dual‐Function Cobalt–Nickel Nanoparticles Tailored for High‐Temperature Induction‐Heated Steam Methane Reforming
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Morten G. Vinum Mads R. Almind Dr. Jakob S. Engbæk Dr. Søren B. Vendelbo Dr. Mikkel F. Hansen Prof. Dr. Cathrine Frandsen Prof. Dr. Jesper Bendix Dr. Peter M. Mortensen 《Angewandte Chemie (International ed. in English)》2018,57(33):10569-10573
The tailored chemical synthesis of binary and ternary alloy nanoparticles with a uniform elemental composition is presented. Their dual use as magnetic susceptors for induction heating and catalytic agent for steam reforming of methane to produce hydrogen at temperatures near and above 800 °C is demonstrated. The heating and catalytic performance of two chemically synthesized samples of CoNi and Cu ? CoNi are compared and held against a traditional Ni‐based reforming catalyst. The structural, magnetic, and catalytic properties of the samples were characterized by X‐ray diffraction, elemental analysis, magnetometry, and reactivity measurements. For induction‐heated catalysts, the conversion rate of methane is limited by chemical reactivity, as opposed to the case of traditional externally heated reformers where heat transport limitations are the limiting factor. Catalyst production by the synthetic route allows controlled doping with miniscule concentrations of auxiliary metals. 相似文献
127.
Ali Nakhaei Pour Yahya Zamani Kheirolah Jafari Jozani Jafar Yeganeh Mehr 《Reaction Kinetics and Catalysis Letters》2005,86(1):157-162
Summary The effect of La2O3 and TiO2 on product selectivity, methane conversion and coke formation over NiO/MgO/ α -Al2O3 catalyst were studied in a simultaneous steam and CO2 reforming of methane to syngas. La2O3 and TiO2 were added to the catalyst via incipient wetness impregnation and bulk precipitation techniques and catalyst activity was tested in a fixed bed quartz reactor. Results reveal that although the addition of these oxides has no effect on the product selectivity and methane conversion, but can reduce coke formation on the surface of the catalysts as it can enhance the mobility of lattice oxygen anions. The results further show that the catalysts prepared by bulk precipitation technique decrease the coke formation more effectively. 相似文献
128.
Fumihisa Kobayashi Tatsuro Sawada Yoshitoshi Nakamura Makoto Ohnaga Mutui Godliving Tomoo Ushiyama 《Applied biochemistry and biotechnology》1998,69(3):177-189
Steam explosion pretreatment of potato for the efficient production of alcohol was experimentally studied. The amount of water-soluble
starch increased with the increase of steam pressure, but the amounts of methanol-soluble material and Klason lignin remained
insignificant, regardless of steam pressure. The potatoes exploded at high pressure were hydrolyzed into a low molecular liquid
starch, and then easily converted into ethanol by simultaneous saccharification and fermentation using mixed microorganisms:
an amylolytic microorganism,Aspergillus awamori, and a fermentation microorganism,Saccharomyces cerevisiae. The maximal ethanol concentration was 4.2 g/L in a batch culture at 15 g/L starch concentration, and 3.6 g/L in a continuous
culture fed the same starch concentration. In the fed-batch culture, the maximal ethanol concentration increased more than
twofold, compared to the batch culture. 相似文献
129.
Ethanol reforming processes over ZnO-supported palladium catalysts: Effect of alloy formation 总被引:2,自引:0,他引:2
Albert Casanovas Jordi Llorca Narcís Homs Jos Luis G. Fierro Pilar Ramírez de la Piscina 《Journal of molecular catalysis. A, Chemical》2006,250(1-2):44-49
ZnO- and SiO2-supported palladium catalysts were evaluated in the ethanol steam-reforming and oxidative ethanol steam-reforming reactions in the temperature range 548–723 K. The catalysts were characterized before and after reaction by X-ray diffraction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy and infrared spectroscopy using CO as a probe molecule. On silica-supported Pd catalyst, ethanol decomposes into H2, CO and CH4 in both steam-reforming and oxidative steam-reforming reactions. In contrast, ZnO-supported catalysts containing the PdZn phase exhibit a better catalytic performance for hydrogen production through dehydrogenation of ethanol into acetaldehyde and ulterior reforming. 相似文献
130.
甲醇水蒸气重整制氢CuO/CeO-ZrO/SiC整体催化剂的研究 《燃料化学学报》2003,48(9):1122-1130
采用浸渍法和溶胶凝胶法制备了CuO/CeO2-ZrO2/SiC整体催化剂,并将其用于甲醇水蒸气重整制氢反应中。结果表明,与CuO/CeO2-ZrO2颗粒催化剂相比,CuO/CeO2-ZrO2/SiC整体催化剂催化活性较好,产氢速率较快且重整气中CO体积分数较低。进一步探究了涂层涂覆量和CuO负载量对催化性能的影响,结果表明,当CeO2-ZrO2复合氧化物涂层涂覆量在15%±1%,CuO负载量为5%±1%时,催化性能较好;当反应温度为340℃,水醇物质的量比为1.2,甲醇水蒸气气体空速为4840 h-1时,甲醇转化率为86.0%,产氢速率为1490.0 L/(m3·s),重整气中CO体积分数为1.55%。最后通过单因素实验法探究了甲醇水蒸气气体空速、水醇物质的量比和反应温度对反应的影响。结果表明,随着气体空速变大,甲醇转化率下降,产氢速率上升,重整气中CO体积分数下降。随着水醇物质的量比增加,甲醇转化率先上升后下降,产氢速率先上升后下降,重整气中CO体积分数下降。随着反应温度的升高,甲醇转化率、产氢速率和重整气中CO体积分数均上升。 相似文献