方形自聚焦透镜5×5阵列的成像特性

采用离子交换工艺和精密加工技术制作了方形自聚焦透镜5×5阵列,并对其成像特性进行研究。结果表明：方形自聚焦透镜阵列相对于圆形孔径阵列而言,能有效增大填充系数,提高受光面积,其多重像和综合像的像质均匀,成像质量好。分析了导致多重像偏离和综合像变形的原因,并给出解决这一问题的关键技术。     

最小二乘法直线拟合基本假定的几点讨论

本文讨论物理实验中因不满足基本假定不宜用最小二乘法进行直线拟合的几种情况。     

方波伏安法间接测定饲料中的高含量磷

在pH=5．5的六次甲基四胺-盐酸缓冲溶液中,硝酸铅与磷酸根和氯离子反应,生成磷酸氯化铅复盐沉淀,用方波伏安法测定过量的铅离子,从而间接测定无机磷。在最佳测定条件下,当0．04mol／L硝酸铅标准溶液的用量为1．0mL时,峰电流ip与磷的质量浓度c在0．2～20μg／mL内呈良好线性关系,线性回归方程为ip=-2．39c 54．82,相关系数为0．9876,检出限为0．085μg／mL。用于饲料中磷含量的测定,测定结果的相对标准偏差为1．24％～2．44％,加标回收率为95％～99％。     

基于化学模式识别技术的枳实HPLC定量指纹图谱研究

建立了枳实的高效液相色谱(HPLC)指纹图谱分析方法.色谱柱为Tnature-ACCHROM C18色谱柱(4.6 mmx250 mm,5 μm);以乙腈-0.5％甲酸水溶液为流动相进行梯度洗脱,结合液相色谱-四极杆飞行时间质谱(HPLC-QTOF-MS)联用技术对枳实指纹图谱中的共有峰进行鉴定;采用相似度评价、聚类分...     

Hydrothermal Synthesis and Crystal Structure of a Square Grid Coordination Copper(II) Polymer from 1,4-Bis(imidazole-1-ylmethyl)benzene

1INTRODUCTION The employment of transition metal ions and ap-propriate bridging ligands has become a dominant theme in the construction of some interesting ar-rays[1,2],especially for the large square grid net-works.Recently,considerable research effort has been focused on the studies of polymeric frame-works with the ligands based on imidazole.These polymers are of great interest not only due to their intriguing topologies but also the potential applications in ion exchange,magnetic and e…     

Coolant Wetting Simulation on Simplified Stator Coil Model by the Phase-Field Lattice Boltzmann Method

Stator coils of automobiles in operation generate heat and are cooled by coolant poured from above. The flow characteristic of the coolant depends on the coil structure, flow condition, solid–fluid interaction, and fluid property, which has not been clarified due to its complexities. Since straight coils are aligned and layered with an angle at the coolant-touchdown region, the coil structure is simplified to a horizontal square rod array referring to an actual coil size. To obtain the flow and wetting characteristics, two-phase fluid flow simulations are conducted by using the phase-field lattice Boltzmann method. First, the flow onto the single-layered rod array is discussed. The wetting area is affected both by the rod gap and the wettability, which is normalized by the gap and the averaged boundary layer thickness. Then, the flow onto the multi-layered rod arrays is investigated with different rod gaps. The top layer wetting becomes longitudinal due to the reduction of the flow advection by the second layer. The wetting area jumps up at the second layer and increases proportionally to the below layers. These become remarkable at the narrow rod gap case, and finally, the dimensionless wetting area is discussed at each layer.     

短波近红外光谱法对蛇床子SFE萃取产物的定量分析

利用中药蛇床子CO2超临界萃取(SFE)的萃取物的短波近红外漫反射光谱(800～1100 nm),以HPLC分析值作参比值,采用化学计量学中的偏最小二乘法(PLS)建立短波近红外漫反射光谱与蛇床子SFE萃取物中主要成分蛇床子素和欧前胡素间定量分析数学模型.实现了快速、无损的测定双组分中药的有效成分.讨论了光谱的预处理方法和主成分数对PLS定量预测蛇床子萃取物中蛇床子素和欧前胡素含量能力的影响,并对预测集样品进行预测.     

用最小二乘法验证转动惯量的平行轴定理

提出用最小二乘法验证转动惯量平行轴定理的新方法,并通过实验证明了该方法的可行性。     

形状渐变的颗粒与沉降液的相互作用

工业过程中存在大量的含非球形颗粒的多相流动,研究这类颗粒与流体的相互作用有重要的应用价值。本文选择底面为方形、形状随边长和高度规律变化的长方体颗粒,采用单颗粒沉降法测量了曳力系数,研究了形状变化、材料密度和沉降液黏度的影响。发现曳力系数在整个颗粒Re_p数范围(0.05～6300)内均高于球形颗粒,特别是采用阿基米德数Ar与Re_p数可揭示出所有数据的内在规律,提出了适用于这类长方体颗粒所有形状的统一曳力模型。