空位对纤锌矿型AlN自发极化影响的最大局域化Wannier函数方法研究

采用基于密度泛函理论的第一性原理平面波超软赝势方法,计算了纤锌矿型AlN中引入不同电荷态的N空位和Al空位时结构中最大局域化Wannier函数,并根据Wannier函数的空间分布及空间分布的几何中心位置,对空位引起的晶体电子结构变化及[0001],[ˉ1010],[ˉ12ˉ10]晶向上的自发极化进行了研究.结果表明,利用最大局域化Wannier函数分析电子结构具有直观的特点,清晰地表明N—Al键具有较强的离子性.研究发现,N空位结构中悬挂键上电荷向空位处转移,而Al空位结构中悬挂键上电荷则远离空位,沿悬挂键方向移动到N原子一侧.同时发现,空位的引入破坏了[ˉ1010],[ˉ12ˉ10]晶向上的中心对称结构,产生了极化,且极化强度随着空位电荷态的增加而增大.在[0001]晶向上,随着N空位电荷态的增加,空位周围电子结构发生了剧烈变化,使得自发极化发生了逆转,极化强度随着电荷态的增加而增大;而在Al空位中,随着电荷态的增加,自发极化沿原方向显著增加,但没有发生极化反转.     

F8BT：P3HT共混薄膜的放大自发辐射

研究了聚合物poly（9,9-dioctylfluorene-co-benzothiadiazole）（F8BT）和poly （3-hexylthiophene）（P3HT）共混薄膜的放大自发辐射（ASE）现象,对影响其阈值的两个因素--增益和损耗进行了详细的研究。结果显示,共混聚合物的发光效率随着P3HT所占比例的增加有所降低。当P3HT比例低于20%时,发光效率降低不多,而其损耗则随着P3HT的增加显著减小。F8BT和P3HT混合后,光损耗系数从7.8 cm^-1下降到4 cm^-1左右。这表明F8BT：P3HT共混聚合物光波导的ASE阈值降低主要是由于其损耗的降低而导致的。ASE阈值的降低预示该材料体系容易实现电泵浦激光。     

一种推导二能级原子自发辐射方法

考虑真空涨落能量为负的特点,提出一个能够简洁描述原子与真空涨落相互作用的方程,得到原子处于激发态的概率随时间变化的关系,讨论了原子自发辐射的速率与真空涨落的强度的关系.     

基于光子晶体光纤的高纯度量子关联光子对的制备

使用脉冲光在室温下抽运一根长1 m 的高非线性光子晶体光纤, 产生了中心波长分别位于830 nm 和1411 nm的具有量子关联性的闲频与信号光子. 实验中闲频和信号通道的带宽分别是15 nm和35 nm. 对单通道光子计数率的拟合结果显示光子几乎全部来源于光纤中的自发四波混频过程, 未受到Raman散射噪声的影响. 当闲频和信号通道的光子产生率约为每脉冲0.0085个时, 测得符合计数率与随机符合计数率的比值为102, 接近理论极限, 不仅证明了光子对的低噪声性, 而且表明所产生的光子对本身具有窄带频谱特性, 因而实验中对其收集效率很高. 此外, 这种高纯度关联光子对还联接了不同波段, 在量子信息技术中有着潜在的应用.     

Investigation of a method to calculate spontaneous radiation spectra from relativistic electrons in undulators

Undulators are key devices to produce brilliant synchrotron radiation at the synchrotron radiation facilities.In this paper we present a numerical computing method,including the computing program that has been developed to calculate the spontaneous radiation emitted from relativistic electrons in undulators by simulating the electrons' trajectory.The effects of electron beam emittance and energy spread have also been taken into account.Comparing with other computing methods available at present,this method has a few advantages with respect to several aspects.It can adopt any measured or arbitrarily simulated 3D magnetic field and arbitrary electron beam pattern for the calculation and it's able to analyze undulators of any type of magnetic structure.It's expected to predict precisely the practical radiation spectrum.The calculation results of a short period in-vacuum undulator and an EllipticaUy Polarized Undulator (EPU) at Shanghai Synchrotron Radiation Facility (SSRF) are presented as examples.     

Neumann Boundary Conditions Inhibiting SSB in Coleman-Weinberg Mechanism

In this work we show that homogeneous Neumann boundary conditionsinhibit the Coleman-Weinberg mechanism for spontaneous symmetry breakingin the scalar electrodynamics if the length of the finite region is small enough (a = e²M^-1_φ, where M_φ is the mass of the scalar field generated by the Coleman-Weinberg mechanism).     

交叉增益调制型波长转换器噪声特性的研究

对基于半导体光放大器的交叉增益调制型波长转换器相向和同向两种工作方式进行了研究。实验上分别实现了两种工作方式在1550nm波段的波长转换,比较了相同外部条件下两种工作方式的噪声特性,在全面考虑放大自发辐射噪声及其消耗载流子,增益谱的色散性和有源区内部损耗等因素的基础上,运用放大器的分段模型,计算了不同条件下两种方式的输出噪声功率,结果表明：相向型工作方式受放大自发辐射噪声的影响要远大于同向工作方式,输出放大自发辐射噪声功率的大小主要取决于载流子浓度的高低,而载流子空间分布的不均匀程度则决定两种工作方式输出噪声功率的差值大小。     

Cosmic history of the Bragin pallasite: evidence from the fission-track analysis

Chronology is rather a weak point in the investigation of pallasites, the stony-iron meteorites. No chronological data are known for the Bragin pallasite. Our attempt to reconstruct its cosmic history was based on the interpretation of fission-track analysis data. To apply this method only uranium-rich phosphates can be used. Extremely rare grains of stanfieldite were extracted from the silicate sawing residue and from the pallasite sample directly.

The researches pursued by us made it possible to find two populations of fossil tracks in stanfieldite grains. The tracks of these populations strongly differed both in size, shape and character of distribution. The first population, consisting of short (L2–6 μm instead of L8–12 μm for induced fission tracks), round-shaped tracks irregularly distributed, as we suppose, suffered an intense heating process, which caused a significant amount of partial annealing. The second population, consisting of longer (L8–12 μm), rhombic-shaped tracks homogeneously distributed, occurred after this thermal event. Only the second population track density was used for the fission-track age calculation.

After correction of the fossil track density, consisting of the second population tracks, for other possible track sources, the revealed tracks were unequivocally identified as those due to the spontaneous fission of ²⁴⁴Pu and ²³⁸U. The largest part of them was attributed to the spontaneous fission of ²⁴⁴Pu; ρ_Pu/ρ_U≈3. The model fission-track age of the studied pallasite turned out to be 4.20 Gyr. This value fix the time of the last shock/thermal event in the cosmic history of the Bragin pallasite, which had caused the partial annealing of tracks presented to that time and “fission-track clock” reset.     

“Charge transfer” polymerization—and the absence thereof!

Mechanisms for “charge‐transfer” spontaneous polymerizations and cycloadditions between electron‐rich olefins and electron‐poor olefins were reviewed. As for propagation, literature proposals involving charge‐transfer complexes were rejected. Instead, alternating copolymerization is ascribed to polar effects in free‐radical reactions. As for spontaneous initiation, literature proposals involving charge‐transfer complexes, with or without proton transfer, were rejected. Instead, the initiating species is postulated to be a tetramethylene zwitterion biradical, which may initiate either ionic homopolymerization or free‐radical copolymerization. A new hypothesis proposes that any interaction that brings vinyl monomers close together may facilitate tetramethylene formation and spontaneous polymerization. These interactions include Coulombic, acid–base, hydrophobic–hydrophilic and templating–tethering interactions. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2069–2077, 2001