全文获取类型
收费全文 | 2889篇 |
免费 | 418篇 |
国内免费 | 228篇 |
专业分类
化学 | 848篇 |
晶体学 | 37篇 |
力学 | 256篇 |
综合类 | 32篇 |
数学 | 1323篇 |
物理学 | 1039篇 |
出版年
2024年 | 2篇 |
2023年 | 26篇 |
2022年 | 84篇 |
2021年 | 65篇 |
2020年 | 94篇 |
2019年 | 70篇 |
2018年 | 90篇 |
2017年 | 102篇 |
2016年 | 92篇 |
2015年 | 73篇 |
2014年 | 112篇 |
2013年 | 353篇 |
2012年 | 121篇 |
2011年 | 163篇 |
2010年 | 122篇 |
2009年 | 166篇 |
2008年 | 174篇 |
2007年 | 190篇 |
2006年 | 167篇 |
2005年 | 163篇 |
2004年 | 135篇 |
2003年 | 109篇 |
2002年 | 102篇 |
2001年 | 81篇 |
2000年 | 97篇 |
1999年 | 75篇 |
1998年 | 68篇 |
1997年 | 57篇 |
1996年 | 51篇 |
1995年 | 44篇 |
1994年 | 46篇 |
1993年 | 29篇 |
1992年 | 34篇 |
1991年 | 26篇 |
1990年 | 18篇 |
1989年 | 12篇 |
1988年 | 10篇 |
1987年 | 10篇 |
1986年 | 11篇 |
1985年 | 15篇 |
1984年 | 16篇 |
1983年 | 5篇 |
1982年 | 10篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 10篇 |
1978年 | 7篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1974年 | 5篇 |
排序方式: 共有3535条查询结果,搜索用时 62 毫秒
101.
Jing Luo Sisi Jiang Yong Wu Meiling Chen Xiaoya Liu 《Journal of polymer science. Part A, Polymer chemistry》2012,50(23):4888-4894
A facile method of producing stable aqueous dispersion of graphene/polyaniline (PANI) composite is described, which involves the in situ polymerization of aniline on the surface of graphene with the aid of polystyrene sulfonic acid (PSS). The prepared aqueous graphene/PANI composite dispersion was very stable and no aggregation or precipitation was observed for several weeks. The excellent aqueous dispersibility and stability of the graphene/PANI composite is attributed to the cooperative interactions of π stacking interaction between PSS, PANI, and the graphene basal planes, and the electrostatic repulsions between negatively charged PSS bound on graphene/PANI composite. Fourier transform‐infrared spectrometry (FTIR), ultraviolet‐visible spectra (UV–vis), and Raman spectra confirmed the interaction of PANI and graphene in the composite, which effectively delocalize the electrons. In addition, the composite showed three orders of magnitude of conductivity increase compared with pure PANI. This new approach is simple, fast, and straightforward, representing a significant improvement in the processing of graphene/PANI composites. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
102.
H. Herzmann 《Isotopes in environmental and health studies》2013,49(2):45-52
Radioaktiv markierte Präparate haben in denletzten Jahren in schnell zunehmendem Maße Eingang in die klinische Medizin gefunden. Sie sind beieiner Reihe von Indikationen schon jetzt außerordentlich wertvolle Hilfsmittel bei der Diagnose, besonders bei der Prüfung von Organfunktionen. 相似文献
103.
Yuan Lou 《Journal of Nonlinear Modeling and Analysis》2019,1(2):151-166
In this paper, the formats of Julia sets for a class of nonlinear complex dynamic systems with variable coefficients were studied under certain conditions. For the complex dynamic systems in piecewise cases, we proposed some methods to control the forms of their Julia sets and stable domains analytically. What’s more, we illustrated that our methods worked well by computational simulations. Our work provides a better understanding about how to control the Julia sets of certain complex dynamic systems. 相似文献
104.
Malek Taher Maghsoodlou Sayyed Mostafa Habibi Khorasani Nourollah Hazeri Mahmoud Nassiri Reza KaKaei Ghasem Marandi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):553-560
Stable crystalline phosphorus ylides were obtained in excellent yields from the 1:1:1 addition reaction between triphenylphosphine and dialkyl acetylenedicarboxylates, in the presence of strong NH-acids, such as imidazole, 2-methylimidazole, 4-methylimidazole, 2-ethylimidazole, benzimidazole, and 5,6-dimethylbezimidazole. These stable ylides exist in solution as a mixture of two geometrical isomers as a result of restricted rotation around the carbon–carbon partial double bond resulting from the conjugation of the ylide moiety with the adjacent carbonyl group. 相似文献
105.
