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991.
本文考察了以微波等离子体炬(MPT)为光源,电热钽丝环进样时,溶液中共存元素对发射信号的影响。 相似文献
992.
We construct a series of pairs of domains in the plane and pairs of surfaces with boundary that are isospectral but not isometric.
The construction is based on the existence of finite transformation groups that are spectrally equivalent but not isomorphic.
Translated fromMatematicheskie Zametki, Vol. 63, No. 5, pp. 660–664, May, 1998.
This research was partially supported by the Russian Foundation for Basic Research and by INTAS under joint grant No. 96-01-00043. 相似文献
993.
S.F. Lienin R. Brüschweiler R.R. Ernst 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,131(2):184-190
The viscosity-dependent retarding effect of a polymeric solvent on the rotation of small solute molecules is investigated by13C NMR relaxation measurements. It is found that the relaxation data of 1,3-dibromoadamantane in highly viscous polymeric chlorotrifluoroethene can be explained neither by isotropic nor by realistic anisotropic tumbling in a single environment. The experimental data are rationalized in terms of fast exchange between at least two environments with correlation times differing by up to two orders of magnitude. The study shows that a uniform retardation of molecular tumbling by a polymeric solvent, desirable for shifting the NMR observation window in studies of intramolecular mobility, is not always feasible. 相似文献
994.
D. Sornette 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,3(1):125-137
We propose a formulation of the term structure of interest rates in which the forward curve is seen as the deformation of
a string. We derive the general condition that the partial differential equations governing the motion of such string must
obey in order to account for the condition of absence of arbitrage opportunities. This condition takes a form similar to a
fluctuation-dissipation theorem, albeit on the same quantity (the forward rate), linking the bias to the covariance of variation
fluctuations. We provide the general structure of the models that obey this constraint in the framework of stochastic partial
(possibly non-linear) differential equations. We derive the general solution for the pricing and hedging of interest rate
derivatives within this framework, albeit for the linear case (we also provide in the appendix a simple and intuitive derivation
of the standard European option problem). We also show how the “string” formulation simplifies into a standard N-factor model under a Galerkin approximation.
Received: 30 January 1998 / Revised: 12 February 1998 / Accepted: 16 February 1998 相似文献
995.
The solvent extraction of cobalt(II), nickel(II) and copper(II) using 2,4-pent-dione (Hacac) and 4-phenyl-2, 4-but-dione (Hbzac)
is carried out by varying the reagent concentration and pH of the aqueous phase. Each of these metals is quantitatively separated
(≈ 98%) from their binary mixtures with monovalent (Ag), divalent (Mn, Zn, Cd, Hg, Mg, Sn, Pb) and trivalent (Cr, Fe) metals.
The extraction constants are calculated from the metal distribution data using linear regression analysis. The extracted species
is MA2 in each case. A most significant result is separation of copper(II) from iron(III) which otherwise interferes when extracted
from the acidic medium. 相似文献
996.
本文在Menser概率赋范空间中引入了(Φ,Δ)型概率收缩的概念,研究了Menger概率赋范空间中具有这类概率收缩的非线性算子方程的解的存在性与唯一性.发展和改进了引文[1]、[4~8]的相应结果. 相似文献
997.
Cyclic and acyclic β-bromovinyl aldehydes are cyclized with an array of arylhydrazines in toluene at 125 °C in the presence of a palladium catalyst and a phosphorus chelating ligand together with NaOtBu to give 1-aryl-1H-pyrazoles in moderate to good yields. 相似文献
998.
We have used electronic spectroscopy in the 160–1100 nm range to study the polyvinyl alcohol-nickel(II) chloride system. Based
on the results obtained, we hypothesize formation of mixed-ligand complexes of the type [Ni(H2O)6-nCln]2-n (n = 0, 1,..., 5) in the polyvinyl alcohol matrix. Transformation of the coordination sphere as the NiCl2 concentration changes is apparent both in the region of the d-d transition bands (350–1100 nm) and in the region of the charge
transfer bands (160–250 nm). We propose assigning the absorption bands separated by mathematical treatment to complexes of
specific compositions.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 1, pp. 136–138, January–February, 2006. 相似文献
999.
对于高温高压下氩等离子体的电离度和物态方程,本文给出了一种基于Thomas-Feimi(TF)统计模型的简化计算新方法:首先将TF模型电离势的数值结果进行函数逼近,给出一个便于数值求解的计算电离度的近似计算方法,并由此计算了局部热动平衡下的氩等离子体在10~1000 eV高温范围内的物态方程.计算结果与国外报道的其他几种理论模型的计算结果均符合很好,与实验值也吻合较好.本文所提出的简单模型也适用于计算混合物物态方程,可以在电磁发射技术领域中的强电离等离子体中有更为广阔的应用前景. 相似文献
1000.
O. A. Brezhneva Yu. G. Evtushenko A. A. Tret’yakov 《Computational Mathematics and Mathematical Physics》2006,46(11):1896-1909
The theory of p-regularity is applied to optimization problems and to singular ordinary differential equations (ODE). The special variant of the method of the modified Lagrangian function proposed by Yu.G. Evtushenko for constrained optimization problems with inequality constraints is justified on the basis of the 2-factor transformation. An implicit function theorem is given for the singular case. This theorem is used to show the existence of solutions to a boundary value problem for a nonlinear differential equation in the resonance case. New numerical methods are proposed including the p-factor method for solving ODEs with a small parameter. 相似文献