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111.
Zhou Yan Bing Xia Ming Hua Qiu Ding Li Sheng Hong Xi Xu 《Biomedical chromatography : BMC》2013,27(11):1560-1567
A rapid and reliable method was established for simultaneous determination of main triterpenoids in Ganoderma lucidum spores using ultra‐high‐performance liquid chromatography coupled with triple quadrupole mass spectrometry (UPLC‐TQ‐MS). The established method was validated in terms of linearity, sensitivity, precision, accuracy and stability, and was successfully applied to determine the contents of 10 main triterpenoids in different batches of G. lucidum spores. The analysis results showed that moderate levels of triterpenoids were found in G. lucidum spores. In addition, a MS full scan with a daughter ion scan experiment was performed to identify the potential derivatives of triterpenoids present in G. lucidum spores. As a result, a total of 22 triterpenoids from different G. lucidum spores were unequivocally or tentatively identified via comparisons with authentic standards and literatures. This method provides both qualitative and quantitative results without the need for repetitive UPLC‐MS analyses, thereby increasing efficiency and productivity, making it suitable for high‐throughput applications. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
112.
An investigation of heat transfer and pressure drop from some louvered surfaces is presented. The test rig and the measuring as well as the data evaluating procedures are described. The measured data are transferred and presented in a nondimenswnal form. The heal transfer data are provided mainly as Stanton numbers versus Reynolds number, and the pressure drop is given as Darcy friction factors versus Reynolds number. For comparing the performance of the various louvered surfaces, the flow area goodness factors and the so-called volume goodness factors are presented. All the louvered surfaces have been found to be more efficient than the corresponding smooth surface. The standard multilouvered fin surfaces were found to be most efficient, but one of the new surfaces also performed very well. 相似文献
113.
The migration of a downsized crescent-shaped dune was investigated in a wind tunnel experiment.Quantified upwind influx and vertical oscillation of the sand bed were introduced to modulate the saturation level of the sand flux above the dune surface to affect dune evolution.The evolution was recorded by top-view photography and then abstracted as the evolution of self-defined characteristic quantities using a digital image processing algorithm.The results showed that,in contrast to the case for spanwise quantities,the evolution of streamwise quantities corresponds to a linear increase in the modulation magnitude more positively and in a monotonic and convergent manner.In contrast with quantities on the windward face,the changes in quantities with respect to the horns were nonmonotonic with time and almost uncorrelated with the variation in modulation strength,which reveals the distinctiveness of leeside evolution. 相似文献
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Sliced Latin hypercube designs are very useful for running a computer model in batches, ensembles of multiple computer models, computer experiments with qualitative and quantitative factors, cross-validation and data pooling. However, the presence of highly correlated columns makes the data analysis intractable. In this paper, a construction method for sliced (nearly) orthogonal Latin hypercube designs is developed. The resulting designs have flexible sizes and most are new. With the orthogonality or near orthogonality being guaranteed, the space-filling property of the resulting designs is also improved. Examples are provided for illustrating the proposed method. 相似文献
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Magnetic‐based picolinaldehyde–melamine copper complex for the one‐pot synthesis of hexahydroquinolines via Hantzsch four‐component reactions 下载免费PDF全文
A picolinaldehyde–melamine copper complex was loaded on a magnetic Fe3O4 core, so that it contained 0.33 mmol of Cu per gram, and was used as an efficient catalyst. The as‐synthesized catalyst was characterized using various techniques, including Fourier transform infrared spectroscopy, X‐ray diffraction, energy‐dispersive X‐ray spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, vibrating sample magnetometry and thermogravimetric analysis. The catalyst was used to activate the raw materials in the synthesis of hexahydroquinoline derivatives in one‐pot four‐component reactions. Low reaction time (minutes versus half an hour), solvent‐free condition and magnetically separable catalyst are some salient features of the developed catalyst. Also, the optimum amount of catalyst and temperature were determined as 0.07 g and 87.6 °C, respectively, which were obtained using response surface methodology and optimization techniques. 相似文献
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Polymer brushes have been widely used as functional surface coatings for broad applications including antifouling, energy storage, and lubrications. Understanding the molecule dynamics at polymer brush interfaces is important in unraveling the structure–property relationships in these materials and establishing a new materials design paradigm of novel functional polymer thin films with efficient interfacial transport. By applying modern fluorescence‐based single‐molecule spectroscopic and microscopic techniques, molecule dynamics at varied polymer brush interfaces have been experimentally investigated in recent years. New insights are given to the understandings of some unique and unusual materials properties of polymer brush thin films. This review summarizes some recent studies of molecular diffusion at polymer brush interfaces, highlights some new understandings of the interfacial properties of polymer brushes, and discusses future research opportunities in this field. © 2013 Wiley Periodicals, Inc. J. Polym. Sci. Part B: Polym. Phys. 2014 , 52, 85–103 相似文献
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结合新课标要求,揭示塑料薄膜撕扯实验在聚合物教学中的重要性、必要性。通过教学片段设计,发展学生“宏观辨识与微观探析、证据推理与模型认知”化学学科核心素养,并让学生认识物质的性能不仅取决于结构,也取决于生产工艺。并对人教版初、高中化学教材和教参中相关问题展开讨论和解释,以期更好地服务教学。 相似文献