不同时间尺度下锂电池SoC估算研究

针对当前电池荷电状态(SoC)估算算法在处理器运算过程中计算量大,耗费处理器资源多的问题,提出在SoC估算中同时增大辨识时间尺度和估算时间尺度。采用带遗忘因子递推最小二乘算法辨识电池模型参数,并探究不同大小的时间尺度对SoC估算精度的影响。仿真结果表明,随着辨识时间尺度和估算时间尺度增大,SoC估算精度下降且计算量快速下降,计算消耗时间呈指数减少;当时间尺度过大时,SoC估算精度难以保证,计算消耗时间减少不明显,收敛时间长;在综合考虑估算精度和计算耗费时间情况下,可以找到一个最优的时间尺度用于保证SoC估算精度同时大大降低计算量。该方法为后续实现电动汽车SoC在线估算提供理论依据。     

Electrochemical modification of a carbon paste electrode with poly (1,5-diaminonaphthalene) and copper-cobalt nanostructures for the determination of thioctic acid in real samples

This study used square-wave voltammetry and cyclic voltammetry to investigate the electrochemical oxidation of Thioctic Acid (TA) on a Carbon Paste Electrode (CPE) modified with copper-cobalt nanostructures and poly (1,5-Diaminonaphthalene). The voltammetric sensor was sensitive to the oxidation of TA. In addition, we optimized the effects of multiple cycles of deposition of Cu-Co nanostructures, and electro-polymerization of monomer 1,5-DAN, scan rate, and pH. The sensor showed good identification capabilities for TA. The linear responses obtained ranged from 0.6 μM to 150 μM with a detection limit of 0.48 μM for the modified CPE. The adsorption process controlled the oxidation of TA. We used the proposed sensor and method to determine TA in real samples.     

Frame self-orthogonal Mendelsohn triple systems of type

A Mendelsohn triple system (MTS) corresponds to an idempotent semisymmetric Latin square (quasigroup) of the same order. A holey MTS is called frame self-orthogonal, briefly FSOMTS, if its associated holey semisymmetric Latin square is frame self-orthogonal. In this paper, we use FSOMTS(hⁿ) to denote an FSOMTS with n spanning holes of size h. The existence of FSOMTS(hⁿ) for h3 has been known with a few exceptions. We extend the existing results and determine the necessary and sufficient conditions for the existence of FSOMTS(hⁿ) for any h and n with some possible exceptions.     

一个包含平方补数的方程

对任意正整数n,我们定义a(n)为n的平方补数,即a(n)表示能够使na(n)为完全平方数的最小正整数.本文的主要目的是利用初等方法研究方程a(n1)+a(n2)+…+a(nk)=m·a(n1+n2+…+nk)的可解性,并证明对某些特殊的正整数m及任意正整数k>1,该方程有无穷多组正整数解(n1,n2,…,nk).     

Adsorptive stripping square wave voltammetry (Ad-SSWV) accomplished with second-order multivariate calibration determination of fenitrothion and its metabolites in river water samples

A method, using stripping square wave voltammetry (Ad-SSWV), for the simultaneous determination of fenitrothion (FEN) and its metabolites: fenitrooxon (OXON) and 3-methyl-4-nitrophenol (3-MET) in environmental samples is reported. All three compounds produce, at mercury electrode (HMDE), an electrochemical signal due to an adsorptive-reductive process. The electrochemical approach shows a very high overlap degree for FEN and OXON voltammograms, however the adsorption kinetic profile could be used as an additional differential variable between both analytes. Second-order multivariate calibration has been tested to solve the mixture of the three compounds. The second-order assayed methods were parallel factor analysis (PARAFAC), unfolded partial least squares (U-PLS), multidimensional partial least squares (N-PLS) and the latest ones were used in combination with the residual bilinearization procedure RBL. U-PLS/RBL model was stated as the best second-order algorithm for the simultaneous determination of these three compounds up to 50 ng mL⁻¹ for each analyte. The detection limits and recovery values were 1.6 ng mL⁻¹ and 92 ± 7% for FEN; 3.7 ng mL⁻¹ and 101 ± 9% for OXON and 0.6 ng mL⁻¹ and 97 ± 8% for 3-MET.     

Comparative chemometric analyses of geographic origins and compositions of lavandin var. Grosso essential oils by mid infrared spectroscopy and gas chromatography

Lavandin, a sterile hybrid of Lavandula angustifolia P. Mill. × Lavandula latifolia (L.f.) Medikus (Lamiaceae) is a plant widely cultivated for essential oil production in the South of France. Chemometric treatment by mid-infrared (MID-IR) spectroscopy data was assessed for the differentiation of Grosso Lavandin Essential Oils of Controlled Area (GLEOCA) and results were compared to those obtained by gas chromatography for MID-IR short time technique validation. The quantification of the main 13 hydrocarbons and oxygenated compounds generally controlled by industrial perfumers in GLEOCA samples (n = 83) of three geographic origins: “Simiane”, “Puimoisson” (with two producers) and “Richerenches” and their classification were successfully obtained by partial least square discriminant analysis (PLS-DA) by comparison with gas chromatography. The best prediction results were obtained using first derivate spectral data in the 1800-700 cm⁻¹ range. The spectroscopic interpretation of regression vectors showed that each geographic origin was correlated to components of GLEOCA. Chemometric MID-IR spectra treatments allowed us to obtain similar results than those obtained by time consuming analytical techniques such as GC and therefore constitute a robust and help fast method for authentication of GLEOCA and should be extended to other essential oils for authentication of geographic origin.     

Osteryoung square wave voltammetric determination of lactose in food samples by a derivative procedure

A method for determination of lactose in food samples by Osteryoung square wave voltammetry （OSWV） was developed. It was based on the nucleophilic addition reaction between lactose and aqua ammonia. The carbonyl group of lactose can be changed into imido group, and this increases the electrochemical activity in reduction and the sensitivity. The optimal condition for the nucleophilic addition reaction was investigated and it was found that in NH4C1-NH3 buffer of pH 10.1, the linear range between the peak current and the concentration of lactose was 0.6-8.4 mg L-l, and the detection limits was 0.44 mg L- 1. The proposed method was applied to the ＇determination of lactose in food samples and satisfactory results were obtained.     

自适应灰色欧拉模型的优化及其应用

灰色预测模型已经在很多领域获得成功的应用,但是该方法的模型性能还可以进一步提高.为此,提出了一种新的灰色欧拉模型GEM(1,1)和OSGEM(1,1),给出了参数的最小二乘法计算公式,并以微分方程为推理过程,得到了GEM(1,1)模型和OSGEM(1,1)模型的时间响应序列.利用2002-2015年的数据建立预测模型,...     

Even points on an algebraic curve

We show that the points of a global function field, whose classes are 2-divisible in the Picard group, form a connected regular infinite graph, with the incidence relation generalizing the well known quadratic reciprocity law. We prove that for every global function field the diameter of this graph is precisely 2. In addition we develop an analog of global square theorem that concerns points 2-divisible in the Picard group.