Malek Taher Maghsoodlou Nourollah Hazeri Sayyed Mostafa Habibi Khorasani Aqil Ghulame Shahzadeh Mahmoud Nassiri 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):913-919
Stable crystalline phosphorus ylides were obtained in excellent yields from the 1:1:1 addition reaction between triphenylphosphine and dialkyl acetylenedicarboxylates in the presence of strong NH acids, such as indole and 2-methyl indole, 3-methyl indole, and 5-boromo indole. These stable ylides exist in a solution as a mixture of two geometrical isomers as a result of the restricted rotation around the carbon–carbon partial double bond resulting from the conjugation of the ylide moiety with the adjacent carbonyl group. 相似文献
106.
107.
Truemper configurations (thetas, pyramids, prisms, and wheels) have played an important role in the study of complex hereditary graph classes (eg, the class of perfect graphs and the class of even-hole-free graphs), appearing both as excluded configurations, and as configurations around which graphs can be decomposed. In this paper, we study the structure of graphs that contain (as induced subgraphs) no Truemper configurations other than (possibly) universal wheels and twin wheels. We also study several subclasses of this class. We use our structural results to analyze the complexity of the recognition, maximum weight clique, maximum weight stable set, and optimal vertex coloring problems for these classes. Furthermore, we obtain polynomial -bounding functions for these classes. 相似文献
108.
In order to synthesize new polyamide(PA) 5 and copolyamides(Co PA) 7a-7d, a new-type of dicarboxylic acid containing triazine ring was successfully synthesized from 2,4-dichloro-6-methoxy-s-triazine 1 and 4-aminobenzoic acid. New polyamide 5 containing triazine moiety was prepared from 4,4'-(6-methoxy-1,3,5-triazine-2,4-diyl)bis(azanediyl)dibenzoic acid 3 and 4,4′-diaminodiphenylether by direct polycondensation reaction. Then new series thermally stable copolyamides 7a-7d with high solubility in common organic solvents were synthesized from the direct polycondensation reaction of diacid 3 as a first monomer, aliphatic-aromatic diacids 6a-6d as second diacids and 4,4′-diaminodiphenylether. All of the above polymers were fully characterized by 1H-NMR and FTIR spectroscopy, elemental analysis(CHN), inherent viscosity, solubility tests, gel permeation chromatography(GPC), differential scanning calorimetry(DSC) and thermogravimetric analysis(TGA). The resulted Co PAs 7a-7d have shown good inherent viscosities, solubility and thermal properties. 相似文献
109.
The effect of the dynamic pressure (non-equilibrium pressure) on stationary heat conduction in a rarefied polyatomic gas at rest is elucidated by the theory of extended thermodynamics. It is shown that this effect is observable in a non-polytropic gas. Numerical studies are presented for a para-hydrogen gas as a typical example. 相似文献
110.
Theoretical study on the improvement of the doping efficiency of Al in 4H-SiC by co-doping group-IVB elements
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Yuanchao Huang 《中国物理 B》2022,31(4):46104-046104
The p-type doping efficiency of 4H silicon carbide (4H-SiC) is rather low due to the large ionization energies of p-type dopants. Such an issue impedes the exploration of the full advantage of 4H-SiC for semiconductor devices. In this study, we show that co-doping group-IVB elements effectively decreases the ionization energy of the most widely used p-type dopant, i.e., aluminum (Al), through the defect-level repulsion between the energy levels of group-IVB elements and that of Al in 4H-SiC. Among group-IVB elements Ti has the most prominent effectiveness. Ti decreases the ionization energy of Al by nearly 50%, leading to a value as low as ~0.13 eV. As a result, the ionization rate of Al with Ti co-doping is up to ~5 times larger than that without co-doping at room temperature when the doping concentration is up to 1018 cm-3. This work may encourage the experimental co-doping of group-IVB elements such as Ti and Al to significantly improve the p-type doping efficiency of 4H-SiC. 相似文献